Microwave Synthesis and Up-Conversion Properties of SHG-Active α‑(La, Er)(IO3)3 Nanocrystals

Microwave Synthesis and Up-Conversion Properties of SHG-Active α‑(La, Er)(IO3)3 Nanocrystals

Pure α-La­(IO3)3 and α-La0.85­Er0.15(IO3)3 nanocrystals were synthesized by a microwave-assisted hydrothermal method leading to a reaction yield of 87 ± 4%. Electron microscopy and dynamic light scattering characterizations provide evidence for the formation of nanocrystals with an average size of 4...

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Veröffentlicht in:Inorganic chemistry 2019-01, Vol.58 (2), p.1647-1656
Hauptverfasser: Regny, Sylvain, Riporto, Jérémy, Mugnier, Yannick, Le Dantec, Ronan, Kodjikian, Stéphanie, Pairis, Sébastien, Gautier-Luneau, Isabelle, Dantelle, Géraldine
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container_issue 2
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container_title Inorganic chemistry
container_volume 58
creator Regny, Sylvain
Riporto, Jérémy
Mugnier, Yannick
Le Dantec, Ronan
Kodjikian, Stéphanie
Pairis, Sébastien
Gautier-Luneau, Isabelle
Dantelle, Géraldine
description Pure α-La­(IO3)3 and α-La0.85­Er0.15(IO3)3 nanocrystals were synthesized by a microwave-assisted hydrothermal method leading to a reaction yield of 87 ± 4%. Electron microscopy and dynamic light scattering characterizations provide evidence for the formation of nanocrystals with an average size of 45 ± 10 nm for α-La­(IO3)3 and 55 ± 10 nm for α-La0.85Er0.15­(IO3)3. When dispersed in ethylene glycol, the nanocrystal suspensions exhibit second-harmonic generation under near-infrared excitations at 800 and 980 nm whereas additional photoluminescence by up-conversion is simultaneously observed in the case of α-La0.85Er0.15­(IO3)3 nanocrystals. Quantitative assessments of the second-harmonic generation efficiency from second-harmonic scattering experiments at 1064 nm result in relatively high ⟨d⟩ coefficients measured at 8.2 ± 2.0 and 8.0 ± 2.0 pm V–1 for α-La­(IO3)3 and α-La0.85Er0.15­(IO3)3, respectively. The relative intensity between second-harmonic generation and photoluminescence is discussed following the excitation wavelength.
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title Microwave Synthesis and Up-Conversion Properties of SHG-Active α‑(La, Er)(IO3)3 Nanocrystals
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