An experimental and modeling study of n-octanol combustion
This study presents the first investigation on the combustion chemistry of n-octanol, a long chain alcohol. Ignition delay times were determined experimentally in a high-pressure shock tube, and stable species concentration profiles were obtained in a jet stirred reactor for a range of initial condi...
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Veröffentlicht in: | Proceedings of the Combustion Institute 2015-01, Vol.35 (1), p.419-427 |
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container_title | Proceedings of the Combustion Institute |
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creator | Cai, Liming Uygun, Yasar Togbé, Casimir Pitsch, Heinz Olivier, Herbert Dagaut, Philippe Sarathy, S. Mani |
description | This study presents the first investigation on the combustion chemistry of n-octanol, a long chain alcohol. Ignition delay times were determined experimentally in a high-pressure shock tube, and stable species concentration profiles were obtained in a jet stirred reactor for a range of initial conditions. A detailed kinetic model was developed to describe the oxidation of n-octanol at both low and high temperatures, and the model shows good agreement with the present dataset. The fuel’s combustion characteristics are compared to those of n-alkanes and to short chain alcohols to illustrate the effects of the hydroxyl moiety and the carbon chain length on important combustion properties. Finally, the results are discussed in detail. |
doi_str_mv | 10.1016/j.proci.2014.05.088 |
format | Article |
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Finally, the results are discussed in detail.</description><subject>Alcohols</subject><subject>Carbon</subject><subject>Chains</subject><subject>Chemical mechanism</subject><subject>Chemical Sciences</subject><subject>Combustion</subject><subject>Combustion chemistry</subject><subject>Delay</subject><subject>Engineering Sciences</subject><subject>High pressure shock tube</subject><subject>Initial conditions</subject><subject>Jet stirred reactor</subject><subject>Mathematical models</subject><subject>n-Octanol</subject><subject>or physical chemistry</subject><subject>Reactive fluid environment</subject><subject>Reactors</subject><subject>Theoretical and</subject><issn>1540-7489</issn><issn>1873-2704</issn><issn>1540-7489</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNp9kM1OwzAQhCMEEuXnCbjkCIeEtRPbKRKHqgKKVIkLnC3X3oCrxC5xUtG3xyGII6ddrb4Z7UySXBHICRB-u813ndc2p0DKHFgOVXWUzEgliowKKI_jzkrIRFnNT5OzELYAhYCCzZK7hUvxa4edbdH1qkmVM2nrDTbWvaehH8wh9XXqMq975XyTat9uhtBb7y6Sk1o1AS9_53ny9vjwulxl65en5-VinelSiD7TtOaiooRVjHKqgJjaMEo1RyW0FnNFaKUpbgxnc16VgEJpJEIZMOVGC1OcJzeT74dq5C4-qrqD9MrK1WItxxuMsTnwPYns9cTGPj4HDL1sbdDYNMqhH4IkXIh5hAsW0WJCdedD6LD-8yYgx1blVv60Kkd7CUzGVqPqflJhTLy32MmgLTqNxnaoe2m8_Vf_DUZDgIY</recordid><startdate>20150101</startdate><enddate>20150101</enddate><creator>Cai, Liming</creator><creator>Uygun, Yasar</creator><creator>Togbé, Casimir</creator><creator>Pitsch, Heinz</creator><creator>Olivier, Herbert</creator><creator>Dagaut, Philippe</creator><creator>Sarathy, S. 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language | eng |
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source | ScienceDirect Journals (5 years ago - present) |
subjects | Alcohols Carbon Chains Chemical mechanism Chemical Sciences Combustion Combustion chemistry Delay Engineering Sciences High pressure shock tube Initial conditions Jet stirred reactor Mathematical models n-Octanol or physical chemistry Reactive fluid environment Reactors Theoretical and |
title | An experimental and modeling study of n-octanol combustion |
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