An experimental and modeling study of n-octanol combustion

This study presents the first investigation on the combustion chemistry of n-octanol, a long chain alcohol. Ignition delay times were determined experimentally in a high-pressure shock tube, and stable species concentration profiles were obtained in a jet stirred reactor for a range of initial condi...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Proceedings of the Combustion Institute 2015-01, Vol.35 (1), p.419-427
Hauptverfasser: Cai, Liming, Uygun, Yasar, Togbé, Casimir, Pitsch, Heinz, Olivier, Herbert, Dagaut, Philippe, Sarathy, S. Mani
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 427
container_issue 1
container_start_page 419
container_title Proceedings of the Combustion Institute
container_volume 35
creator Cai, Liming
Uygun, Yasar
Togbé, Casimir
Pitsch, Heinz
Olivier, Herbert
Dagaut, Philippe
Sarathy, S. Mani
description This study presents the first investigation on the combustion chemistry of n-octanol, a long chain alcohol. Ignition delay times were determined experimentally in a high-pressure shock tube, and stable species concentration profiles were obtained in a jet stirred reactor for a range of initial conditions. A detailed kinetic model was developed to describe the oxidation of n-octanol at both low and high temperatures, and the model shows good agreement with the present dataset. The fuel’s combustion characteristics are compared to those of n-alkanes and to short chain alcohols to illustrate the effects of the hydroxyl moiety and the carbon chain length on important combustion properties. Finally, the results are discussed in detail.
doi_str_mv 10.1016/j.proci.2014.05.088
format Article
fullrecord <record><control><sourceid>proquest_hal_p</sourceid><recordid>TN_cdi_hal_primary_oai_HAL_hal_02014606v1</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S1540748914000911</els_id><sourcerecordid>1677914635</sourcerecordid><originalsourceid>FETCH-LOGICAL-c477t-c2f67821585262a01dfd522c6ea7cc79a128c2ebd6596840e7ace17ad0d4bc7d3</originalsourceid><addsrcrecordid>eNp9kM1OwzAQhCMEEuXnCbjkCIeEtRPbKRKHqgKKVIkLnC3X3oCrxC5xUtG3xyGII6ddrb4Z7UySXBHICRB-u813ndc2p0DKHFgOVXWUzEgliowKKI_jzkrIRFnNT5OzELYAhYCCzZK7hUvxa4edbdH1qkmVM2nrDTbWvaehH8wh9XXqMq975XyTat9uhtBb7y6Sk1o1AS9_53ny9vjwulxl65en5-VinelSiD7TtOaiooRVjHKqgJjaMEo1RyW0FnNFaKUpbgxnc16VgEJpJEIZMOVGC1OcJzeT74dq5C4-qrqD9MrK1WItxxuMsTnwPYns9cTGPj4HDL1sbdDYNMqhH4IkXIh5hAsW0WJCdedD6LD-8yYgx1blVv60Kkd7CUzGVqPqflJhTLy32MmgLTqNxnaoe2m8_Vf_DUZDgIY</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1677914635</pqid></control><display><type>article</type><title>An experimental and modeling study of n-octanol combustion</title><source>ScienceDirect Journals (5 years ago - present)</source><creator>Cai, Liming ; Uygun, Yasar ; Togbé, Casimir ; Pitsch, Heinz ; Olivier, Herbert ; Dagaut, Philippe ; Sarathy, S. Mani</creator><creatorcontrib>Cai, Liming ; Uygun, Yasar ; Togbé, Casimir ; Pitsch, Heinz ; Olivier, Herbert ; Dagaut, Philippe ; Sarathy, S. Mani</creatorcontrib><description>This study presents the first investigation on the combustion chemistry of n-octanol, a long chain alcohol. Ignition delay times were determined experimentally in a high-pressure shock tube, and stable species concentration profiles were obtained in a jet stirred reactor for a range of initial conditions. A detailed kinetic model was developed to describe the oxidation of n-octanol at both low and high temperatures, and the model shows good agreement with the present dataset. The fuel’s combustion characteristics are compared to those of n-alkanes and to short chain alcohols to illustrate the effects of the hydroxyl moiety and the carbon chain length on important combustion properties. Finally, the results are discussed in detail.</description><identifier>ISSN: 1540-7489</identifier><identifier>EISSN: 1873-2704</identifier><identifier>EISSN: 1540-7489</identifier><identifier>DOI: 10.1016/j.proci.2014.05.088</identifier><language>eng</language><publisher>Elsevier Inc</publisher><subject>Alcohols ; Carbon ; Chains ; Chemical mechanism ; Chemical Sciences ; Combustion ; Combustion chemistry ; Delay ; Engineering Sciences ; High pressure shock tube ; Initial conditions ; Jet stirred reactor ; Mathematical models ; n-Octanol ; or physical chemistry ; Reactive fluid environment ; Reactors ; Theoretical and</subject><ispartof>Proceedings of the Combustion Institute, 2015-01, Vol.35 (1), p.419-427</ispartof><rights>2014 The Combustion Institute</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c477t-c2f67821585262a01dfd522c6ea7cc79a128c2ebd6596840e7ace17ad0d4bc7d3</citedby><cites>FETCH-LOGICAL-c477t-c2f67821585262a01dfd522c6ea7cc79a128c2ebd6596840e7ace17ad0d4bc7d3</cites><orcidid>0000-0002-3975-6206 ; 0000-0003-4825-3288</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.proci.2014.05.088$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>230,314,780,784,885,3549,27923,27924,45994</link.rule.ids><backlink>$$Uhttps://hal.science/hal-02014606$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Cai, Liming</creatorcontrib><creatorcontrib>Uygun, Yasar</creatorcontrib><creatorcontrib>Togbé, Casimir</creatorcontrib><creatorcontrib>Pitsch, Heinz</creatorcontrib><creatorcontrib>Olivier, Herbert</creatorcontrib><creatorcontrib>Dagaut, Philippe</creatorcontrib><creatorcontrib>Sarathy, S. Mani</creatorcontrib><title>An experimental and modeling study of n-octanol combustion</title><title>Proceedings of the Combustion Institute</title><description>This study presents the first investigation on the combustion chemistry of n-octanol, a long chain alcohol. Ignition delay times were determined experimentally in a high-pressure shock tube, and stable species concentration profiles were obtained in a jet stirred reactor for a range of initial conditions. A detailed kinetic model was developed to describe the oxidation of n-octanol at both low and high temperatures, and the model shows good agreement with the present dataset. The fuel’s combustion characteristics are compared to those of n-alkanes and to short chain alcohols to illustrate the effects of the hydroxyl moiety and the carbon chain length on important combustion properties. Finally, the results are discussed in detail.</description><subject>Alcohols</subject><subject>Carbon</subject><subject>Chains</subject><subject>Chemical mechanism</subject><subject>Chemical Sciences</subject><subject>Combustion</subject><subject>Combustion chemistry</subject><subject>Delay</subject><subject>Engineering Sciences</subject><subject>High pressure shock tube</subject><subject>Initial conditions</subject><subject>Jet stirred reactor</subject><subject>Mathematical models</subject><subject>n-Octanol</subject><subject>or physical chemistry</subject><subject>Reactive fluid environment</subject><subject>Reactors</subject><subject>Theoretical and</subject><issn>1540-7489</issn><issn>1873-2704</issn><issn>1540-7489</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNp9kM1OwzAQhCMEEuXnCbjkCIeEtRPbKRKHqgKKVIkLnC3X3oCrxC5xUtG3xyGII6ddrb4Z7UySXBHICRB-u813ndc2p0DKHFgOVXWUzEgliowKKI_jzkrIRFnNT5OzELYAhYCCzZK7hUvxa4edbdH1qkmVM2nrDTbWvaehH8wh9XXqMq975XyTat9uhtBb7y6Sk1o1AS9_53ny9vjwulxl65en5-VinelSiD7TtOaiooRVjHKqgJjaMEo1RyW0FnNFaKUpbgxnc16VgEJpJEIZMOVGC1OcJzeT74dq5C4-qrqD9MrK1WItxxuMsTnwPYns9cTGPj4HDL1sbdDYNMqhH4IkXIh5hAsW0WJCdedD6LD-8yYgx1blVv60Kkd7CUzGVqPqflJhTLy32MmgLTqNxnaoe2m8_Vf_DUZDgIY</recordid><startdate>20150101</startdate><enddate>20150101</enddate><creator>Cai, Liming</creator><creator>Uygun, Yasar</creator><creator>Togbé, Casimir</creator><creator>Pitsch, Heinz</creator><creator>Olivier, Herbert</creator><creator>Dagaut, Philippe</creator><creator>Sarathy, S. Mani</creator><general>Elsevier Inc</general><general>Elsevier</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>H8D</scope><scope>JG9</scope><scope>L7M</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0002-3975-6206</orcidid><orcidid>https://orcid.org/0000-0003-4825-3288</orcidid></search><sort><creationdate>20150101</creationdate><title>An experimental and modeling study of n-octanol combustion</title><author>Cai, Liming ; Uygun, Yasar ; Togbé, Casimir ; Pitsch, Heinz ; Olivier, Herbert ; Dagaut, Philippe ; Sarathy, S. Mani</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c477t-c2f67821585262a01dfd522c6ea7cc79a128c2ebd6596840e7ace17ad0d4bc7d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Alcohols</topic><topic>Carbon</topic><topic>Chains</topic><topic>Chemical mechanism</topic><topic>Chemical Sciences</topic><topic>Combustion</topic><topic>Combustion chemistry</topic><topic>Delay</topic><topic>Engineering Sciences</topic><topic>High pressure shock tube</topic><topic>Initial conditions</topic><topic>Jet stirred reactor</topic><topic>Mathematical models</topic><topic>n-Octanol</topic><topic>or physical chemistry</topic><topic>Reactive fluid environment</topic><topic>Reactors</topic><topic>Theoretical and</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Cai, Liming</creatorcontrib><creatorcontrib>Uygun, Yasar</creatorcontrib><creatorcontrib>Togbé, Casimir</creatorcontrib><creatorcontrib>Pitsch, Heinz</creatorcontrib><creatorcontrib>Olivier, Herbert</creatorcontrib><creatorcontrib>Dagaut, Philippe</creatorcontrib><creatorcontrib>Sarathy, S. Mani</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Aerospace Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Proceedings of the Combustion Institute</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Cai, Liming</au><au>Uygun, Yasar</au><au>Togbé, Casimir</au><au>Pitsch, Heinz</au><au>Olivier, Herbert</au><au>Dagaut, Philippe</au><au>Sarathy, S. Mani</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>An experimental and modeling study of n-octanol combustion</atitle><jtitle>Proceedings of the Combustion Institute</jtitle><date>2015-01-01</date><risdate>2015</risdate><volume>35</volume><issue>1</issue><spage>419</spage><epage>427</epage><pages>419-427</pages><issn>1540-7489</issn><eissn>1873-2704</eissn><eissn>1540-7489</eissn><abstract>This study presents the first investigation on the combustion chemistry of n-octanol, a long chain alcohol. Ignition delay times were determined experimentally in a high-pressure shock tube, and stable species concentration profiles were obtained in a jet stirred reactor for a range of initial conditions. A detailed kinetic model was developed to describe the oxidation of n-octanol at both low and high temperatures, and the model shows good agreement with the present dataset. The fuel’s combustion characteristics are compared to those of n-alkanes and to short chain alcohols to illustrate the effects of the hydroxyl moiety and the carbon chain length on important combustion properties. Finally, the results are discussed in detail.</abstract><pub>Elsevier Inc</pub><doi>10.1016/j.proci.2014.05.088</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0002-3975-6206</orcidid><orcidid>https://orcid.org/0000-0003-4825-3288</orcidid></addata></record>
fulltext fulltext
identifier ISSN: 1540-7489
ispartof Proceedings of the Combustion Institute, 2015-01, Vol.35 (1), p.419-427
issn 1540-7489
1873-2704
1540-7489
language eng
recordid cdi_hal_primary_oai_HAL_hal_02014606v1
source ScienceDirect Journals (5 years ago - present)
subjects Alcohols
Carbon
Chains
Chemical mechanism
Chemical Sciences
Combustion
Combustion chemistry
Delay
Engineering Sciences
High pressure shock tube
Initial conditions
Jet stirred reactor
Mathematical models
n-Octanol
or physical chemistry
Reactive fluid environment
Reactors
Theoretical and
title An experimental and modeling study of n-octanol combustion
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-08T16%3A36%3A30IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_hal_p&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=An%20experimental%20and%20modeling%20study%20of%20n-octanol%20combustion&rft.jtitle=Proceedings%20of%20the%20Combustion%20Institute&rft.au=Cai,%20Liming&rft.date=2015-01-01&rft.volume=35&rft.issue=1&rft.spage=419&rft.epage=427&rft.pages=419-427&rft.issn=1540-7489&rft.eissn=1873-2704&rft_id=info:doi/10.1016/j.proci.2014.05.088&rft_dat=%3Cproquest_hal_p%3E1677914635%3C/proquest_hal_p%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1677914635&rft_id=info:pmid/&rft_els_id=S1540748914000911&rfr_iscdi=true