A direct route to polythiophenes displaying lateral substituents: Easy one-step synthesis and polymerization of thiophene monomers substituted by a dimethylenecarboxylate (CH2CH2COOR) appendage on the 3-position

Thiophene monomers displaying a dimethylenecarboxylate (CH2CH2COOR) substituent on the 3‐position of the aromatic ring can be easily obtained and in one step from the electrochemically induced reaction of 3‐bromothiophene with the corresponding acrylate (CH2CHCOOR). The synthesis of the ethyl ester...

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Veröffentlicht in:	Journal of polymer science. Part A, Polymer chemistry Polymer chemistry, 2012-03, Vol.50 (5), p.900-911
Hauptverfasser:	Sengmany, Stéphane, Ceballos, Claire, Belhadj, Romain, Cachet-Vivier, Christine, Gall, Erwan Le, Brissault, Blandine, Penelle, Jacques, Léonel, Eric
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences Chemical Sciences conducting polymers electrochemistry Exact sciences and technology Material chemistry monomer synthesis Organic chemistry Organic polymers Physicochemistry of polymers Polymerization Polymers Polymers and radiations Polymers with particular properties Preparation, kinetics, thermodynamics, mechanism and catalysts step-growth polymerizations substituted polythiophenes
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