Characterization of berkelium(III) dipicolinate and borate compounds in solution and the solid state
Berkelium is positioned at a crucial location in the actinide series between the inherently stable half-filled 5f(7) configuration of curium and the abrupt transition in chemical behavior created by the onset of a metastable divalent state that starts at californium. However, the mere 320-day half-l...
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| Veröffentlicht in: | Science (American Association for the Advancement of Science) 2016-08, Vol.353 (6302), p.aaf3762-aaf3762 |
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| creator | Silver, Mark A Cary, Samantha K Johnson, Jason A Baumbach, Ryan E Arico, Alexandra A Luckey, Morgan Urban, Matthew Wang, Jamie C Polinski, Matthew J Chemey, Alexander Liu, Guokui Chen, Kuan-Wen Van Cleve, Shelley M Marsh, Matthew L Eaton, Teresa M van de Burgt, Lambertus J Gray, Ashley L Hobart, David E Hanson, Kenneth Maron, Laurent Gendron, Frédéric Autschbach, Jochen Speldrich, Manfred Kögerler, Paul Yang, Ping Braley, Jenifer Albrecht-Schmitt, Thomas E |
| description | Berkelium is positioned at a crucial location in the actinide series between the inherently stable half-filled 5f(7) configuration of curium and the abrupt transition in chemical behavior created by the onset of a metastable divalent state that starts at californium. However, the mere 320-day half-life of berkelium's only available isotope, (249)Bk, has hindered in-depth studies of the element's coordination chemistry. Herein, we report the synthesis and detailed solid-state and solution-phase characterization of a berkelium coordination complex, Bk(III)tris(dipicolinate), as well as a chemically distinct Bk(III) borate material for comparison. We demonstrate that berkelium's complexation is analogous to that of californium. However, from a range of spectroscopic techniques and quantum mechanical calculations, it is clear that spin-orbit coupling contributes significantly to berkelium's multiconfigurational ground state. |
| doi_str_mv | 10.1126/science.aaf3762 |
| format | Article |
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However, the mere 320-day half-life of berkelium's only available isotope, (249)Bk, has hindered in-depth studies of the element's coordination chemistry. Herein, we report the synthesis and detailed solid-state and solution-phase characterization of a berkelium coordination complex, Bk(III)tris(dipicolinate), as well as a chemically distinct Bk(III) borate material for comparison. We demonstrate that berkelium's complexation is analogous to that of californium. However, from a range of spectroscopic techniques and quantum mechanical calculations, it is clear that spin-orbit coupling contributes significantly to berkelium's multiconfigurational ground state.</description><identifier>ISSN: 0036-8075</identifier><identifier>EISSN: 1095-9203</identifier><identifier>DOI: 10.1126/science.aaf3762</identifier><identifier>PMID: 27563098</identifier><identifier>CODEN: SCIEAS</identifier><language>eng</language><publisher>United States: The American Association for the Advancement of Science</publisher><subject>Berkelium ; Borates ; Californium ; Chemical elements ; Chemical Sciences ; Chemistry ; Coordination ; Coordination compounds ; Crystal structure ; Electronics ; Half life ; Isotopes ; Literary Devices ; Organic Chemistry ; Oxidation ; Physical properties ; Single crystals ; Solid state ; Spin-orbit interactions ; Topology</subject><ispartof>Science (American Association for the Advancement of Science), 2016-08, Vol.353 (6302), p.aaf3762-aaf3762</ispartof><rights>Copyright © 2016, American Association for the Advancement of Science.</rights><rights>Copyright © 2016, American Association for the Advancement of Science</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c499t-dd86df6bc0202505b6f740bd2457737178074cec8c71e6ce7a554fc96ff3b68b3</citedby><cites>FETCH-LOGICAL-c499t-dd86df6bc0202505b6f740bd2457737178074cec8c71e6ce7a554fc96ff3b68b3</cites><orcidid>0000-0003-2653-8557</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,776,780,881,2871,2872,27901,27902</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/27563098$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://insa-toulouse.hal.science/hal-01968947$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Silver, Mark A</creatorcontrib><creatorcontrib>Cary, Samantha K</creatorcontrib><creatorcontrib>Johnson, Jason A</creatorcontrib><creatorcontrib>Baumbach, Ryan E</creatorcontrib><creatorcontrib>Arico, Alexandra A</creatorcontrib><creatorcontrib>Luckey, Morgan</creatorcontrib><creatorcontrib>Urban, Matthew</creatorcontrib><creatorcontrib>Wang, Jamie C</creatorcontrib><creatorcontrib>Polinski, Matthew J</creatorcontrib><creatorcontrib>Chemey, Alexander</creatorcontrib><creatorcontrib>Liu, Guokui</creatorcontrib><creatorcontrib>Chen, Kuan-Wen</creatorcontrib><creatorcontrib>Van Cleve, Shelley M</creatorcontrib><creatorcontrib>Marsh, Matthew L</creatorcontrib><creatorcontrib>Eaton, Teresa M</creatorcontrib><creatorcontrib>van de Burgt, Lambertus J</creatorcontrib><creatorcontrib>Gray, Ashley L</creatorcontrib><creatorcontrib>Hobart, David E</creatorcontrib><creatorcontrib>Hanson, Kenneth</creatorcontrib><creatorcontrib>Maron, Laurent</creatorcontrib><creatorcontrib>Gendron, Frédéric</creatorcontrib><creatorcontrib>Autschbach, Jochen</creatorcontrib><creatorcontrib>Speldrich, Manfred</creatorcontrib><creatorcontrib>Kögerler, Paul</creatorcontrib><creatorcontrib>Yang, Ping</creatorcontrib><creatorcontrib>Braley, Jenifer</creatorcontrib><creatorcontrib>Albrecht-Schmitt, Thomas E</creatorcontrib><title>Characterization of berkelium(III) dipicolinate and borate compounds in solution and the solid state</title><title>Science (American Association for the Advancement of Science)</title><addtitle>Science</addtitle><description>Berkelium is positioned at a crucial location in the actinide series between the inherently stable half-filled 5f(7) configuration of curium and the abrupt transition in chemical behavior created by the onset of a metastable divalent state that starts at californium. However, the mere 320-day half-life of berkelium's only available isotope, (249)Bk, has hindered in-depth studies of the element's coordination chemistry. Herein, we report the synthesis and detailed solid-state and solution-phase characterization of a berkelium coordination complex, Bk(III)tris(dipicolinate), as well as a chemically distinct Bk(III) borate material for comparison. We demonstrate that berkelium's complexation is analogous to that of californium. However, from a range of spectroscopic techniques and quantum mechanical calculations, it is clear that spin-orbit coupling contributes significantly to berkelium's multiconfigurational ground state.</description><subject>Berkelium</subject><subject>Borates</subject><subject>Californium</subject><subject>Chemical elements</subject><subject>Chemical Sciences</subject><subject>Chemistry</subject><subject>Coordination</subject><subject>Coordination compounds</subject><subject>Crystal structure</subject><subject>Electronics</subject><subject>Half life</subject><subject>Isotopes</subject><subject>Literary Devices</subject><subject>Organic Chemistry</subject><subject>Oxidation</subject><subject>Physical properties</subject><subject>Single crystals</subject><subject>Solid state</subject><subject>Spin-orbit 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state</title><author>Silver, Mark A ; Cary, Samantha K ; Johnson, Jason A ; Baumbach, Ryan E ; Arico, Alexandra A ; Luckey, Morgan ; Urban, Matthew ; Wang, Jamie C ; Polinski, Matthew J ; Chemey, Alexander ; Liu, Guokui ; Chen, Kuan-Wen ; Van Cleve, Shelley M ; Marsh, Matthew L ; Eaton, Teresa M ; van de Burgt, Lambertus J ; Gray, Ashley L ; Hobart, David E ; Hanson, Kenneth ; Maron, Laurent ; Gendron, Frédéric ; Autschbach, Jochen ; Speldrich, Manfred ; Kögerler, Paul ; Yang, Ping ; Braley, Jenifer ; Albrecht-Schmitt, Thomas E</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c499t-dd86df6bc0202505b6f740bd2457737178074cec8c71e6ce7a554fc96ff3b68b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Berkelium</topic><topic>Borates</topic><topic>Californium</topic><topic>Chemical elements</topic><topic>Chemical 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Manfred</au><au>Kögerler, Paul</au><au>Yang, Ping</au><au>Braley, Jenifer</au><au>Albrecht-Schmitt, Thomas E</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Characterization of berkelium(III) dipicolinate and borate compounds in solution and the solid state</atitle><jtitle>Science (American Association for the Advancement of Science)</jtitle><addtitle>Science</addtitle><date>2016-08-26</date><risdate>2016</risdate><volume>353</volume><issue>6302</issue><spage>aaf3762</spage><epage>aaf3762</epage><pages>aaf3762-aaf3762</pages><issn>0036-8075</issn><eissn>1095-9203</eissn><coden>SCIEAS</coden><abstract>Berkelium is positioned at a crucial location in the actinide series between the inherently stable half-filled 5f(7) configuration of curium and the abrupt transition in chemical behavior created by the onset of a metastable divalent state that starts at californium. However, the mere 320-day half-life of berkelium's only available isotope, (249)Bk, has hindered in-depth studies of the element's coordination chemistry. Herein, we report the synthesis and detailed solid-state and solution-phase characterization of a berkelium coordination complex, Bk(III)tris(dipicolinate), as well as a chemically distinct Bk(III) borate material for comparison. We demonstrate that berkelium's complexation is analogous to that of californium. However, from a range of spectroscopic techniques and quantum mechanical calculations, it is clear that spin-orbit coupling contributes significantly to berkelium's multiconfigurational ground state.</abstract><cop>United States</cop><pub>The American Association for the Advancement of Science</pub><pmid>27563098</pmid><doi>10.1126/science.aaf3762</doi><orcidid>https://orcid.org/0000-0003-2653-8557</orcidid><oa>free_for_read</oa></addata></record> |
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| source | American Association for the Advancement of Science; Jstor Complete Legacy |
| subjects | Berkelium Borates Californium Chemical elements Chemical Sciences Chemistry Coordination Coordination compounds Crystal structure Electronics Half life Isotopes Literary Devices Organic Chemistry Oxidation Physical properties Single crystals Solid state Spin-orbit interactions Topology |
| title | Characterization of berkelium(III) dipicolinate and borate compounds in solution and the solid state |
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