Synthesis, crystal structure, spectroscopic, and photoreactive properties of a ruthenium(II)-mononitrosyl complex

The sizeable differences observed in the switching capabilities of two closely related ruthenium-nitrosyl complexes are investigated computationally by DFT, and are found to arise from the very different UV–visible spectra in the ruthenium-isonitrosyl metastable state. [Display omitted] A compound o...

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Veröffentlicht in:	Polyhedron 2016-11, Vol.119, p.350-358
Hauptverfasser:	Tassé, Marine, Mohammed, Hasan S., Sabourdy, Chloé, Mallet-Ladeira, Sonia, Lacroix, Pascal G., Malfant, Isabelle
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical Sciences Computational chemistry Coordination chemistry Molecular switch Nitric oxide NO release Ruthenium complexes
Online-Zugang:	Volltext
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