Extension to the Silyl-Tethered Radical Cyclization: Cyclohex-2-en-1-oxy Vinyl Silanes in Stereoselective Radical Addition/Cyclization Cascades

A novel radical cascade reaction of xanthates with 1-[(vinyldimethylsilyl)­oxy]­cyclohex-2-enes is developed. Due to the steric and electronic differentiation of the two olefinic functions, exclusive regioselectivity and high stereoselectivity of the addition–cyclization are observed. Several method...

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Veröffentlicht in:	Organic letters 2017-04, Vol.19 (7), p.1866-1869
Hauptverfasser:	Mikhaylov, Andrey A, Zard, Samir Z
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical Sciences Organic chemistry
Online-Zugang:	Volltext
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