Hyperfine‐Interaction‐Driven Suppression of Quantum Tunneling at Zero Field in a Holmium(III) Single‐Ion Magnet
An extremely rare non‐Kramers holmium(III) single‐ion magnet (SIM) is reported to be stabilized in the pentagonal‐bipyramidal geometry by a phosphine oxide with a high energy barrier of 237(4) cm−1. The suppression of the quantum tunneling of magnetization (QTM) at zero field and the hyperfine struc...
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| Veröffentlicht in: | Angewandte Chemie International Edition 2017-04, Vol.56 (18), p.4996-5000 |
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| creator | Chen, Yan‐Cong Liu, Jun‐Liang Wernsdorfer, Wolfgang Liu, Dan Chibotaru, Liviu F. Chen, Xiao‐Ming Tong, Ming‐Liang |
| description | An extremely rare non‐Kramers holmium(III) single‐ion magnet (SIM) is reported to be stabilized in the pentagonal‐bipyramidal geometry by a phosphine oxide with a high energy barrier of 237(4) cm−1. The suppression of the quantum tunneling of magnetization (QTM) at zero field and the hyperfine structures originating from field‐induced QTMs can be observed even from the field‐dependent alternating‐current magnetic susceptibility in addition to single‐crystal hysteresis loops. These dramatic dynamics were attributed to the combination of the favorable crystal‐field environment and the hyperfine interactions arising from 165Ho (I=7/2) with a natural abundance of 100 %.
An extremely rare non‐Kramers holmium(III) single‐ion magnet is reported. The suppression of the quantum tunneling of magnetization at zero field and the hyperfine structures were observed in AC magnetic susceptibility measurements, and were attributed to the combination of a favorable crystal‐field environment and the hyperfine interactions arising from 165Ho (I=7/2) with a natural abundance of 100 %. |
| doi_str_mv | 10.1002/anie.201701480 |
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An extremely rare non‐Kramers holmium(III) single‐ion magnet is reported. The suppression of the quantum tunneling of magnetization at zero field and the hyperfine structures were observed in AC magnetic susceptibility measurements, and were attributed to the combination of a favorable crystal‐field environment and the hyperfine interactions arising from 165Ho (I=7/2) with a natural abundance of 100 %.</description><edition>International ed. in English</edition><identifier>ISSN: 1433-7851</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/anie.201701480</identifier><identifier>PMID: 28295930</identifier><identifier>CODEN: ACIEAY</identifier><language>eng</language><publisher>Germany: Wiley Subscription Services, Inc</publisher><subject>Abundance ; Chemical Sciences ; Energy ; Environments ; Holmium ; hyperfine interactions ; Hysteresis ; Hysteresis loops ; lanthanides ; Magnetic permeability ; magnetic properties ; Magnetic susceptibility ; Magnetization ; Phosphine ; Phosphine oxide ; Quantum tunnelling ; Single crystals ; single-molecule magnets</subject><ispartof>Angewandte Chemie International Edition, 2017-04, Vol.56 (18), p.4996-5000</ispartof><rights>2017 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><rights>2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c5780-1a740c93c8525ef42efa908a40fe772fed2a95ac352b6a5f262eb72d5f606e83</citedby><cites>FETCH-LOGICAL-c5780-1a740c93c8525ef42efa908a40fe772fed2a95ac352b6a5f262eb72d5f606e83</cites><orcidid>0000-0002-5811-6300 ; 0000-0003-4725-0798</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fanie.201701480$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fanie.201701480$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>230,314,777,781,882,1412,27905,27906,45555,45556</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/28295930$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://hal.science/hal-01978462$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Chen, Yan‐Cong</creatorcontrib><creatorcontrib>Liu, Jun‐Liang</creatorcontrib><creatorcontrib>Wernsdorfer, Wolfgang</creatorcontrib><creatorcontrib>Liu, Dan</creatorcontrib><creatorcontrib>Chibotaru, Liviu F.</creatorcontrib><creatorcontrib>Chen, Xiao‐Ming</creatorcontrib><creatorcontrib>Tong, Ming‐Liang</creatorcontrib><title>Hyperfine‐Interaction‐Driven Suppression of Quantum Tunneling at Zero Field in a Holmium(III) Single‐Ion Magnet</title><title>Angewandte Chemie International Edition</title><addtitle>Angew Chem Int Ed Engl</addtitle><description>An extremely rare non‐Kramers holmium(III) single‐ion magnet (SIM) is reported to be stabilized in the pentagonal‐bipyramidal geometry by a phosphine oxide with a high energy barrier of 237(4) cm−1. The suppression of the quantum tunneling of magnetization (QTM) at zero field and the hyperfine structures originating from field‐induced QTMs can be observed even from the field‐dependent alternating‐current magnetic susceptibility in addition to single‐crystal hysteresis loops. These dramatic dynamics were attributed to the combination of the favorable crystal‐field environment and the hyperfine interactions arising from 165Ho (I=7/2) with a natural abundance of 100 %.
An extremely rare non‐Kramers holmium(III) single‐ion magnet is reported. The suppression of the quantum tunneling of magnetization at zero field and the hyperfine structures were observed in AC magnetic susceptibility measurements, and were attributed to the combination of a favorable crystal‐field environment and the hyperfine interactions arising from 165Ho (I=7/2) with a natural abundance of 100 %.</description><subject>Abundance</subject><subject>Chemical Sciences</subject><subject>Energy</subject><subject>Environments</subject><subject>Holmium</subject><subject>hyperfine interactions</subject><subject>Hysteresis</subject><subject>Hysteresis loops</subject><subject>lanthanides</subject><subject>Magnetic permeability</subject><subject>magnetic properties</subject><subject>Magnetic susceptibility</subject><subject>Magnetization</subject><subject>Phosphine</subject><subject>Phosphine oxide</subject><subject>Quantum tunnelling</subject><subject>Single crystals</subject><subject>single-molecule magnets</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNqFkcuO0zAUhiMEYi6wZYkssZlZpPgSx86ymguNVEBoumJjuenx4JHjBDse1B2PMM_Ik-DSoUgswBvbR58_HZ-_KF4RPCMY07faW5hRTAQmlcRPimPCKSmZEOxpPleMlUJyclScxHiXeSlx_bw4opI2vGH4uEiL7QjBWA8_vj-0foKgu8kOPt8ug70Hj27SOAaIMRfRYNCnpP2UerRK3oOz_hbpCX2GMKBrC26DrEcaLQbX29SftW17jm4y5H7ps-G9vvUwvSieGe0ivHzcT4vV9dXqYlEuP75rL-bLsuNC4pJoUeGuYZ3klIOpKBjdYKkrbEAIamBDdcN1xzhd15obWlNYC7rhpsY1SHZanO-1X7RTY7C9Dls1aKsW86Xa1TBphKxqek8ye7ZnxzB8TRAn1dvYgXPaw5CiIlLkSXJW0Yy--Qu9G1Lw-SOKNJgLVgvO_knJvPL8651rtqe6MMQYwBz6JFjtEla7hNUh4fzg9aM2rXvYHPDfkWag2QPfrIPtf3Rq_qG9-iP_CaHHszI</recordid><startdate>20170424</startdate><enddate>20170424</enddate><creator>Chen, Yan‐Cong</creator><creator>Liu, Jun‐Liang</creator><creator>Wernsdorfer, Wolfgang</creator><creator>Liu, Dan</creator><creator>Chibotaru, Liviu F.</creator><creator>Chen, Xiao‐Ming</creator><creator>Tong, Ming‐Liang</creator><general>Wiley Subscription Services, Inc</general><general>Wiley-VCH Verlag</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7TM</scope><scope>K9.</scope><scope>7X8</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0002-5811-6300</orcidid><orcidid>https://orcid.org/0000-0003-4725-0798</orcidid></search><sort><creationdate>20170424</creationdate><title>Hyperfine‐Interaction‐Driven Suppression of Quantum Tunneling at Zero Field in a Holmium(III) Single‐Ion Magnet</title><author>Chen, Yan‐Cong ; Liu, Jun‐Liang ; Wernsdorfer, Wolfgang ; Liu, Dan ; Chibotaru, Liviu F. ; Chen, Xiao‐Ming ; Tong, Ming‐Liang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c5780-1a740c93c8525ef42efa908a40fe772fed2a95ac352b6a5f262eb72d5f606e83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Abundance</topic><topic>Chemical Sciences</topic><topic>Energy</topic><topic>Environments</topic><topic>Holmium</topic><topic>hyperfine interactions</topic><topic>Hysteresis</topic><topic>Hysteresis loops</topic><topic>lanthanides</topic><topic>Magnetic permeability</topic><topic>magnetic properties</topic><topic>Magnetic susceptibility</topic><topic>Magnetization</topic><topic>Phosphine</topic><topic>Phosphine oxide</topic><topic>Quantum tunnelling</topic><topic>Single crystals</topic><topic>single-molecule magnets</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Chen, Yan‐Cong</creatorcontrib><creatorcontrib>Liu, Jun‐Liang</creatorcontrib><creatorcontrib>Wernsdorfer, Wolfgang</creatorcontrib><creatorcontrib>Liu, Dan</creatorcontrib><creatorcontrib>Chibotaru, Liviu F.</creatorcontrib><creatorcontrib>Chen, Xiao‐Ming</creatorcontrib><creatorcontrib>Tong, Ming‐Liang</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Nucleic Acids Abstracts</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>MEDLINE - Academic</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Angewandte Chemie International Edition</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chen, Yan‐Cong</au><au>Liu, Jun‐Liang</au><au>Wernsdorfer, Wolfgang</au><au>Liu, Dan</au><au>Chibotaru, Liviu F.</au><au>Chen, Xiao‐Ming</au><au>Tong, Ming‐Liang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Hyperfine‐Interaction‐Driven Suppression of Quantum Tunneling at Zero Field in a Holmium(III) Single‐Ion Magnet</atitle><jtitle>Angewandte Chemie International Edition</jtitle><addtitle>Angew Chem Int Ed Engl</addtitle><date>2017-04-24</date><risdate>2017</risdate><volume>56</volume><issue>18</issue><spage>4996</spage><epage>5000</epage><pages>4996-5000</pages><issn>1433-7851</issn><eissn>1521-3773</eissn><coden>ACIEAY</coden><abstract>An extremely rare non‐Kramers holmium(III) single‐ion magnet (SIM) is reported to be stabilized in the pentagonal‐bipyramidal geometry by a phosphine oxide with a high energy barrier of 237(4) cm−1. The suppression of the quantum tunneling of magnetization (QTM) at zero field and the hyperfine structures originating from field‐induced QTMs can be observed even from the field‐dependent alternating‐current magnetic susceptibility in addition to single‐crystal hysteresis loops. These dramatic dynamics were attributed to the combination of the favorable crystal‐field environment and the hyperfine interactions arising from 165Ho (I=7/2) with a natural abundance of 100 %.
An extremely rare non‐Kramers holmium(III) single‐ion magnet is reported. The suppression of the quantum tunneling of magnetization at zero field and the hyperfine structures were observed in AC magnetic susceptibility measurements, and were attributed to the combination of a favorable crystal‐field environment and the hyperfine interactions arising from 165Ho (I=7/2) with a natural abundance of 100 %.</abstract><cop>Germany</cop><pub>Wiley Subscription Services, Inc</pub><pmid>28295930</pmid><doi>10.1002/anie.201701480</doi><tpages>5</tpages><edition>International ed. in English</edition><orcidid>https://orcid.org/0000-0002-5811-6300</orcidid><orcidid>https://orcid.org/0000-0003-4725-0798</orcidid><oa>free_for_read</oa></addata></record> |
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| subjects | Abundance Chemical Sciences Energy Environments Holmium hyperfine interactions Hysteresis Hysteresis loops lanthanides Magnetic permeability magnetic properties Magnetic susceptibility Magnetization Phosphine Phosphine oxide Quantum tunnelling Single crystals single-molecule magnets |
| title | Hyperfine‐Interaction‐Driven Suppression of Quantum Tunneling at Zero Field in a Holmium(III) Single‐Ion Magnet |
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