Synthesis of the H-cluster framework of iron-only hydrogenase

Fuel cells: iron is the new platinum In conventional hydrogen fuel cells the rapid interconversion of protons and electrons to hydrogen requires catalysis by expensive metals, usually platinum. In the living world enzymes catalyse this same reaction at extraordinary rates using abundant metals. Tard...

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Veröffentlicht in:	Nature 2005-02, Vol.433 (7026), p.610-613
Hauptverfasser:	Tard, Cédric, Liu, Xiaoming, Ibrahim, Saad K., Bruschi, Maurizio, Gioia, Luca De, Davies, Siân C., Yang, Xin, Wang, Lai-Sheng, Sawers, Gary, Pickett, Christopher J.
Format:	Artikel
Sprache:	eng
Schlagworte:	08 HYDROGEN Analytical, structural and metabolic biochemistry Binding Sites Biological and medical sciences BIOLOGY Biomimetic Materials - chemical synthesis Biomimetic Materials - chemistry Biotechnology CATALYSIS Chemical Sciences Chemical synthesis CHEMISTRY Clostridium - enzymology DESIGN Desulfovibrio desulfuricans - enzymology Electrochemistry environmental molecular sciences laboratory ENZYMES Enzymes and enzyme inhibitors Fuel cells Fundamental and applied biological sciences. Psychology Humanities and Social Sciences HYDROGEN Hydrogen - chemistry HYDROGEN PRODUCTION Hydrogenase - chemical synthesis Hydrogenase - chemistry HYDROGENASES Iron Iron - chemistry Iron-Sulfur Proteins - chemical synthesis Iron-Sulfur Proteins - chemistry letter Lyases Models, Molecular multidisciplinary NITROGEN FIXATION Other Oxidation-Reduction PROTONS Science Science (multidisciplinary) Structure-Activity Relationship Sulfur - chemistry SYNTHESIS
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