A Fullerene‐Substituted Pillar[5]arene for the Construction of a Photoactive Rotaxane

Transformation of a methylene group of the pillar[5]arene scaffold into a ketone has been achieved by treatment with N‐bromosuccinimide followed by hydrolysis of the bromide intermediate and oxidation of the resulting secondary benzylic alcohol with BaMnO4. Condensation of the resulting macrocycle i...

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Veröffentlicht in:	Helvetica chimica acta 2018-06, Vol.101 (6), p.n/a
Hauptverfasser:	Meichsner, Eric, Nierengarten, Iwona, Holler, Michel, Chessé, Matthieu, Nierengarten, Jean‐François
Format:	Artikel
Sprache:	eng
Schlagworte:	Alcohols Buckminsterfullerene Chemical Sciences Construction Fullerenes Ketones Molecular chains Organic chemistry Oxidation photoactive molecular device pillararenes porphyrins rotaxanes Shafts (machine elements)
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