Interaction of (3-Aminopropyl)triethoxysilane With Late Ar-N 2 Afterglow: Application to Nanoparticles Synthesis
From results of in situ FTIR absorption and optical emission spectroscopy, the interaction of (3‐aminopropyl)triethoxysilane (APTES) with late Ar-N2 afterglow is shown to occur mainly with N atoms. They react preferentially with carbon from CHx groups in the precursor, leading to the synthesis of CN...
Gespeichert in:
| Veröffentlicht in: | Plasma processes and polymers 2016, Vol.13 (7), p.698-710 |
|---|---|
| Hauptverfasser: | , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 710 |
|---|---|
| container_issue | 7 |
| container_start_page | 698 |
| container_title | Plasma processes and polymers |
| container_volume | 13 |
| creator | Gueye, Magamou Gries, Thomas Noel, Cédric Migot-Choux, Sylvie Bulou, Simon Lecoq, Elodie Choquet, Patrick Belmonte, Thierry |
| description | From results of in situ FTIR absorption and optical emission spectroscopy, the interaction of (3‐aminopropyl)triethoxysilane (APTES) with late Ar-N2 afterglow is shown to occur mainly with N atoms. They react preferentially with carbon from CHx groups in the precursor, leading to the synthesis of CN bonds. No production of NH radical is observed, demonstrating the lack of direct reaction between active nitrogen and APTES. The -NH2 group is not affected by the afterglow. One of the C-C bonds of the propylamine group in the APTES is likely broken. These nanoparticles present secondary amides due to reactions with active nitrogen. They are amorphous and react in air to produce a salt. |
| doi_str_mv | 10.1002/ppap.201500201 |
| format | Article |
| fullrecord | <record><control><sourceid>hal</sourceid><recordid>TN_cdi_hal_primary_oai_HAL_hal_02113596v1</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>oai_HAL_hal_02113596v1</sourcerecordid><originalsourceid>FETCH-LOGICAL-c791-42cac3a6302efdc30b1ef911a5db0615438cc4cebbcaf9200c7155e8486052d83</originalsourceid><addsrcrecordid>eNo9jD1PwzAURS0EEqWwMnukQ8p7dpwmbFEFtFJUBioxRi-OQ4zS2EosIP-e8iGme--R7mHsGmGJAOLWe_JLAaiOA_CEzTBBEaVpkp3-dwXn7GIc3wAkqBRmzG_7YAbSwbqeu4bfyCg_2N75wfmpW4TBmtC6z2m0HfWGv9jQ8oKC4fkQ7bjgeXO8v3bu447n3ndW048pOL6jo4WGYHVnRv489aE1ox0v2VlD3Wiu_nLO9g_3-_UmKp4et-u8iPQqwygWmrSkRIIwTa0lVGiaDJFUXUGCKpap1rE2VaWpyQSAXqFSJo3TBJSoUzlni19tS13pB3ugYSod2XKTF-U3A4EoVZa8o_wCB3pegw</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Interaction of (3-Aminopropyl)triethoxysilane With Late Ar-N 2 Afterglow: Application to Nanoparticles Synthesis</title><source>Wiley Online Library All Journals</source><creator>Gueye, Magamou ; Gries, Thomas ; Noel, Cédric ; Migot-Choux, Sylvie ; Bulou, Simon ; Lecoq, Elodie ; Choquet, Patrick ; Belmonte, Thierry</creator><creatorcontrib>Gueye, Magamou ; Gries, Thomas ; Noel, Cédric ; Migot-Choux, Sylvie ; Bulou, Simon ; Lecoq, Elodie ; Choquet, Patrick ; Belmonte, Thierry</creatorcontrib><description>From results of in situ FTIR absorption and optical emission spectroscopy, the interaction of (3‐aminopropyl)triethoxysilane (APTES) with late Ar-N2 afterglow is shown to occur mainly with N atoms. They react preferentially with carbon from CHx groups in the precursor, leading to the synthesis of CN bonds. No production of NH radical is observed, demonstrating the lack of direct reaction between active nitrogen and APTES. The -NH2 group is not affected by the afterglow. One of the C-C bonds of the propylamine group in the APTES is likely broken. These nanoparticles present secondary amides due to reactions with active nitrogen. They are amorphous and react in air to produce a salt.</description><identifier>ISSN: 1612-8850</identifier><identifier>EISSN: 1612-8869</identifier><identifier>DOI: 10.1002/ppap.201500201</identifier><language>eng</language><publisher>Wiley-VCH Verlag</publisher><subject>Chemical Sciences ; Engineering Sciences ; Other ; Plasmas</subject><ispartof>Plasma processes and polymers, 2016, Vol.13 (7), p.698-710</ispartof><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c791-42cac3a6302efdc30b1ef911a5db0615438cc4cebbcaf9200c7155e8486052d83</citedby><orcidid>0000-0002-8572-7676 ; 0000-0003-4601-2675 ; 0000-0001-8651-1423</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,780,784,885,4024,27923,27924,27925</link.rule.ids><backlink>$$Uhttps://hal.science/hal-02113596$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Gueye, Magamou</creatorcontrib><creatorcontrib>Gries, Thomas</creatorcontrib><creatorcontrib>Noel, Cédric</creatorcontrib><creatorcontrib>Migot-Choux, Sylvie</creatorcontrib><creatorcontrib>Bulou, Simon</creatorcontrib><creatorcontrib>Lecoq, Elodie</creatorcontrib><creatorcontrib>Choquet, Patrick</creatorcontrib><creatorcontrib>Belmonte, Thierry</creatorcontrib><title>Interaction of (3-Aminopropyl)triethoxysilane With Late Ar-N 2 Afterglow: Application to Nanoparticles Synthesis</title><title>Plasma processes and polymers</title><description>From results of in situ FTIR absorption and optical emission spectroscopy, the interaction of (3‐aminopropyl)triethoxysilane (APTES) with late Ar-N2 afterglow is shown to occur mainly with N atoms. They react preferentially with carbon from CHx groups in the precursor, leading to the synthesis of CN bonds. No production of NH radical is observed, demonstrating the lack of direct reaction between active nitrogen and APTES. The -NH2 group is not affected by the afterglow. One of the C-C bonds of the propylamine group in the APTES is likely broken. These nanoparticles present secondary amides due to reactions with active nitrogen. They are amorphous and react in air to produce a salt.</description><subject>Chemical Sciences</subject><subject>Engineering Sciences</subject><subject>Other</subject><subject>Plasmas</subject><issn>1612-8850</issn><issn>1612-8869</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNo9jD1PwzAURS0EEqWwMnukQ8p7dpwmbFEFtFJUBioxRi-OQ4zS2EosIP-e8iGme--R7mHsGmGJAOLWe_JLAaiOA_CEzTBBEaVpkp3-dwXn7GIc3wAkqBRmzG_7YAbSwbqeu4bfyCg_2N75wfmpW4TBmtC6z2m0HfWGv9jQ8oKC4fkQ7bjgeXO8v3bu447n3ndW048pOL6jo4WGYHVnRv489aE1ox0v2VlD3Wiu_nLO9g_3-_UmKp4et-u8iPQqwygWmrSkRIIwTa0lVGiaDJFUXUGCKpap1rE2VaWpyQSAXqFSJo3TBJSoUzlni19tS13pB3ugYSod2XKTF-U3A4EoVZa8o_wCB3pegw</recordid><startdate>2016</startdate><enddate>2016</enddate><creator>Gueye, Magamou</creator><creator>Gries, Thomas</creator><creator>Noel, Cédric</creator><creator>Migot-Choux, Sylvie</creator><creator>Bulou, Simon</creator><creator>Lecoq, Elodie</creator><creator>Choquet, Patrick</creator><creator>Belmonte, Thierry</creator><general>Wiley-VCH Verlag</general><scope>1XC</scope><scope>VOOES</scope><orcidid>https://orcid.org/0000-0002-8572-7676</orcidid><orcidid>https://orcid.org/0000-0003-4601-2675</orcidid><orcidid>https://orcid.org/0000-0001-8651-1423</orcidid></search><sort><creationdate>2016</creationdate><title>Interaction of (3-Aminopropyl)triethoxysilane With Late Ar-N 2 Afterglow: Application to Nanoparticles Synthesis</title><author>Gueye, Magamou ; Gries, Thomas ; Noel, Cédric ; Migot-Choux, Sylvie ; Bulou, Simon ; Lecoq, Elodie ; Choquet, Patrick ; Belmonte, Thierry</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c791-42cac3a6302efdc30b1ef911a5db0615438cc4cebbcaf9200c7155e8486052d83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Chemical Sciences</topic><topic>Engineering Sciences</topic><topic>Other</topic><topic>Plasmas</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gueye, Magamou</creatorcontrib><creatorcontrib>Gries, Thomas</creatorcontrib><creatorcontrib>Noel, Cédric</creatorcontrib><creatorcontrib>Migot-Choux, Sylvie</creatorcontrib><creatorcontrib>Bulou, Simon</creatorcontrib><creatorcontrib>Lecoq, Elodie</creatorcontrib><creatorcontrib>Choquet, Patrick</creatorcontrib><creatorcontrib>Belmonte, Thierry</creatorcontrib><collection>Hyper Article en Ligne (HAL)</collection><collection>Hyper Article en Ligne (HAL) (Open Access)</collection><jtitle>Plasma processes and polymers</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gueye, Magamou</au><au>Gries, Thomas</au><au>Noel, Cédric</au><au>Migot-Choux, Sylvie</au><au>Bulou, Simon</au><au>Lecoq, Elodie</au><au>Choquet, Patrick</au><au>Belmonte, Thierry</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Interaction of (3-Aminopropyl)triethoxysilane With Late Ar-N 2 Afterglow: Application to Nanoparticles Synthesis</atitle><jtitle>Plasma processes and polymers</jtitle><date>2016</date><risdate>2016</risdate><volume>13</volume><issue>7</issue><spage>698</spage><epage>710</epage><pages>698-710</pages><issn>1612-8850</issn><eissn>1612-8869</eissn><abstract>From results of in situ FTIR absorption and optical emission spectroscopy, the interaction of (3‐aminopropyl)triethoxysilane (APTES) with late Ar-N2 afterglow is shown to occur mainly with N atoms. They react preferentially with carbon from CHx groups in the precursor, leading to the synthesis of CN bonds. No production of NH radical is observed, demonstrating the lack of direct reaction between active nitrogen and APTES. The -NH2 group is not affected by the afterglow. One of the C-C bonds of the propylamine group in the APTES is likely broken. These nanoparticles present secondary amides due to reactions with active nitrogen. They are amorphous and react in air to produce a salt.</abstract><pub>Wiley-VCH Verlag</pub><doi>10.1002/ppap.201500201</doi><tpages>13</tpages><orcidid>https://orcid.org/0000-0002-8572-7676</orcidid><orcidid>https://orcid.org/0000-0003-4601-2675</orcidid><orcidid>https://orcid.org/0000-0001-8651-1423</orcidid><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1612-8850 |
| ispartof | Plasma processes and polymers, 2016, Vol.13 (7), p.698-710 |
| issn | 1612-8850 1612-8869 |
| language | eng |
| recordid | cdi_hal_primary_oai_HAL_hal_02113596v1 |
| source | Wiley Online Library All Journals |
| subjects | Chemical Sciences Engineering Sciences Other Plasmas |
| title | Interaction of (3-Aminopropyl)triethoxysilane With Late Ar-N 2 Afterglow: Application to Nanoparticles Synthesis |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-07T07%3A32%3A00IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-hal&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Interaction%20of%20(3-Aminopropyl)triethoxysilane%20With%20Late%20Ar-N%202%20Afterglow:%20Application%20to%20Nanoparticles%20Synthesis&rft.jtitle=Plasma%20processes%20and%20polymers&rft.au=Gueye,%20Magamou&rft.date=2016&rft.volume=13&rft.issue=7&rft.spage=698&rft.epage=710&rft.pages=698-710&rft.issn=1612-8850&rft.eissn=1612-8869&rft_id=info:doi/10.1002/ppap.201500201&rft_dat=%3Chal%3Eoai_HAL_hal_02113596v1%3C/hal%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |