Understanding Gas-Induced Structural Deformation of ZIF-8

ZIF-8 is a zeolitic imidazolate framework with very good thermal and chemical stability that opens up many applications that are not feasible by other metal–organic frameowrks (MOFs) and zeolites. Several works report the adsorption properties of ZIF-8 for strategic gases. However, despite the vast...

Ausführliche Beschreibung

Gespeichert in:

Bibliographische Detailangaben
Veröffentlicht in:	The journal of physical chemistry letters 2012-05, Vol.3 (9), p.1159-1164
Hauptverfasser:	Ania, Conchi O, García-Pérez, E, Haro, M, Gutiérrez-Sevillano, J. J, Valdés-Solís, T, Parra, J. B, Calero, S
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Chemical Sciences Environmental Engineering Environmental Sciences Material chemistry Surfaces, Interfaces, Porous Materials, and Catalysis
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!

container_end_page	1164
container_issue	9
container_start_page	1159
container_title	The journal of physical chemistry letters
container_volume	3
creator	Ania, Conchi O García-Pérez, E Haro, M Gutiérrez-Sevillano, J. J Valdés-Solís, T Parra, J. B Calero, S
description	ZIF-8 is a zeolitic imidazolate framework with very good thermal and chemical stability that opens up many applications that are not feasible by other metal–organic frameowrks (MOFs) and zeolites. Several works report the adsorption properties of ZIF-8 for strategic gases. However, despite the vast experimental corpus of data reported, there seems yet to be a dearth in the understanding of the gas adsorption properties. In this work we provide insights at a molecular level on the mechanisms governing the ZIF-8 structural deformation during molecular adsorption. We demonstrate that the ZIF-8 structural deformation during the adsorption of different molecules at cryogenic temperature goes beyond the gas-induced rotation of the imidazolate linkers. We combine experimental and simulation studies to demonstrate that this deformation is governed by the polarizability and molecular size and shape of the gases, and that the stepped adsorption behavior is defined by the packing arrangement of the guest inside the host.
doi_str_mv	10.1021/jz300292y
format	Article
fullrecord	<record><control><sourceid>proquest_hal_p</sourceid><recordid>TN_cdi_hal_primary_oai_HAL_hal_02124970v1</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1715659285</sourcerecordid><originalsourceid>FETCH-LOGICAL-a415t-e363bee061597ecb717c6c2e45ff02304326deabc02b9a005ee4252ca43525f93</originalsourceid><addsrcrecordid>eNptkL1OwzAURi0EoqUw8AIoCxIMgWsnTuKxKvRHqsQAXVgsx7mBVElc7ASpPD2pUgoD0_10dXSGQ8glhTsKjN6vvwIAJtj2iAypCBM_pgk__rMH5My5NUAkIIlPyYBFLEmA0yERqzpD6xpVZ0X95s2U8xd11mrMvOfGtrpprSq9B8yNrVRTmNozufe6mPrJOTnJVenwYn9HZDV9fJnM_eXTbDEZL30VUt74GERBiggR5SJGncY01pFmGPI8BxZAGLAoQ5VqYKlQABwxZJxpFQac8VwEI3Lbe99VKTe2qJTdSqMKOR8v5e7XFWChiOGTduxNz26s-WjRNbIqnMayVDWa1kkaUx5xwRL-q9XWOGcxP7gpyF1VeajasVd7bZtWmB3In4wdcN0DSju5Nq2tuyL_iL4BRg97mg</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1715659285</pqid></control><display><type>article</type><title>Understanding Gas-Induced Structural Deformation of ZIF-8</title><source>American Chemical Society Journals</source><creator>Ania, Conchi O ; García-Pérez, E ; Haro, M ; Gutiérrez-Sevillano, J. J ; Valdés-Solís, T ; Parra, J. B ; Calero, S</creator><creatorcontrib>Ania, Conchi O ; García-Pérez, E ; Haro, M ; Gutiérrez-Sevillano, J. J ; Valdés-Solís, T ; Parra, J. B ; Calero, S</creatorcontrib><description>ZIF-8 is a zeolitic imidazolate framework with very good thermal and chemical stability that opens up many applications that are not feasible by other metal–organic frameowrks (MOFs) and zeolites. Several works report the adsorption properties of ZIF-8 for strategic gases. However, despite the vast experimental corpus of data reported, there seems yet to be a dearth in the understanding of the gas adsorption properties. In this work we provide insights at a molecular level on the mechanisms governing the ZIF-8 structural deformation during molecular adsorption. We demonstrate that the ZIF-8 structural deformation during the adsorption of different molecules at cryogenic temperature goes beyond the gas-induced rotation of the imidazolate linkers. We combine experimental and simulation studies to demonstrate that this deformation is governed by the polarizability and molecular size and shape of the gases, and that the stepped adsorption behavior is defined by the packing arrangement of the guest inside the host.</description><identifier>ISSN: 1948-7185</identifier><identifier>EISSN: 1948-7185</identifier><identifier>DOI: 10.1021/jz300292y</identifier><identifier>PMID: 26288051</identifier><language>eng</language><publisher>United States: American Chemical Society</publisher><subject>Catalysis ; Chemical Sciences ; Environmental Engineering ; Environmental Sciences ; Material chemistry ; Surfaces, Interfaces, Porous Materials, and Catalysis</subject><ispartof>The journal of physical chemistry letters, 2012-05, Vol.3 (9), p.1159-1164</ispartof><rights>Copyright © 2012 American Chemical Society</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a415t-e363bee061597ecb717c6c2e45ff02304326deabc02b9a005ee4252ca43525f93</citedby><cites>FETCH-LOGICAL-a415t-e363bee061597ecb717c6c2e45ff02304326deabc02b9a005ee4252ca43525f93</cites><orcidid>0000-0001-9517-8132 ; 0000-0001-9535-057X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/jz300292y$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/jz300292y$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>230,314,776,780,881,2752,27053,27901,27902,56713,56763</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/26288051$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://hal.science/hal-02124970$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Ania, Conchi O</creatorcontrib><creatorcontrib>García-Pérez, E</creatorcontrib><creatorcontrib>Haro, M</creatorcontrib><creatorcontrib>Gutiérrez-Sevillano, J. J</creatorcontrib><creatorcontrib>Valdés-Solís, T</creatorcontrib><creatorcontrib>Parra, J. B</creatorcontrib><creatorcontrib>Calero, S</creatorcontrib><title>Understanding Gas-Induced Structural Deformation of ZIF-8</title><title>The journal of physical chemistry letters</title><addtitle>J. Phys. Chem. Lett</addtitle><description>ZIF-8 is a zeolitic imidazolate framework with very good thermal and chemical stability that opens up many applications that are not feasible by other metal–organic frameowrks (MOFs) and zeolites. Several works report the adsorption properties of ZIF-8 for strategic gases. However, despite the vast experimental corpus of data reported, there seems yet to be a dearth in the understanding of the gas adsorption properties. In this work we provide insights at a molecular level on the mechanisms governing the ZIF-8 structural deformation during molecular adsorption. We demonstrate that the ZIF-8 structural deformation during the adsorption of different molecules at cryogenic temperature goes beyond the gas-induced rotation of the imidazolate linkers. We combine experimental and simulation studies to demonstrate that this deformation is governed by the polarizability and molecular size and shape of the gases, and that the stepped adsorption behavior is defined by the packing arrangement of the guest inside the host.</description><subject>Catalysis</subject><subject>Chemical Sciences</subject><subject>Environmental Engineering</subject><subject>Environmental Sciences</subject><subject>Material chemistry</subject><subject>Surfaces, Interfaces, Porous Materials, and Catalysis</subject><issn>1948-7185</issn><issn>1948-7185</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2012</creationdate><recordtype>article</recordtype><recordid>eNptkL1OwzAURi0EoqUw8AIoCxIMgWsnTuKxKvRHqsQAXVgsx7mBVElc7ASpPD2pUgoD0_10dXSGQ8glhTsKjN6vvwIAJtj2iAypCBM_pgk__rMH5My5NUAkIIlPyYBFLEmA0yERqzpD6xpVZ0X95s2U8xd11mrMvOfGtrpprSq9B8yNrVRTmNozufe6mPrJOTnJVenwYn9HZDV9fJnM_eXTbDEZL30VUt74GERBiggR5SJGncY01pFmGPI8BxZAGLAoQ5VqYKlQABwxZJxpFQac8VwEI3Lbe99VKTe2qJTdSqMKOR8v5e7XFWChiOGTduxNz26s-WjRNbIqnMayVDWa1kkaUx5xwRL-q9XWOGcxP7gpyF1VeajasVd7bZtWmB3In4wdcN0DSju5Nq2tuyL_iL4BRg97mg</recordid><startdate>20120503</startdate><enddate>20120503</enddate><creator>Ania, Conchi O</creator><creator>García-Pérez, E</creator><creator>Haro, M</creator><creator>Gutiérrez-Sevillano, J. J</creator><creator>Valdés-Solís, T</creator><creator>Parra, J. B</creator><creator>Calero, S</creator><general>American Chemical Society</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0001-9517-8132</orcidid><orcidid>https://orcid.org/0000-0001-9535-057X</orcidid></search><sort><creationdate>20120503</creationdate><title>Understanding Gas-Induced Structural Deformation of ZIF-8</title><author>Ania, Conchi O ; García-Pérez, E ; Haro, M ; Gutiérrez-Sevillano, J. J ; Valdés-Solís, T ; Parra, J. B ; Calero, S</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a415t-e363bee061597ecb717c6c2e45ff02304326deabc02b9a005ee4252ca43525f93</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2012</creationdate><topic>Catalysis</topic><topic>Chemical Sciences</topic><topic>Environmental Engineering</topic><topic>Environmental Sciences</topic><topic>Material chemistry</topic><topic>Surfaces, Interfaces, Porous Materials, and Catalysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ania, Conchi O</creatorcontrib><creatorcontrib>García-Pérez, E</creatorcontrib><creatorcontrib>Haro, M</creatorcontrib><creatorcontrib>Gutiérrez-Sevillano, J. J</creatorcontrib><creatorcontrib>Valdés-Solís, T</creatorcontrib><creatorcontrib>Parra, J. B</creatorcontrib><creatorcontrib>Calero, S</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>The journal of physical chemistry letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ania, Conchi O</au><au>García-Pérez, E</au><au>Haro, M</au><au>Gutiérrez-Sevillano, J. J</au><au>Valdés-Solís, T</au><au>Parra, J. B</au><au>Calero, S</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Understanding Gas-Induced Structural Deformation of ZIF-8</atitle><jtitle>The journal of physical chemistry letters</jtitle><addtitle>J. Phys. Chem. Lett</addtitle><date>2012-05-03</date><risdate>2012</risdate><volume>3</volume><issue>9</issue><spage>1159</spage><epage>1164</epage><pages>1159-1164</pages><issn>1948-7185</issn><eissn>1948-7185</eissn><abstract>ZIF-8 is a zeolitic imidazolate framework with very good thermal and chemical stability that opens up many applications that are not feasible by other metal–organic frameowrks (MOFs) and zeolites. Several works report the adsorption properties of ZIF-8 for strategic gases. However, despite the vast experimental corpus of data reported, there seems yet to be a dearth in the understanding of the gas adsorption properties. In this work we provide insights at a molecular level on the mechanisms governing the ZIF-8 structural deformation during molecular adsorption. We demonstrate that the ZIF-8 structural deformation during the adsorption of different molecules at cryogenic temperature goes beyond the gas-induced rotation of the imidazolate linkers. We combine experimental and simulation studies to demonstrate that this deformation is governed by the polarizability and molecular size and shape of the gases, and that the stepped adsorption behavior is defined by the packing arrangement of the guest inside the host.</abstract><cop>United States</cop><pub>American Chemical Society</pub><pmid>26288051</pmid><doi>10.1021/jz300292y</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0001-9517-8132</orcidid><orcidid>https://orcid.org/0000-0001-9535-057X</orcidid></addata></record>
fulltext	fulltext
identifier	ISSN: 1948-7185
ispartof	The journal of physical chemistry letters, 2012-05, Vol.3 (9), p.1159-1164
issn	1948-7185 1948-7185
language	eng
recordid	cdi_hal_primary_oai_HAL_hal_02124970v1
source	American Chemical Society Journals
subjects	Catalysis Chemical Sciences Environmental Engineering Environmental Sciences Material chemistry Surfaces, Interfaces, Porous Materials, and Catalysis
title	Understanding Gas-Induced Structural Deformation of ZIF-8
url	https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-30T07%3A00%3A41IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_hal_p&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Understanding%20Gas-Induced%20Structural%20Deformation%20of%20ZIF-8&rft.jtitle=The%20journal%20of%20physical%20chemistry%20letters&rft.au=Ania,%20Conchi%20O&rft.date=2012-05-03&rft.volume=3&rft.issue=9&rft.spage=1159&rft.epage=1164&rft.pages=1159-1164&rft.issn=1948-7185&rft.eissn=1948-7185&rft_id=info:doi/10.1021/jz300292y&rft_dat=%3Cproquest_hal_p%3E1715659285%3C/proquest_hal_p%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1715659285&rft_id=info:pmid/26288051&rfr_iscdi=true