"Fishing" of heteropolyacids into carbonaceous seine via coking

"Fishing" of heteropolyacids into carbonaceous seine via coking

The carbon encapsulated tungstophosphoric acid was synthesized by the controlled coking during gas phase reaction of formaldehyde with isobutene. The as-made material showed unique stability toward leaching in the aqueous phase due to localization of HPA clusters inside the porous coke matrix with h...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2015-01, Vol.51 (96), p.17120-17123
Hauptverfasser: Sushkevich, Vitaly L, Ivanova, Irina I, Lancelot, Christine, Moldovan, Simona, Ersen, Ovidiu, Ordomsky, Vitaly V
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Sprache:eng
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Catalysis
Chemical Sciences
Material chemistry
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container_end_page 17123
container_issue 96
container_start_page 17120
container_title Chemical communications (Cambridge, England)
container_volume 51
creator Sushkevich, Vitaly L
Ivanova, Irina I
Lancelot, Christine
Moldovan, Simona
Ersen, Ovidiu
Ordomsky, Vitaly V
description The carbon encapsulated tungstophosphoric acid was synthesized by the controlled coking during gas phase reaction of formaldehyde with isobutene. The as-made material showed unique stability toward leaching in the aqueous phase due to localization of HPA clusters inside the porous coke matrix with high activity in the esterification reaction.
doi_str_mv 10.1039/c5cc07280h
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Catalysis
Chemical Sciences
Material chemistry
title "Fishing" of heteropolyacids into carbonaceous seine via coking
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