The interaction between mass transfer effects and morphology in heterogeneous olefin polymerization

A new mathematical model describing the build-up and relaxation of elastic tensions inside growing particles during the heterogeneous polymerization of olefins is described. Mass transfer resistance can lead to spatial variation in the expansion rate of polymer which creates tension. This can cause...

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Veröffentlicht in:	Chemical engineering science 2001, Vol.56 (13), p.4015-4028
Hauptverfasser:	Kittilsen, Pål, McKenna, Timothy F., Svendsen, Hallvard, Jakobsen, Hugo A., Fredriksen, Siw B.
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences Chemical Sciences Exact sciences and technology Industrial polymers. Preparations Mass transfer Morphology Olefin Particle formation Polymer industry, paints, wood Polymerization Polymers Single particle modeling Technology of polymers Thermoplastics
Online-Zugang:	Volltext
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