Phase equilibria in the Zn–Mn–O system

Different ratios of ZnO and MnCO3 were mixed and processed by ceramic route to investigate phase relations in the Zn–Mn–O system using differential thermal analysis and X-ray powder diffraction techniques. Except for Zn1−xMnxO we detected two different spinel phases in this system. FactSage program...

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Veröffentlicht in:Journal of the European Ceramic Society 2015-02, Vol.35 (2), p.555-560
Hauptverfasser: Nádherný, Ladislav, Jankovský, Ondřej, Sofer, Zdeněk, Leitner, Jindřich, Martin, Christine, Sedmidubský, David
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container_issue 2
container_start_page 555
container_title Journal of the European Ceramic Society
container_volume 35
creator Nádherný, Ladislav
Jankovský, Ondřej
Sofer, Zdeněk
Leitner, Jindřich
Martin, Christine
Sedmidubský, David
description Different ratios of ZnO and MnCO3 were mixed and processed by ceramic route to investigate phase relations in the Zn–Mn–O system using differential thermal analysis and X-ray powder diffraction techniques. Except for Zn1−xMnxO we detected two different spinel phases in this system. FactSage program was used for the construction of the Zn–Mn–O phase diagram in air and oxygen atmosphere. To verify the composition in several parts of the diagram at the temperature of interest, a number of high-temperature annealings followed by quenching was performed.
doi_str_mv 10.1016/j.jeurceramsoc.2014.09.008
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subjects Chemical Sciences
Cristallography
Material chemistry
or physical chemistry
Phase diagram
Spinel
Theoretical and
Thermodynamic properties
Zinc oxide
Zn–Mn–O
title Phase equilibria in the Zn–Mn–O system
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