Impact of Zeolite Structure on Entropic–Enthalpic Contributions to Alkane Monomolecular Cracking: An IR Operando Study

The monomolecular cracking rates of propane and n‐butane over MFI, CHA, FER and TON zeolites were determined simultaneously with the coverage of active sites at reaction condition using IR operando spectroscopy. This allowed direct determination of adsorption thermodynamics and intrinsic rate parame...

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Veröffentlicht in:	Chemistry : a European journal 2018-04, Vol.24 (21), p.5489-5492
Hauptverfasser:	Kadam, Shashikant A., Li, Haoguang, Wormsbecher, Richard F., Travert, Arnaud
Format:	Artikel
Sprache:	eng
Schlagworte:	Activation energy activation entropy adsorption Alkanes Butane Catalysis Chemical Sciences Chemistry Confinement Enthalpy Entropy Entropy of activation IR operando spectroscopy Zeolites
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