Characterization of berkelium(III) dipicolinate and borate compounds in solution and the solid state

Berkelium is positioned at a crucial location in the actinide series between the inherently stable half-filled 5f(7) configuration of curium and the abrupt transition in chemical behavior created by the onset of a metastable divalent state that starts at californium. However, the mere 320-day half-l...

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Veröffentlicht in:	Science (American Association for the Advancement of Science) 2016-08, Vol.353 (6302), p.aaf3762-aaf3762
Hauptverfasser:	Silver, Mark A, Cary, Samantha K, Johnson, Jason A, Baumbach, Ryan E, Arico, Alexandra A, Luckey, Morgan, Urban, Matthew, Wang, Jamie C, Polinski, Matthew J, Chemey, Alexander, Liu, Guokui, Chen, Kuan-Wen, Van Cleve, Shelley M, Marsh, Matthew L, Eaton, Teresa M, van de Burgt, Lambertus J, Gray, Ashley L, Hobart, David E, Hanson, Kenneth, Maron, Laurent, Gendron, Frédéric, Autschbach, Jochen, Speldrich, Manfred, Kögerler, Paul, Yang, Ping, Braley, Jenifer, Albrecht-Schmitt, Thomas E
Format:	Artikel
Sprache:	eng
Schlagworte:	Berkelium Borates Californium Chemical elements Chemical Sciences Chemistry Coordination Coordination compounds Crystal structure Electronics Half life Isotopes Literary Devices Organic Chemistry Oxidation Physical properties Single crystals Solid state Spin-orbit interactions Topology
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