Comparison of three labeled silica nanoparticles used as tracers in transport experiments in porous media. Part I: Syntheses and characterizations
The synthesis and the characterization of three kinds of labeled silica nanoparticles were performed. Three different labeling strategies were investigated: fluorescent organic molecule (FITC) embedded in silica matrix, heavy metal core (Ag(0)) and radioactive core (110mAg) surrounded by a silica sh...
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| Veröffentlicht in: | Environmental pollution (1987) 2014-01, Vol.184, p.605-612 |
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| creator | Vitorge, Elsa Szenknect, Stéphanie Martins, Jean M.F. Barthès, Véronique Auger, Aurélien Renard, Oliver Gaudet, Jean-Paul |
| description | The synthesis and the characterization of three kinds of labeled silica nanoparticles were performed. Three different labeling strategies were investigated: fluorescent organic molecule (FITC) embedded in silica matrix, heavy metal core (Ag(0)) and radioactive core (110mAg) surrounded by a silica shell. The main properties and the suitability of each kind of labeled nanoparticle in terms of size, surface properties, stability, detection limits, and cost were determined and compared regarding its use for transport studies. Fluorescent labeling was found the most convenient and the cheapest, but the best detection limits were reached with chemical (Ag(0)) and radio-labeled (110mAg) nanoparticles, which also allowed nondestructive quantifications. This work showed that the choice of labeled nanoparticles as surrogates of natural colloids or manufactured nanoparticles strongly depends on the experimental conditions, especially the concentration and amount required, the composition of the effluent, and the timescale of the experiment.
[Display omitted]
•Labeled silica nanotracers were synthesized using the sol–gel method.•The nanotracers were detectable by fluorescence, analytical chemistry or radioactivity measurement.•The nanotracers were characterized regarding their size, surface properties, stability, and detection limits.•The suitability of these nanotracers was evaluated in experiments dealing with colloid transport in natural porous media.
How to synthesize and choose suitable tracers for engineered silica nanoparticles or natural colloids? |
| doi_str_mv | 10.1016/j.envpol.2013.07.031 |
| format | Article |
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[Display omitted]
•Labeled silica nanotracers were synthesized using the sol–gel method.•The nanotracers were detectable by fluorescence, analytical chemistry or radioactivity measurement.•The nanotracers were characterized regarding their size, surface properties, stability, and detection limits.•The suitability of these nanotracers was evaluated in experiments dealing with colloid transport in natural porous media.
How to synthesize and choose suitable tracers for engineered silica nanoparticles or natural colloids?</description><identifier>ISSN: 0269-7491</identifier><identifier>EISSN: 1873-6424</identifier><identifier>DOI: 10.1016/j.envpol.2013.07.031</identifier><identifier>PMID: 23948261</identifier><identifier>CODEN: ENVPAF</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Colloids - chemistry ; Concentration (composition) ; Continental interfaces, environment ; Core–shell nanoparticles ; Earth Sciences ; Earth, ocean, space ; Effluents ; Environmental Monitoring - methods ; Exact sciences and technology ; Fluorescent labeling ; Geochemistry ; Hydrogeology ; Hydrology ; Hydrology. Hydrogeology ; Marking ; Nanoparticles ; Nanoparticles - analysis ; Nanoparticles - chemistry ; Porosity ; Radioactive labeling ; Sciences of the Universe ; Silica colloids ; Silicon dioxide ; Silicon Dioxide - analysis ; Silicon Dioxide - chemistry ; Strategy ; Surface Properties ; Tracers ; Transport ; Water Pollutants, Chemical - analysis ; Water Pollutants, Chemical - chemistry</subject><ispartof>Environmental pollution (1987), 2014-01, Vol.184, p.605-612</ispartof><rights>2013 Elsevier Ltd</rights><rights>2015 INIST-CNRS</rights><rights>Copyright © 2013 Elsevier Ltd. All rights reserved.</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c558t-ba9912a3eeebd6eb2edddc8dab183d72be6ee90c6b210d6d0941f5bb71124b133</citedby><cites>FETCH-LOGICAL-c558t-ba9912a3eeebd6eb2edddc8dab183d72be6ee90c6b210d6d0941f5bb71124b133</cites><orcidid>0000-0003-3691-3621 ; 0000-0003-0314-1311</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0269749113004004$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>230,314,776,780,881,3536,4009,27902,27903,27904,65309</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=27994513$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/23948261$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://hal.science/hal-02048829$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Vitorge, Elsa</creatorcontrib><creatorcontrib>Szenknect, Stéphanie</creatorcontrib><creatorcontrib>Martins, Jean M.F.</creatorcontrib><creatorcontrib>Barthès, Véronique</creatorcontrib><creatorcontrib>Auger, Aurélien</creatorcontrib><creatorcontrib>Renard, Oliver</creatorcontrib><creatorcontrib>Gaudet, Jean-Paul</creatorcontrib><title>Comparison of three labeled silica nanoparticles used as tracers in transport experiments in porous media. Part I: Syntheses and characterizations</title><title>Environmental pollution (1987)</title><addtitle>Environ Pollut</addtitle><description>The synthesis and the characterization of three kinds of labeled silica nanoparticles were performed. Three different labeling strategies were investigated: fluorescent organic molecule (FITC) embedded in silica matrix, heavy metal core (Ag(0)) and radioactive core (110mAg) surrounded by a silica shell. The main properties and the suitability of each kind of labeled nanoparticle in terms of size, surface properties, stability, detection limits, and cost were determined and compared regarding its use for transport studies. Fluorescent labeling was found the most convenient and the cheapest, but the best detection limits were reached with chemical (Ag(0)) and radio-labeled (110mAg) nanoparticles, which also allowed nondestructive quantifications. This work showed that the choice of labeled nanoparticles as surrogates of natural colloids or manufactured nanoparticles strongly depends on the experimental conditions, especially the concentration and amount required, the composition of the effluent, and the timescale of the experiment.
[Display omitted]
•Labeled silica nanotracers were synthesized using the sol–gel method.•The nanotracers were detectable by fluorescence, analytical chemistry or radioactivity measurement.•The nanotracers were characterized regarding their size, surface properties, stability, and detection limits.•The suitability of these nanotracers was evaluated in experiments dealing with colloid transport in natural porous media.
How to synthesize and choose suitable tracers for engineered silica nanoparticles or natural colloids?</description><subject>Colloids - chemistry</subject><subject>Concentration (composition)</subject><subject>Continental interfaces, environment</subject><subject>Core–shell nanoparticles</subject><subject>Earth Sciences</subject><subject>Earth, ocean, space</subject><subject>Effluents</subject><subject>Environmental Monitoring - methods</subject><subject>Exact sciences and technology</subject><subject>Fluorescent labeling</subject><subject>Geochemistry</subject><subject>Hydrogeology</subject><subject>Hydrology</subject><subject>Hydrology. Hydrogeology</subject><subject>Marking</subject><subject>Nanoparticles</subject><subject>Nanoparticles - analysis</subject><subject>Nanoparticles - chemistry</subject><subject>Porosity</subject><subject>Radioactive labeling</subject><subject>Sciences of the Universe</subject><subject>Silica colloids</subject><subject>Silicon dioxide</subject><subject>Silicon Dioxide - analysis</subject><subject>Silicon Dioxide - chemistry</subject><subject>Strategy</subject><subject>Surface Properties</subject><subject>Tracers</subject><subject>Transport</subject><subject>Water Pollutants, Chemical - analysis</subject><subject>Water Pollutants, Chemical - chemistry</subject><issn>0269-7491</issn><issn>1873-6424</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqNks1uEzEUhUcIREPhDRDyBgkWGfw3todFpSoqtFIkkIC15bFvFEcTe7CdiPIYPHGdJpQdsLLl-93rY5_TNC8Jbgkm4t2mhbCf4thSTFiLZYsZedTMiJJsLjjlj5sZpqKfS96Ts-ZZzhuMMWeMPW3OKOu5ooLMml-LuJ1M8jkGFFeorBMAGs0AIziU_eitQcGEWJni7QgZ7XKtmIxKMhZSRj4ctiFPMRUEPyZIfguh3BfqWdxltAXnTYs-1xno5j36chvKGnKdZYJDdm3qpFLbfpriY8jPmycrM2Z4cVrPm28frr4urufLTx9vFpfLue06VeaD6XtCDQOAwQkYKDjnrHJmIIo5SQcQAD22YqAEO-Fwz8mqGwZJCOUDYey8eXucuzajnqpqk251NF5fXy714QxTzJWi_Z5U9s2RnVL8voNc9NZnC-NoAtQXaiJUJxWXXP4HKgXrSMfFv1EuiFJcyYMAfkRtijknWD0oJlgf8qA3-pgHfciDxlLXPNS2V6cbdkN14aHpdwAq8PoEmGzNuKpOWp__cLLveXf_WRdHDqojew9JZ-sh2OpsAlu0i_7vSu4AquzXxQ</recordid><startdate>201401</startdate><enddate>201401</enddate><creator>Vitorge, Elsa</creator><creator>Szenknect, Stéphanie</creator><creator>Martins, Jean M.F.</creator><creator>Barthès, Véronique</creator><creator>Auger, Aurélien</creator><creator>Renard, Oliver</creator><creator>Gaudet, Jean-Paul</creator><general>Elsevier Ltd</general><general>Elsevier</general><scope>IQODW</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7X8</scope><scope>7ST</scope><scope>7TV</scope><scope>7U7</scope><scope>C1K</scope><scope>SOI</scope><scope>7SU</scope><scope>7U5</scope><scope>8FD</scope><scope>FR3</scope><scope>KR7</scope><scope>L7M</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0003-3691-3621</orcidid><orcidid>https://orcid.org/0000-0003-0314-1311</orcidid></search><sort><creationdate>201401</creationdate><title>Comparison of three labeled silica nanoparticles used as tracers in transport experiments in porous media. Part I: Syntheses and characterizations</title><author>Vitorge, Elsa ; Szenknect, Stéphanie ; Martins, Jean M.F. ; Barthès, Véronique ; Auger, Aurélien ; Renard, Oliver ; Gaudet, Jean-Paul</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c558t-ba9912a3eeebd6eb2edddc8dab183d72be6ee90c6b210d6d0941f5bb71124b133</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Colloids - chemistry</topic><topic>Concentration (composition)</topic><topic>Continental interfaces, environment</topic><topic>Core–shell nanoparticles</topic><topic>Earth Sciences</topic><topic>Earth, ocean, space</topic><topic>Effluents</topic><topic>Environmental Monitoring - methods</topic><topic>Exact sciences and technology</topic><topic>Fluorescent labeling</topic><topic>Geochemistry</topic><topic>Hydrogeology</topic><topic>Hydrology</topic><topic>Hydrology. Hydrogeology</topic><topic>Marking</topic><topic>Nanoparticles</topic><topic>Nanoparticles - analysis</topic><topic>Nanoparticles - chemistry</topic><topic>Porosity</topic><topic>Radioactive labeling</topic><topic>Sciences of the Universe</topic><topic>Silica colloids</topic><topic>Silicon dioxide</topic><topic>Silicon Dioxide - analysis</topic><topic>Silicon Dioxide - chemistry</topic><topic>Strategy</topic><topic>Surface Properties</topic><topic>Tracers</topic><topic>Transport</topic><topic>Water Pollutants, Chemical - analysis</topic><topic>Water Pollutants, Chemical - chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Vitorge, Elsa</creatorcontrib><creatorcontrib>Szenknect, Stéphanie</creatorcontrib><creatorcontrib>Martins, Jean M.F.</creatorcontrib><creatorcontrib>Barthès, Véronique</creatorcontrib><creatorcontrib>Auger, Aurélien</creatorcontrib><creatorcontrib>Renard, Oliver</creatorcontrib><creatorcontrib>Gaudet, Jean-Paul</creatorcontrib><collection>Pascal-Francis</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>MEDLINE - Academic</collection><collection>Environment Abstracts</collection><collection>Pollution Abstracts</collection><collection>Toxicology Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Environment Abstracts</collection><collection>Environmental Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Engineering Research Database</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Environmental pollution (1987)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Vitorge, Elsa</au><au>Szenknect, Stéphanie</au><au>Martins, Jean M.F.</au><au>Barthès, Véronique</au><au>Auger, Aurélien</au><au>Renard, Oliver</au><au>Gaudet, Jean-Paul</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Comparison of three labeled silica nanoparticles used as tracers in transport experiments in porous media. Part I: Syntheses and characterizations</atitle><jtitle>Environmental pollution (1987)</jtitle><addtitle>Environ Pollut</addtitle><date>2014-01</date><risdate>2014</risdate><volume>184</volume><spage>605</spage><epage>612</epage><pages>605-612</pages><issn>0269-7491</issn><eissn>1873-6424</eissn><coden>ENVPAF</coden><abstract>The synthesis and the characterization of three kinds of labeled silica nanoparticles were performed. Three different labeling strategies were investigated: fluorescent organic molecule (FITC) embedded in silica matrix, heavy metal core (Ag(0)) and radioactive core (110mAg) surrounded by a silica shell. The main properties and the suitability of each kind of labeled nanoparticle in terms of size, surface properties, stability, detection limits, and cost were determined and compared regarding its use for transport studies. Fluorescent labeling was found the most convenient and the cheapest, but the best detection limits were reached with chemical (Ag(0)) and radio-labeled (110mAg) nanoparticles, which also allowed nondestructive quantifications. This work showed that the choice of labeled nanoparticles as surrogates of natural colloids or manufactured nanoparticles strongly depends on the experimental conditions, especially the concentration and amount required, the composition of the effluent, and the timescale of the experiment.
[Display omitted]
•Labeled silica nanotracers were synthesized using the sol–gel method.•The nanotracers were detectable by fluorescence, analytical chemistry or radioactivity measurement.•The nanotracers were characterized regarding their size, surface properties, stability, and detection limits.•The suitability of these nanotracers was evaluated in experiments dealing with colloid transport in natural porous media.
How to synthesize and choose suitable tracers for engineered silica nanoparticles or natural colloids?</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><pmid>23948261</pmid><doi>10.1016/j.envpol.2013.07.031</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0003-3691-3621</orcidid><orcidid>https://orcid.org/0000-0003-0314-1311</orcidid></addata></record> |
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| identifier | ISSN: 0269-7491 |
| ispartof | Environmental pollution (1987), 2014-01, Vol.184, p.605-612 |
| issn | 0269-7491 1873-6424 |
| language | eng |
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| source | MEDLINE; Elsevier ScienceDirect Journals |
| subjects | Colloids - chemistry Concentration (composition) Continental interfaces, environment Core–shell nanoparticles Earth Sciences Earth, ocean, space Effluents Environmental Monitoring - methods Exact sciences and technology Fluorescent labeling Geochemistry Hydrogeology Hydrology Hydrology. Hydrogeology Marking Nanoparticles Nanoparticles - analysis Nanoparticles - chemistry Porosity Radioactive labeling Sciences of the Universe Silica colloids Silicon dioxide Silicon Dioxide - analysis Silicon Dioxide - chemistry Strategy Surface Properties Tracers Transport Water Pollutants, Chemical - analysis Water Pollutants, Chemical - chemistry |
| title | Comparison of three labeled silica nanoparticles used as tracers in transport experiments in porous media. Part I: Syntheses and characterizations |
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