Cobalt-Catalyzed Oxidative Homocoupling of Arylzinc Species
Abstract A novel procedure for the synthesis of functionalized symmetrical biaryl compounds is described. The reaction proceeds via the oxidative homocoupling of arylzinc species formed by cobalt catalysis in the presence of air or p -benzoquinone depending on the nature of the functional group.
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| Veröffentlicht in: | Synthesis (Stuttgart) 2016-10, Vol.48 (19), p.3352-3356 |
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| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | Abstract
A novel procedure for the synthesis of functionalized symmetrical biaryl compounds is described. The reaction proceeds via the oxidative homocoupling of arylzinc species formed by cobalt catalysis in the presence of air or
p
-benzoquinone depending on the nature of the functional group. |
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| ISSN: | 0039-7881 1437-210X |
| DOI: | 10.1055/s-0035-1562488 |