Fe‐Based Complexes as Styrene Aziridination Catalysts: Ligand Substitution Tunes Catalyst Activity
As part of our effort to improve our understanding of aziridination mechanism, we used tetra substitution of a diphenol ligand to modify the redox properties of corresponding Fe complexes. This allowed us to confirm that aziridination catalysis by Fe‐based complexes is governed by electron affinity...
Gespeichert in:
| Veröffentlicht in: | ChemCatChem 2019-11, Vol.11 (21), p.5296-5299 |
|---|---|
| Hauptverfasser: | , , , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 5299 |
|---|---|
| container_issue | 21 |
| container_start_page | 5296 |
| container_title | ChemCatChem |
| container_volume | 11 |
| creator | Coin, Guillaume Patra, Ranjan Clémancey, Martin Dubourdeaux, Patrick Pécaut, Jacques Lebrun, Colette Castro, Ludovic Maldivi, Pascale Chardon‐Noblat, Sylvie Latour, Jean‐Marc |
| description | As part of our effort to improve our understanding of aziridination mechanism, we used tetra substitution of a diphenol ligand to modify the redox properties of corresponding Fe complexes. This allowed us to confirm that aziridination catalysis by Fe‐based complexes is governed by electron affinity of the active species and further show that it correlates with the FeIII/FeII redox potential.
Catalyst tuning: Iron aminophenolates: aziridination yields parallel the FeIII/II reduction potentials of the catalyst precursors allowing to evaluate the aziridination capacity of the catalyst by cyclic voltammetry experiments. |
| doi_str_mv | 10.1002/cctc.201901211 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_hal_p</sourceid><recordid>TN_cdi_hal_primary_oai_HAL_hal_02293319v1</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2312726017</sourcerecordid><originalsourceid>FETCH-LOGICAL-c3511-20ec7674bc82cd5275ea846b9c8b907013e1d7bca78d8fd37517c16d7653de1f3</originalsourceid><addsrcrecordid>eNqFkDFPwzAQhSMEEqWwMkdiYkjx2U0cs4WIUqRIDC2z5dgOuEqTEjtAmPgJ_EZ-CSmBMjLd6e57T0_P804BTQAhfCGlkxOMgCHAAHveCOKIBiRmbH-3x-jQO7J2hVDECA1Hnprpz_ePK2G18tN6vSn1q7a-sP7CdY2utJ-8mcYoUwln6spPhRNlZ5299DPzICrlL9rcOuPa7_eyrXr1L-Qn0pln47pj76AQpdUnP3Ps3c-ul-k8yO5ubtMkCyQJAQKMtKQRneYyxlKFmIZaxNMoZzLOGaIIiAZFcylorOJC9fmBSogUjUKiNBRk7J0Pvo-i5JvGrEXT8VoYPk8yvr0hjBkhwJ6hZ88GdtPUT622jq_qtqn6eBwTwBRHCGhPTQZKNrW1jS52toD4tnW-bZ3vWu8FbBC8mFJ3_9A8TZfpn_YLVkSHBw</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2312726017</pqid></control><display><type>article</type><title>Fe‐Based Complexes as Styrene Aziridination Catalysts: Ligand Substitution Tunes Catalyst Activity</title><source>Wiley Online Library All Journals</source><creator>Coin, Guillaume ; Patra, Ranjan ; Clémancey, Martin ; Dubourdeaux, Patrick ; Pécaut, Jacques ; Lebrun, Colette ; Castro, Ludovic ; Maldivi, Pascale ; Chardon‐Noblat, Sylvie ; Latour, Jean‐Marc</creator><creatorcontrib>Coin, Guillaume ; Patra, Ranjan ; Clémancey, Martin ; Dubourdeaux, Patrick ; Pécaut, Jacques ; Lebrun, Colette ; Castro, Ludovic ; Maldivi, Pascale ; Chardon‐Noblat, Sylvie ; Latour, Jean‐Marc</creatorcontrib><description>As part of our effort to improve our understanding of aziridination mechanism, we used tetra substitution of a diphenol ligand to modify the redox properties of corresponding Fe complexes. This allowed us to confirm that aziridination catalysis by Fe‐based complexes is governed by electron affinity of the active species and further show that it correlates with the FeIII/FeII redox potential.
Catalyst tuning: Iron aminophenolates: aziridination yields parallel the FeIII/II reduction potentials of the catalyst precursors allowing to evaluate the aziridination capacity of the catalyst by cyclic voltammetry experiments.</description><identifier>ISSN: 1867-3880</identifier><identifier>ISSN: 1867-3899</identifier><identifier>EISSN: 1867-3899</identifier><identifier>DOI: 10.1002/cctc.201901211</identifier><language>eng</language><publisher>Weinheim: Wiley Subscription Services, Inc</publisher><subject>aziridination ; Catalysis ; Catalysts ; Chemical Sciences ; DFT calculations ; Electron affinity ; iron catalyst ; Ligands ; mechanism ; redox properties ; Substitutes</subject><ispartof>ChemCatChem, 2019-11, Vol.11 (21), p.5296-5299</ispartof><rights>2019 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3511-20ec7674bc82cd5275ea846b9c8b907013e1d7bca78d8fd37517c16d7653de1f3</citedby><cites>FETCH-LOGICAL-c3511-20ec7674bc82cd5275ea846b9c8b907013e1d7bca78d8fd37517c16d7653de1f3</cites><orcidid>0000-0002-9939-4542 ; 0000-0003-2008-1090 ; 0000-0001-6088-3026 ; 0000-0003-0273-1571 ; 0000-0001-9666-3105</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fcctc.201901211$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fcctc.201901211$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>230,314,776,780,881,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttps://hal.science/hal-02293319$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Coin, Guillaume</creatorcontrib><creatorcontrib>Patra, Ranjan</creatorcontrib><creatorcontrib>Clémancey, Martin</creatorcontrib><creatorcontrib>Dubourdeaux, Patrick</creatorcontrib><creatorcontrib>Pécaut, Jacques</creatorcontrib><creatorcontrib>Lebrun, Colette</creatorcontrib><creatorcontrib>Castro, Ludovic</creatorcontrib><creatorcontrib>Maldivi, Pascale</creatorcontrib><creatorcontrib>Chardon‐Noblat, Sylvie</creatorcontrib><creatorcontrib>Latour, Jean‐Marc</creatorcontrib><title>Fe‐Based Complexes as Styrene Aziridination Catalysts: Ligand Substitution Tunes Catalyst Activity</title><title>ChemCatChem</title><description>As part of our effort to improve our understanding of aziridination mechanism, we used tetra substitution of a diphenol ligand to modify the redox properties of corresponding Fe complexes. This allowed us to confirm that aziridination catalysis by Fe‐based complexes is governed by electron affinity of the active species and further show that it correlates with the FeIII/FeII redox potential.
Catalyst tuning: Iron aminophenolates: aziridination yields parallel the FeIII/II reduction potentials of the catalyst precursors allowing to evaluate the aziridination capacity of the catalyst by cyclic voltammetry experiments.</description><subject>aziridination</subject><subject>Catalysis</subject><subject>Catalysts</subject><subject>Chemical Sciences</subject><subject>DFT calculations</subject><subject>Electron affinity</subject><subject>iron catalyst</subject><subject>Ligands</subject><subject>mechanism</subject><subject>redox properties</subject><subject>Substitutes</subject><issn>1867-3880</issn><issn>1867-3899</issn><issn>1867-3899</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNqFkDFPwzAQhSMEEqWwMkdiYkjx2U0cs4WIUqRIDC2z5dgOuEqTEjtAmPgJ_EZ-CSmBMjLd6e57T0_P804BTQAhfCGlkxOMgCHAAHveCOKIBiRmbH-3x-jQO7J2hVDECA1Hnprpz_ePK2G18tN6vSn1q7a-sP7CdY2utJ-8mcYoUwln6spPhRNlZ5299DPzICrlL9rcOuPa7_eyrXr1L-Qn0pln47pj76AQpdUnP3Ps3c-ul-k8yO5ubtMkCyQJAQKMtKQRneYyxlKFmIZaxNMoZzLOGaIIiAZFcylorOJC9fmBSogUjUKiNBRk7J0Pvo-i5JvGrEXT8VoYPk8yvr0hjBkhwJ6hZ88GdtPUT622jq_qtqn6eBwTwBRHCGhPTQZKNrW1jS52toD4tnW-bZ3vWu8FbBC8mFJ3_9A8TZfpn_YLVkSHBw</recordid><startdate>20191107</startdate><enddate>20191107</enddate><creator>Coin, Guillaume</creator><creator>Patra, Ranjan</creator><creator>Clémancey, Martin</creator><creator>Dubourdeaux, Patrick</creator><creator>Pécaut, Jacques</creator><creator>Lebrun, Colette</creator><creator>Castro, Ludovic</creator><creator>Maldivi, Pascale</creator><creator>Chardon‐Noblat, Sylvie</creator><creator>Latour, Jean‐Marc</creator><general>Wiley Subscription Services, Inc</general><general>Wiley</general><scope>AAYXX</scope><scope>CITATION</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0002-9939-4542</orcidid><orcidid>https://orcid.org/0000-0003-2008-1090</orcidid><orcidid>https://orcid.org/0000-0001-6088-3026</orcidid><orcidid>https://orcid.org/0000-0003-0273-1571</orcidid><orcidid>https://orcid.org/0000-0001-9666-3105</orcidid></search><sort><creationdate>20191107</creationdate><title>Fe‐Based Complexes as Styrene Aziridination Catalysts: Ligand Substitution Tunes Catalyst Activity</title><author>Coin, Guillaume ; Patra, Ranjan ; Clémancey, Martin ; Dubourdeaux, Patrick ; Pécaut, Jacques ; Lebrun, Colette ; Castro, Ludovic ; Maldivi, Pascale ; Chardon‐Noblat, Sylvie ; Latour, Jean‐Marc</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3511-20ec7674bc82cd5275ea846b9c8b907013e1d7bca78d8fd37517c16d7653de1f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>aziridination</topic><topic>Catalysis</topic><topic>Catalysts</topic><topic>Chemical Sciences</topic><topic>DFT calculations</topic><topic>Electron affinity</topic><topic>iron catalyst</topic><topic>Ligands</topic><topic>mechanism</topic><topic>redox properties</topic><topic>Substitutes</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Coin, Guillaume</creatorcontrib><creatorcontrib>Patra, Ranjan</creatorcontrib><creatorcontrib>Clémancey, Martin</creatorcontrib><creatorcontrib>Dubourdeaux, Patrick</creatorcontrib><creatorcontrib>Pécaut, Jacques</creatorcontrib><creatorcontrib>Lebrun, Colette</creatorcontrib><creatorcontrib>Castro, Ludovic</creatorcontrib><creatorcontrib>Maldivi, Pascale</creatorcontrib><creatorcontrib>Chardon‐Noblat, Sylvie</creatorcontrib><creatorcontrib>Latour, Jean‐Marc</creatorcontrib><collection>CrossRef</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>ChemCatChem</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Coin, Guillaume</au><au>Patra, Ranjan</au><au>Clémancey, Martin</au><au>Dubourdeaux, Patrick</au><au>Pécaut, Jacques</au><au>Lebrun, Colette</au><au>Castro, Ludovic</au><au>Maldivi, Pascale</au><au>Chardon‐Noblat, Sylvie</au><au>Latour, Jean‐Marc</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Fe‐Based Complexes as Styrene Aziridination Catalysts: Ligand Substitution Tunes Catalyst Activity</atitle><jtitle>ChemCatChem</jtitle><date>2019-11-07</date><risdate>2019</risdate><volume>11</volume><issue>21</issue><spage>5296</spage><epage>5299</epage><pages>5296-5299</pages><issn>1867-3880</issn><issn>1867-3899</issn><eissn>1867-3899</eissn><abstract>As part of our effort to improve our understanding of aziridination mechanism, we used tetra substitution of a diphenol ligand to modify the redox properties of corresponding Fe complexes. This allowed us to confirm that aziridination catalysis by Fe‐based complexes is governed by electron affinity of the active species and further show that it correlates with the FeIII/FeII redox potential.
Catalyst tuning: Iron aminophenolates: aziridination yields parallel the FeIII/II reduction potentials of the catalyst precursors allowing to evaluate the aziridination capacity of the catalyst by cyclic voltammetry experiments.</abstract><cop>Weinheim</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/cctc.201901211</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0002-9939-4542</orcidid><orcidid>https://orcid.org/0000-0003-2008-1090</orcidid><orcidid>https://orcid.org/0000-0001-6088-3026</orcidid><orcidid>https://orcid.org/0000-0003-0273-1571</orcidid><orcidid>https://orcid.org/0000-0001-9666-3105</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1867-3880 |
| ispartof | ChemCatChem, 2019-11, Vol.11 (21), p.5296-5299 |
| issn | 1867-3880 1867-3899 1867-3899 |
| language | eng |
| recordid | cdi_hal_primary_oai_HAL_hal_02293319v1 |
| source | Wiley Online Library All Journals |
| subjects | aziridination Catalysis Catalysts Chemical Sciences DFT calculations Electron affinity iron catalyst Ligands mechanism redox properties Substitutes |
| title | Fe‐Based Complexes as Styrene Aziridination Catalysts: Ligand Substitution Tunes Catalyst Activity |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-02-07T08%3A24%3A07IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_hal_p&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Fe%E2%80%90Based%20Complexes%20as%20Styrene%20Aziridination%20Catalysts:%20Ligand%20Substitution%20Tunes%20Catalyst%20Activity&rft.jtitle=ChemCatChem&rft.au=Coin,%20Guillaume&rft.date=2019-11-07&rft.volume=11&rft.issue=21&rft.spage=5296&rft.epage=5299&rft.pages=5296-5299&rft.issn=1867-3880&rft.eissn=1867-3899&rft_id=info:doi/10.1002/cctc.201901211&rft_dat=%3Cproquest_hal_p%3E2312726017%3C/proquest_hal_p%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2312726017&rft_id=info:pmid/&rfr_iscdi=true |