Contributions of local and regional anthropogenic sources of metals in PM 2.5 at an urban site in northern France
PM have been related to various adverse health effects, mainly due to their ability to penetrate deeply and to convey harmful chemical components, such as metals inside the body. In this work, PM were sampled at Saint-Omer, a medium-sized city located in northern France, in March-April 2011 and anal...
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| Veröffentlicht in: | Chemosphere (Oxford) 2017-08, Vol.181, p.713-724 |
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| creator | Ledoux, Frédéric Kfoury, Adib Delmaire, Gilles Roussel, Gilles El Zein, Atallah Courcot, Dominique |
| description | PM
have been related to various adverse health effects, mainly due to their ability to penetrate deeply and to convey harmful chemical components, such as metals inside the body. In this work, PM
were sampled at Saint-Omer, a medium-sized city located in northern France, in March-April 2011 and analyzed for their total carbon, water-soluble ions, major and trace elements. More specifically, the origin of 15 selected elements was examined using different tools including enrichment factors, conditional bivariate probability function (CBPF) representations, diagnostic ratios and receptor modelling. The results indicated that PM
metal composition is affected by both emissions of a local glassmaking factory and an integrated steelworks located at a distance of 35 km from the sampling site. For the first time, diagnostic ratios were proposed for the glassmaking activity. Therefore, metals in PM
could be attributed to the following anthropogenic sources: (i) local glassmaking industry for Sn, As, Cu and Cr, (ii) distant integrated steelworks for Ag, Fe, Cd, Mn, Rb and Pb, (iii) heavy fuel oil combustion for Ni, V and Co and (iv) non-exhaust traffic for Zn, Pb, Mn, Sb, and Cu. The impact of such sources on metal concentrations in PM
was assessed using a constrained receptor model. Despite their low participation to PM
concentration (2.7%), the latter sources were found as the main contributors (80%) to the overall concentration levels of the 15 selected elements in PM
. |
| doi_str_mv | 10.1016/j.chemosphere.2017.04.128 |
| format | Article |
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have been related to various adverse health effects, mainly due to their ability to penetrate deeply and to convey harmful chemical components, such as metals inside the body. In this work, PM
were sampled at Saint-Omer, a medium-sized city located in northern France, in March-April 2011 and analyzed for their total carbon, water-soluble ions, major and trace elements. More specifically, the origin of 15 selected elements was examined using different tools including enrichment factors, conditional bivariate probability function (CBPF) representations, diagnostic ratios and receptor modelling. The results indicated that PM
metal composition is affected by both emissions of a local glassmaking factory and an integrated steelworks located at a distance of 35 km from the sampling site. For the first time, diagnostic ratios were proposed for the glassmaking activity. Therefore, metals in PM
could be attributed to the following anthropogenic sources: (i) local glassmaking industry for Sn, As, Cu and Cr, (ii) distant integrated steelworks for Ag, Fe, Cd, Mn, Rb and Pb, (iii) heavy fuel oil combustion for Ni, V and Co and (iv) non-exhaust traffic for Zn, Pb, Mn, Sb, and Cu. The impact of such sources on metal concentrations in PM
was assessed using a constrained receptor model. Despite their low participation to PM
concentration (2.7%), the latter sources were found as the main contributors (80%) to the overall concentration levels of the 15 selected elements in PM
.</description><identifier>ISSN: 0045-6535</identifier><identifier>EISSN: 1879-1298</identifier><identifier>DOI: 10.1016/j.chemosphere.2017.04.128</identifier><identifier>PMID: 28477528</identifier><language>eng</language><publisher>England: Elsevier</publisher><subject>Air Pollutants - analysis ; Analytical chemistry ; Chemical Sciences ; Cities ; Computer Science ; Environmental Monitoring - methods ; France ; Industrial Waste - analysis ; Metals, Heavy - analysis ; Models, Theoretical ; Particulate Matter - analysis ; Signal and Image Processing ; Trace Elements - analysis</subject><ispartof>Chemosphere (Oxford), 2017-08, Vol.181, p.713-724</ispartof><rights>Copyright © 2017 Elsevier Ltd. All rights reserved.</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><orcidid>0000-0003-4425-4507 ; 0000-0001-6475-1450 ; 0000-0002-8531-1566 ; 0000-0001-7985-6503</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,776,780,881,27901,27902</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/28477528$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://hal.science/hal-02293180$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Ledoux, Frédéric</creatorcontrib><creatorcontrib>Kfoury, Adib</creatorcontrib><creatorcontrib>Delmaire, Gilles</creatorcontrib><creatorcontrib>Roussel, Gilles</creatorcontrib><creatorcontrib>El Zein, Atallah</creatorcontrib><creatorcontrib>Courcot, Dominique</creatorcontrib><title>Contributions of local and regional anthropogenic sources of metals in PM 2.5 at an urban site in northern France</title><title>Chemosphere (Oxford)</title><addtitle>Chemosphere</addtitle><description>PM
have been related to various adverse health effects, mainly due to their ability to penetrate deeply and to convey harmful chemical components, such as metals inside the body. In this work, PM
were sampled at Saint-Omer, a medium-sized city located in northern France, in March-April 2011 and analyzed for their total carbon, water-soluble ions, major and trace elements. More specifically, the origin of 15 selected elements was examined using different tools including enrichment factors, conditional bivariate probability function (CBPF) representations, diagnostic ratios and receptor modelling. The results indicated that PM
metal composition is affected by both emissions of a local glassmaking factory and an integrated steelworks located at a distance of 35 km from the sampling site. For the first time, diagnostic ratios were proposed for the glassmaking activity. Therefore, metals in PM
could be attributed to the following anthropogenic sources: (i) local glassmaking industry for Sn, As, Cu and Cr, (ii) distant integrated steelworks for Ag, Fe, Cd, Mn, Rb and Pb, (iii) heavy fuel oil combustion for Ni, V and Co and (iv) non-exhaust traffic for Zn, Pb, Mn, Sb, and Cu. The impact of such sources on metal concentrations in PM
was assessed using a constrained receptor model. Despite their low participation to PM
concentration (2.7%), the latter sources were found as the main contributors (80%) to the overall concentration levels of the 15 selected elements in PM
.</description><subject>Air Pollutants - analysis</subject><subject>Analytical chemistry</subject><subject>Chemical Sciences</subject><subject>Cities</subject><subject>Computer Science</subject><subject>Environmental Monitoring - methods</subject><subject>France</subject><subject>Industrial Waste - analysis</subject><subject>Metals, Heavy - analysis</subject><subject>Models, Theoretical</subject><subject>Particulate Matter - analysis</subject><subject>Signal and Image Processing</subject><subject>Trace Elements - analysis</subject><issn>0045-6535</issn><issn>1879-1298</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNo9kMFOwzAMhiMEYmPwCigcObQkbtKkx2liDKkIDrtXaZqtndqkpC0Sb0-2ARdb_v39lm2EHiiJKaHp0yHWtenc0NfGmxgIFTFhMQV5geZUiiyikMlLNCeE8SjlCZ-hm2E4EBLMPLtGM5BMCA5yjj5Xzo6-KaexcXbAbodbp1WLla2wN_sgnoqx9q53e2MbjQc3eW1ObGdG1Q64sfjjDUPMsRoDjCdfhjg0ozm2rPNjWNTitVdWm1t0tQsmc_ebF2i7ft6uNlH-_vK6WuZRzYWMSk1LZkDzBMpMM6HKKmUCEs7DBVQymSopqixjOw5KS5qkVKYgtQFmlAaVLNDjeWyt2qL3Taf8d-FUU2yWeXHUCECWUEm-aGDvz2w_lZ2p_vG_NyU_31ttBw</recordid><startdate>201708</startdate><enddate>201708</enddate><creator>Ledoux, Frédéric</creator><creator>Kfoury, Adib</creator><creator>Delmaire, Gilles</creator><creator>Roussel, Gilles</creator><creator>El Zein, Atallah</creator><creator>Courcot, Dominique</creator><general>Elsevier</general><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0003-4425-4507</orcidid><orcidid>https://orcid.org/0000-0001-6475-1450</orcidid><orcidid>https://orcid.org/0000-0002-8531-1566</orcidid><orcidid>https://orcid.org/0000-0001-7985-6503</orcidid></search><sort><creationdate>201708</creationdate><title>Contributions of local and regional anthropogenic sources of metals in PM 2.5 at an urban site in northern France</title><author>Ledoux, Frédéric ; Kfoury, Adib ; Delmaire, Gilles ; Roussel, Gilles ; El Zein, Atallah ; Courcot, Dominique</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-h578-bc1b4e2c532b9c47abd647235565918486a87d994f52ac813618628ce24eac2a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Air Pollutants - analysis</topic><topic>Analytical chemistry</topic><topic>Chemical Sciences</topic><topic>Cities</topic><topic>Computer Science</topic><topic>Environmental Monitoring - methods</topic><topic>France</topic><topic>Industrial Waste - analysis</topic><topic>Metals, Heavy - analysis</topic><topic>Models, Theoretical</topic><topic>Particulate Matter - analysis</topic><topic>Signal and Image Processing</topic><topic>Trace Elements - analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ledoux, Frédéric</creatorcontrib><creatorcontrib>Kfoury, Adib</creatorcontrib><creatorcontrib>Delmaire, Gilles</creatorcontrib><creatorcontrib>Roussel, Gilles</creatorcontrib><creatorcontrib>El Zein, Atallah</creatorcontrib><creatorcontrib>Courcot, Dominique</creatorcontrib><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Chemosphere (Oxford)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ledoux, Frédéric</au><au>Kfoury, Adib</au><au>Delmaire, Gilles</au><au>Roussel, Gilles</au><au>El Zein, Atallah</au><au>Courcot, Dominique</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Contributions of local and regional anthropogenic sources of metals in PM 2.5 at an urban site in northern France</atitle><jtitle>Chemosphere (Oxford)</jtitle><addtitle>Chemosphere</addtitle><date>2017-08</date><risdate>2017</risdate><volume>181</volume><spage>713</spage><epage>724</epage><pages>713-724</pages><issn>0045-6535</issn><eissn>1879-1298</eissn><abstract>PM
have been related to various adverse health effects, mainly due to their ability to penetrate deeply and to convey harmful chemical components, such as metals inside the body. In this work, PM
were sampled at Saint-Omer, a medium-sized city located in northern France, in March-April 2011 and analyzed for their total carbon, water-soluble ions, major and trace elements. More specifically, the origin of 15 selected elements was examined using different tools including enrichment factors, conditional bivariate probability function (CBPF) representations, diagnostic ratios and receptor modelling. The results indicated that PM
metal composition is affected by both emissions of a local glassmaking factory and an integrated steelworks located at a distance of 35 km from the sampling site. For the first time, diagnostic ratios were proposed for the glassmaking activity. Therefore, metals in PM
could be attributed to the following anthropogenic sources: (i) local glassmaking industry for Sn, As, Cu and Cr, (ii) distant integrated steelworks for Ag, Fe, Cd, Mn, Rb and Pb, (iii) heavy fuel oil combustion for Ni, V and Co and (iv) non-exhaust traffic for Zn, Pb, Mn, Sb, and Cu. The impact of such sources on metal concentrations in PM
was assessed using a constrained receptor model. Despite their low participation to PM
concentration (2.7%), the latter sources were found as the main contributors (80%) to the overall concentration levels of the 15 selected elements in PM
.</abstract><cop>England</cop><pub>Elsevier</pub><pmid>28477528</pmid><doi>10.1016/j.chemosphere.2017.04.128</doi><tpages>12</tpages><orcidid>https://orcid.org/0000-0003-4425-4507</orcidid><orcidid>https://orcid.org/0000-0001-6475-1450</orcidid><orcidid>https://orcid.org/0000-0002-8531-1566</orcidid><orcidid>https://orcid.org/0000-0001-7985-6503</orcidid></addata></record> |
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| ispartof | Chemosphere (Oxford), 2017-08, Vol.181, p.713-724 |
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| source | MEDLINE; Elsevier ScienceDirect Journals |
| subjects | Air Pollutants - analysis Analytical chemistry Chemical Sciences Cities Computer Science Environmental Monitoring - methods France Industrial Waste - analysis Metals, Heavy - analysis Models, Theoretical Particulate Matter - analysis Signal and Image Processing Trace Elements - analysis |
| title | Contributions of local and regional anthropogenic sources of metals in PM 2.5 at an urban site in northern France |
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