Peroxide detected in imidazolium-based ionic liquids and approaches for reducing its presence in aqueous and non-aqueous environments
Imidazolium-based ionic liquids were discovered to contain micromolar (M) quantities of a peroxide species. A general approach using catalase (aqueous solution) or a salenmanganese complex (neat IL) for reducing the presence of the peroxide species is described herein. Peroxide species appearing in...
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Veröffentlicht in: | RSC advances 2015-01, Vol.5 (3), p.23715-23718 |
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creator | Carter, Julie L. L Santini, Catherine C Blum, Loc J Doumche, Bastien |
description | Imidazolium-based ionic liquids were discovered to contain micromolar (M) quantities of a peroxide species. A general approach using catalase (aqueous solution) or a salenmanganese complex (neat IL) for reducing the presence of the peroxide species is described herein.
Peroxide species appearing in imidazolium-based ionic liquids could be removed by salenmanganese complexes or the enzyme catalase. |
doi_str_mv | 10.1039/c5ra01080b |
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Peroxide species appearing in imidazolium-based ionic liquids could be removed by salenmanganese complexes or the enzyme catalase.</description><subject>Aqueous solutions</subject><subject>Biochemistry, Molecular Biology</subject><subject>Catalase</subject><subject>Chemical Sciences</subject><subject>Ionic liquids</subject><subject>Life Sciences</subject><subject>Peroxides</subject><issn>2046-2069</issn><issn>2046-2069</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNp9kU1r3DAQhk1IIMtmL7kH1FtTcCNZltY-bpbmAxZaSnsWY2mcVbElR7JD03v-d-w6SXvKXOaDZ15meJPklNHPjPLyQosAlNGCVgfJIqO5TDMqy8P_6uNkFeMvOoYULJNskTx9w-B_W4PEYI-6R0OsI7a1Bv74xg5tWkGcht5ZTRp7P1gTCThDoOuCB73HSGofSEAzaOvuiO0j6QJGdBonLbgf0A_zjvMufe3RPdjgXYuujyfJUQ1NxNVLXiY_r7782N6ku6_Xt9vNLtU8l32aGYlGlLJYY1WPD9RCFHme16yqQUvQmBXcaM2FKFEawU0pywqrHEAgcCP5MjmfdffQqC7YFsKj8mDVzWanphnNaLGma_rARvbjzI5vjifHXrU2amwacNP9iq05Hckim2Q_zagOPsaA9Zs2o2qyRm3F981fay5H-MMMh6jfuH_Wqc7UI3P2HsOfAWfKmO0</recordid><startdate>20150101</startdate><enddate>20150101</enddate><creator>Carter, Julie L. L</creator><creator>Santini, Catherine C</creator><creator>Blum, Loc J</creator><creator>Doumche, Bastien</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0003-3458-1029</orcidid></search><sort><creationdate>20150101</creationdate><title>Peroxide detected in imidazolium-based ionic liquids and approaches for reducing its presence in aqueous and non-aqueous environments</title><author>Carter, Julie L. L ; Santini, Catherine C ; Blum, Loc J ; Doumche, Bastien</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c346t-2d6ed59687ebf512f558444f1bfac6ace283dcc3559e6d53d969beb4aa5ea3d63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Aqueous solutions</topic><topic>Biochemistry, Molecular Biology</topic><topic>Catalase</topic><topic>Chemical Sciences</topic><topic>Ionic liquids</topic><topic>Life Sciences</topic><topic>Peroxides</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Carter, Julie L. L</creatorcontrib><creatorcontrib>Santini, Catherine C</creatorcontrib><creatorcontrib>Blum, Loc J</creatorcontrib><creatorcontrib>Doumche, Bastien</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>RSC advances</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Carter, Julie L. L</au><au>Santini, Catherine C</au><au>Blum, Loc J</au><au>Doumche, Bastien</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Peroxide detected in imidazolium-based ionic liquids and approaches for reducing its presence in aqueous and non-aqueous environments</atitle><jtitle>RSC advances</jtitle><date>2015-01-01</date><risdate>2015</risdate><volume>5</volume><issue>3</issue><spage>23715</spage><epage>23718</epage><pages>23715-23718</pages><issn>2046-2069</issn><eissn>2046-2069</eissn><abstract>Imidazolium-based ionic liquids were discovered to contain micromolar (M) quantities of a peroxide species. A general approach using catalase (aqueous solution) or a salenmanganese complex (neat IL) for reducing the presence of the peroxide species is described herein.
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subjects | Aqueous solutions Biochemistry, Molecular Biology Catalase Chemical Sciences Ionic liquids Life Sciences Peroxides |
title | Peroxide detected in imidazolium-based ionic liquids and approaches for reducing its presence in aqueous and non-aqueous environments |
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