Regioselective Pd-Catalyzed Carbopalladation/Decarboxylative Allylic Alkynylation of ortho-Iodoallenamides with Alkynyl Carboxylic Acids

A regioselective Pd-catalyzed domino carbopalladation/decarboxylative allylic alkynylation of ortho-iodoallenamides with alkynyl carboxylic acids was studied. This domino process, based on the consecutive formation of C­(sp2)–C­(sp2) and C­(sp3)–C­(sp) bonds, was originally achieved for the design o...

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Veröffentlicht in:Journal of organic chemistry 2019-08, Vol.84 (16), p.10535-10545
Hauptverfasser: Hédouin, Jonathan, Carpentier, Vincent, Renard, Romain M. Q, Schneider, Cédric, Gillaizeau, Isabelle, Hoarau, Christophe
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Sprache:eng
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