Stereoselectivity Switch in the Trapping of Polar Organometallics with Andersen’s ReagentAccess to Highly Stereoenriched Transformable Biphenyls

The trapping of racemic polar carbometallic species with (−)-menthyl (S S)-p-toluenesulfinate (Andersen’s reagent) typically proceeds with a very low level of resolution. In this paper, we describe a strategy that allows access to highly atropo-enriched and functionalizable biphenyls by means of And...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Journal of organic chemistry 2018-08, Vol.83 (15), p.7751-7761
Hauptverfasser:	Bortoluzzi, Julien, Jha, Vishwajeet, Levitre, Guillaume, Fer, Mickaël J, Berreur, Jordan, Masson, Géraldine, Panossian, Armen, Leroux, Frédéric R
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical Sciences Organic chemistry
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!