Asymmetric Total Synthesis of Distaminolyne A and Revision of Its Absolute Configuration

The first total synthesis of a marine derived polyacetylene, distaminolyne A, and its enantiomer were achieved from the commercially available undec-10-en-1-ol. A key proline-catalyzed asymmetric α-aminooxylation of an aldehyde intermediate was used to introduce the chiral center en route to the ena...

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Veröffentlicht in:	Organic letters 2017-02, Vol.19 (3), p.714-717
Hauptverfasser:	Sun, Dong-Yu, Han, Guan-Ying, Gong, Jing-Xu, Nay, Bastien, Li, Xu-Wen, Guo, Yue-Wei
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical Sciences Organic chemistry
Online-Zugang:	Volltext
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