Unique Class of Enantiopure N‑Heterocyclic Carbene Half-Sandwich Iridium(III) Complexes with Stable Configurations: Probing Five-Membered versus Six-Membered Iridacycles

A unique class of enantiopure N-heterocyclic carbene half-sandwich iridium complexes is reported. These compounds display stable configurations at the metal center, as demonstrated by their chiroptical properties. Remarkably, because of the nature of the naphthalimide molecule, two regioisomers cont...

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Veröffentlicht in:	Inorganic chemistry 2019-03, Vol.58 (5), p.2930-2933
Hauptverfasser:	Groué, Antoine, Tranchier, Jean-Philippe, Rager, Marie-Noelle, Gontard, Geoffrey, Jean, Marion, Vanthuyne, Nicolas, Pearce, Harrison R, Cooksy, Andrew L, Amouri, Hani
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical Sciences Coordination chemistry
Online-Zugang:	Volltext
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