Structural Transition at 360 K in the CaFe 5 O 7 Ferrite: Toward a New Charge Ordering Distribution

An efficient synthesis route is proposed to obtain single phase powder ceramic of CaFe5O7. This complex structure can be described as an intergrowth between one CaFe2O4 unit and n = 3 slices of FeO Wüstite-type structure. A detailed structural study has been carried out at room temperature combining...

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Veröffentlicht in:Inorganic chemistry 2014-10, Vol.53 (19), p.10171-10177
Hauptverfasser: Delacotte, C., Hüe, F., Bréard, Y., Hébert, S., Pérez, O., Caignaert, V., Greneche, J. M., Pelloquin, D.
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Sprache:eng
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