Coupling Raman spectroscopy and drop tensiometry for in situ monitoring of radical polymerization in a single monomer droplet
Two complementary analytical techniques, Raman spectroscopy and drop tensiometry, were coupled in an original homemade experimental setup for in situ monitoring of radical polymerization in a single monomer droplet. Homopolymerizations of styrene and methyl methacrylate initiated by 2,2′‐azobisisobu...
Gespeichert in:
| Veröffentlicht in: | Journal of Raman spectroscopy 2018-12, Vol.49 (12), p.2046-2049 |
|---|---|
| Hauptverfasser: | , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 2049 |
|---|---|
| container_issue | 12 |
| container_start_page | 2046 |
| container_title | Journal of Raman spectroscopy |
| container_volume | 49 |
| creator | Dropsit, Elise Desbrières, Jacques Chapron, David Hoppe, Sandrine Durand, Alain Bourson, Patrice |
| description | Two complementary analytical techniques, Raman spectroscopy and drop tensiometry, were coupled in an original homemade experimental setup for in situ monitoring of radical polymerization in a single monomer droplet. Homopolymerizations of styrene and methyl methacrylate initiated by 2,2′‐azobisisobutyronitrile in a single droplet surrounded by an aqueous medium containing sodium dodecylsulfate were investigated. Monomer conversion (from Raman spectroscopy) and interfacial properties (interfacial tension and dilational moduli, from drop tensiometry) were simultaneously acquired in situ.
Raman spectroscopy and drop tensiometry were coupled in an original homemade experimental setup for in situ monitoring of radical polymerization in a single monomer droplet. |
| doi_str_mv | 10.1002/jrs.5489 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_hal_p</sourceid><recordid>TN_cdi_hal_primary_oai_HAL_hal_01893737v1</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2157211488</sourcerecordid><originalsourceid>FETCH-LOGICAL-c3649-1e1bb4d2d86eebe5c53637bdf67425cf3d13dfd66a8d99a82a04147f7288e1d03</originalsourceid><addsrcrecordid>eNp10UFLwzAYBuAgCs4p-BMCXvTQmTRpkx5lqFMGwtRzSJt0ZrRNTVqlgv_ddBVvngIfz_fykReAc4wWGKH4euf8IqE8OwAzjDIW0SRJDsEMEcYiRHl6DE683yGEsizFM_C9tH1bmWYLN7KWDfStLjpnfWHbAcpGQeVsCzvdeGNr3bkBltZBE6DpeljbxnTWjeu2hE4qU8gKtrYaau3Ml-yMbUYsA2-2lR4XQozbp1a6OwVHpay8Pvt95-D17vZluYrWT_cPy5t1VJCUZhHWOM-pihVPtc51UiQkJSxXZcponBQlUZioUqWp5CrLJI8lopiyksWca6wQmYOrKfdNVqJ1ppZuEFYasbpZi3GGMM8II-wDB3sx2dbZ9177Tuxs75pwnohxwmKMKedBXU6qCJ_lnS7_YjESYxEiFCHGIgKNJvppKj3868Tj5nnvfwB3LYvg</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2157211488</pqid></control><display><type>article</type><title>Coupling Raman spectroscopy and drop tensiometry for in situ monitoring of radical polymerization in a single monomer droplet</title><source>Wiley Online Library Journals Frontfile Complete</source><creator>Dropsit, Elise ; Desbrières, Jacques ; Chapron, David ; Hoppe, Sandrine ; Durand, Alain ; Bourson, Patrice</creator><creatorcontrib>Dropsit, Elise ; Desbrières, Jacques ; Chapron, David ; Hoppe, Sandrine ; Durand, Alain ; Bourson, Patrice</creatorcontrib><description>Two complementary analytical techniques, Raman spectroscopy and drop tensiometry, were coupled in an original homemade experimental setup for in situ monitoring of radical polymerization in a single monomer droplet. Homopolymerizations of styrene and methyl methacrylate initiated by 2,2′‐azobisisobutyronitrile in a single droplet surrounded by an aqueous medium containing sodium dodecylsulfate were investigated. Monomer conversion (from Raman spectroscopy) and interfacial properties (interfacial tension and dilational moduli, from drop tensiometry) were simultaneously acquired in situ.
Raman spectroscopy and drop tensiometry were coupled in an original homemade experimental setup for in situ monitoring of radical polymerization in a single monomer droplet.</description><identifier>ISSN: 0377-0486</identifier><identifier>EISSN: 1097-4555</identifier><identifier>DOI: 10.1002/jrs.5489</identifier><language>eng</language><publisher>Bognor Regis: Wiley Subscription Services, Inc</publisher><subject>Aqueous solutions ; Azobisisobutyronitrile ; Chemical Sciences ; coupling ; drop tensiometry ; Droplets ; Engineering Sciences ; Interfacial properties ; Monitoring ; Monomers ; Optics ; Photonic ; Polymerization ; Polymethyl methacrylate ; Raman spectroscopy ; single‐droplet Raman spectroscopy ; Sodium ; Spectroscopy ; Spectrum analysis ; Styrene ; Surface tension</subject><ispartof>Journal of Raman spectroscopy, 2018-12, Vol.49 (12), p.2046-2049</ispartof><rights>2018 John Wiley & Sons, Ltd.</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3649-1e1bb4d2d86eebe5c53637bdf67425cf3d13dfd66a8d99a82a04147f7288e1d03</citedby><cites>FETCH-LOGICAL-c3649-1e1bb4d2d86eebe5c53637bdf67425cf3d13dfd66a8d99a82a04147f7288e1d03</cites><orcidid>0000-0003-1017-6029 ; 0000-0003-3460-4585 ; 0000-0003-1688-4042 ; 0000-0002-0738-6626 ; 0000-0002-3541-3257</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fjrs.5489$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fjrs.5489$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>230,314,777,781,882,1412,27905,27906,45555,45556</link.rule.ids><backlink>$$Uhttps://centralesupelec.hal.science/hal-01893737$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Dropsit, Elise</creatorcontrib><creatorcontrib>Desbrières, Jacques</creatorcontrib><creatorcontrib>Chapron, David</creatorcontrib><creatorcontrib>Hoppe, Sandrine</creatorcontrib><creatorcontrib>Durand, Alain</creatorcontrib><creatorcontrib>Bourson, Patrice</creatorcontrib><title>Coupling Raman spectroscopy and drop tensiometry for in situ monitoring of radical polymerization in a single monomer droplet</title><title>Journal of Raman spectroscopy</title><description>Two complementary analytical techniques, Raman spectroscopy and drop tensiometry, were coupled in an original homemade experimental setup for in situ monitoring of radical polymerization in a single monomer droplet. Homopolymerizations of styrene and methyl methacrylate initiated by 2,2′‐azobisisobutyronitrile in a single droplet surrounded by an aqueous medium containing sodium dodecylsulfate were investigated. Monomer conversion (from Raman spectroscopy) and interfacial properties (interfacial tension and dilational moduli, from drop tensiometry) were simultaneously acquired in situ.
Raman spectroscopy and drop tensiometry were coupled in an original homemade experimental setup for in situ monitoring of radical polymerization in a single monomer droplet.</description><subject>Aqueous solutions</subject><subject>Azobisisobutyronitrile</subject><subject>Chemical Sciences</subject><subject>coupling</subject><subject>drop tensiometry</subject><subject>Droplets</subject><subject>Engineering Sciences</subject><subject>Interfacial properties</subject><subject>Monitoring</subject><subject>Monomers</subject><subject>Optics</subject><subject>Photonic</subject><subject>Polymerization</subject><subject>Polymethyl methacrylate</subject><subject>Raman spectroscopy</subject><subject>single‐droplet Raman spectroscopy</subject><subject>Sodium</subject><subject>Spectroscopy</subject><subject>Spectrum analysis</subject><subject>Styrene</subject><subject>Surface tension</subject><issn>0377-0486</issn><issn>1097-4555</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNp10UFLwzAYBuAgCs4p-BMCXvTQmTRpkx5lqFMGwtRzSJt0ZrRNTVqlgv_ddBVvngIfz_fykReAc4wWGKH4euf8IqE8OwAzjDIW0SRJDsEMEcYiRHl6DE683yGEsizFM_C9tH1bmWYLN7KWDfStLjpnfWHbAcpGQeVsCzvdeGNr3bkBltZBE6DpeljbxnTWjeu2hE4qU8gKtrYaau3Ml-yMbUYsA2-2lR4XQozbp1a6OwVHpay8Pvt95-D17vZluYrWT_cPy5t1VJCUZhHWOM-pihVPtc51UiQkJSxXZcponBQlUZioUqWp5CrLJI8lopiyksWca6wQmYOrKfdNVqJ1ppZuEFYasbpZi3GGMM8II-wDB3sx2dbZ9177Tuxs75pwnohxwmKMKedBXU6qCJ_lnS7_YjESYxEiFCHGIgKNJvppKj3868Tj5nnvfwB3LYvg</recordid><startdate>201812</startdate><enddate>201812</enddate><creator>Dropsit, Elise</creator><creator>Desbrières, Jacques</creator><creator>Chapron, David</creator><creator>Hoppe, Sandrine</creator><creator>Durand, Alain</creator><creator>Bourson, Patrice</creator><general>Wiley Subscription Services, Inc</general><general>Wiley</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QF</scope><scope>7QO</scope><scope>7QQ</scope><scope>7SC</scope><scope>7SE</scope><scope>7SP</scope><scope>7SR</scope><scope>7TA</scope><scope>7TB</scope><scope>7U5</scope><scope>7U9</scope><scope>8BQ</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>H8D</scope><scope>H8G</scope><scope>H94</scope><scope>JG9</scope><scope>JQ2</scope><scope>KR7</scope><scope>L7M</scope><scope>L~C</scope><scope>L~D</scope><scope>P64</scope><scope>RC3</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0003-1017-6029</orcidid><orcidid>https://orcid.org/0000-0003-3460-4585</orcidid><orcidid>https://orcid.org/0000-0003-1688-4042</orcidid><orcidid>https://orcid.org/0000-0002-0738-6626</orcidid><orcidid>https://orcid.org/0000-0002-3541-3257</orcidid></search><sort><creationdate>201812</creationdate><title>Coupling Raman spectroscopy and drop tensiometry for in situ monitoring of radical polymerization in a single monomer droplet</title><author>Dropsit, Elise ; Desbrières, Jacques ; Chapron, David ; Hoppe, Sandrine ; Durand, Alain ; Bourson, Patrice</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3649-1e1bb4d2d86eebe5c53637bdf67425cf3d13dfd66a8d99a82a04147f7288e1d03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Aqueous solutions</topic><topic>Azobisisobutyronitrile</topic><topic>Chemical Sciences</topic><topic>coupling</topic><topic>drop tensiometry</topic><topic>Droplets</topic><topic>Engineering Sciences</topic><topic>Interfacial properties</topic><topic>Monitoring</topic><topic>Monomers</topic><topic>Optics</topic><topic>Photonic</topic><topic>Polymerization</topic><topic>Polymethyl methacrylate</topic><topic>Raman spectroscopy</topic><topic>single‐droplet Raman spectroscopy</topic><topic>Sodium</topic><topic>Spectroscopy</topic><topic>Spectrum analysis</topic><topic>Styrene</topic><topic>Surface tension</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Dropsit, Elise</creatorcontrib><creatorcontrib>Desbrières, Jacques</creatorcontrib><creatorcontrib>Chapron, David</creatorcontrib><creatorcontrib>Hoppe, Sandrine</creatorcontrib><creatorcontrib>Durand, Alain</creatorcontrib><creatorcontrib>Bourson, Patrice</creatorcontrib><collection>CrossRef</collection><collection>Aluminium Industry Abstracts</collection><collection>Biotechnology Research Abstracts</collection><collection>Ceramic Abstracts</collection><collection>Computer and Information Systems Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Electronics & Communications Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>Materials Business File</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Virology and AIDS Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Copper Technical Reference Library</collection><collection>AIDS and Cancer Research Abstracts</collection><collection>Materials Research Database</collection><collection>ProQuest Computer Science Collection</collection><collection>Civil Engineering Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Computer and Information Systems Abstracts Academic</collection><collection>Computer and Information Systems Abstracts Professional</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>Genetics Abstracts</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Journal of Raman spectroscopy</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Dropsit, Elise</au><au>Desbrières, Jacques</au><au>Chapron, David</au><au>Hoppe, Sandrine</au><au>Durand, Alain</au><au>Bourson, Patrice</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Coupling Raman spectroscopy and drop tensiometry for in situ monitoring of radical polymerization in a single monomer droplet</atitle><jtitle>Journal of Raman spectroscopy</jtitle><date>2018-12</date><risdate>2018</risdate><volume>49</volume><issue>12</issue><spage>2046</spage><epage>2049</epage><pages>2046-2049</pages><issn>0377-0486</issn><eissn>1097-4555</eissn><abstract>Two complementary analytical techniques, Raman spectroscopy and drop tensiometry, were coupled in an original homemade experimental setup for in situ monitoring of radical polymerization in a single monomer droplet. Homopolymerizations of styrene and methyl methacrylate initiated by 2,2′‐azobisisobutyronitrile in a single droplet surrounded by an aqueous medium containing sodium dodecylsulfate were investigated. Monomer conversion (from Raman spectroscopy) and interfacial properties (interfacial tension and dilational moduli, from drop tensiometry) were simultaneously acquired in situ.
Raman spectroscopy and drop tensiometry were coupled in an original homemade experimental setup for in situ monitoring of radical polymerization in a single monomer droplet.</abstract><cop>Bognor Regis</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/jrs.5489</doi><tpages>4</tpages><orcidid>https://orcid.org/0000-0003-1017-6029</orcidid><orcidid>https://orcid.org/0000-0003-3460-4585</orcidid><orcidid>https://orcid.org/0000-0003-1688-4042</orcidid><orcidid>https://orcid.org/0000-0002-0738-6626</orcidid><orcidid>https://orcid.org/0000-0002-3541-3257</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0377-0486 |
| ispartof | Journal of Raman spectroscopy, 2018-12, Vol.49 (12), p.2046-2049 |
| issn | 0377-0486 1097-4555 |
| language | eng |
| recordid | cdi_hal_primary_oai_HAL_hal_01893737v1 |
| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Aqueous solutions Azobisisobutyronitrile Chemical Sciences coupling drop tensiometry Droplets Engineering Sciences Interfacial properties Monitoring Monomers Optics Photonic Polymerization Polymethyl methacrylate Raman spectroscopy single‐droplet Raman spectroscopy Sodium Spectroscopy Spectrum analysis Styrene Surface tension |
| title | Coupling Raman spectroscopy and drop tensiometry for in situ monitoring of radical polymerization in a single monomer droplet |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-20T15%3A56%3A33IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_hal_p&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Coupling%20Raman%20spectroscopy%20and%20drop%20tensiometry%20for%20in%20situ%20monitoring%20of%20radical%20polymerization%20in%20a%20single%20monomer%20droplet&rft.jtitle=Journal%20of%20Raman%20spectroscopy&rft.au=Dropsit,%20Elise&rft.date=2018-12&rft.volume=49&rft.issue=12&rft.spage=2046&rft.epage=2049&rft.pages=2046-2049&rft.issn=0377-0486&rft.eissn=1097-4555&rft_id=info:doi/10.1002/jrs.5489&rft_dat=%3Cproquest_hal_p%3E2157211488%3C/proquest_hal_p%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2157211488&rft_id=info:pmid/&rfr_iscdi=true |