The impact of paper constituents on the efficiency of mechanical strengthening by polyaminoalkylalkoxysilanes

The aim of the research was to evaluate the influence of certain components of paper such as lignin and papermaking additives (fillers and sizing) on the efficiency of a recently proposed treatment for simultaneous deacidification and mechanical strengthening with polyaminosiloxane copolymer network...

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Veröffentlicht in:Cellulose (London) 2017-12, Vol.24 (12), p.5671-5684
Hauptverfasser: Piovesan, Camille, Fabre-Francke, Isabelle, Dupont, Anne-Laurence, Fichet, Odile, Paris-Lacombe, Sabrina, Lavédrine, Bertrand, Cheradame, Hervé
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container_end_page 5684
container_issue 12
container_start_page 5671
container_title Cellulose (London)
container_volume 24
creator Piovesan, Camille
Fabre-Francke, Isabelle
Dupont, Anne-Laurence
Fichet, Odile
Paris-Lacombe, Sabrina
Lavédrine, Bertrand
Cheradame, Hervé
description The aim of the research was to evaluate the influence of certain components of paper such as lignin and papermaking additives (fillers and sizing) on the efficiency of a recently proposed treatment for simultaneous deacidification and mechanical strengthening with polyaminosiloxane copolymer networks. Mixed mechanical and chemical pulp papers containing various additives were treated with aminoalkylalkoxysilanes (AAAS) by immersion or by spray. Upon treatment, the deposited alkaline reserve varied from 0.34 to 1.14 mol kg −1 . For all the papers, copolymers formed from binary mixtures of a di- and a tri-functional AAAS provided the best improvement in the mechanical properties, i.e. in the tensile strength and the folding endurance, indicating an increase in the interfiber bonding energy and in the paper flexibility and plasticity, respectively. It was found that fillers had no influence while sizing hampered the efficiency of the treatment. The presence of mechanical pulp was shown to have a significant impact on the effect of the treatments as well by increasing the tensile resistance more than the folding endurance, indicating an increase in the paper rigidity. This observation was attributed to the response of lignin to the treatment.
doi_str_mv 10.1007/s10570-017-1513-5
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subjects Additives
Binary mixtures
Bioorganic Chemistry
Bonding strength
Ceramics
Chemical bonds
Chemical Sciences
Chemistry
Chemistry and Materials Science
Composites
Copolymers
Durability
Efficiency
Endurance
Fillers
Folding
Glass
Lignin
Mechanical properties
Natural Materials
Organic Chemistry
Original Paper
Papermaking
Physical Chemistry
Polymer Sciences
Polymers
Sizing
Submerging
Sustainable Development
title The impact of paper constituents on the efficiency of mechanical strengthening by polyaminoalkylalkoxysilanes
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