Dimensional instabilities of polyester and polyolefin films as origin of delamination in laminated multilayer
ABSTRACT Polymer–metal multilayer films provide attractive barrier properties to air and water, provided by several films bonded together. Used in high temperature and humidity, the delamination is the most common degradation mechanism. This mode of failure is critical because it leads to premature...
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| Veröffentlicht in: | Journal of polymer science. Part B, Polymer physics Polymer physics, 2017-02, Vol.55 (4), p.309-319 |
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| container_title | Journal of polymer science. Part B, Polymer physics |
| container_volume | 55 |
| creator | Dubelley, Florence Planes, Emilie Bas, Corine Pons, Emmanuelle Yrieix, Bernard Flandin, Lionel |
| description | ABSTRACT
Polymer–metal multilayer films provide attractive barrier properties to air and water, provided by several films bonded together. Used in high temperature and humidity, the delamination is the most common degradation mechanism. This mode of failure is critical because it leads to premature loss of barrier properties. Therefore, delaminations limit the use of multilayer in these conditions. Delamination should result from interfacial shear stress, and plausibly from difference of shrinkage of the films, due to relaxation of internal stress. A method was developed for measuring the deformations of each individual film. The measurements indicate that the shrinkage is anisotropic and controls the decohesion in the multilayer. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2017, 55, 309–319
In stacked films, interfacial delamination is a common and well‐identified problem. This failure mechanism reduces the use of multilayer polymer systems. Unfortunately this degradation might originate from a series of very dissimilar causes. This work details why the difference in dilatation and/or shrinkage between assembled films should be considered as a very plausible cause for interfacial separations. |
| doi_str_mv | 10.1002/polb.24274 |
| format | Article |
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Polymer–metal multilayer films provide attractive barrier properties to air and water, provided by several films bonded together. Used in high temperature and humidity, the delamination is the most common degradation mechanism. This mode of failure is critical because it leads to premature loss of barrier properties. Therefore, delaminations limit the use of multilayer in these conditions. Delamination should result from interfacial shear stress, and plausibly from difference of shrinkage of the films, due to relaxation of internal stress. A method was developed for measuring the deformations of each individual film. The measurements indicate that the shrinkage is anisotropic and controls the decohesion in the multilayer. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2017, 55, 309–319
In stacked films, interfacial delamination is a common and well‐identified problem. This failure mechanism reduces the use of multilayer polymer systems. Unfortunately this degradation might originate from a series of very dissimilar causes. This work details why the difference in dilatation and/or shrinkage between assembled films should be considered as a very plausible cause for interfacial separations.</description><identifier>ISSN: 0887-6266</identifier><identifier>EISSN: 1099-0488</identifier><identifier>DOI: 10.1002/polb.24274</identifier><identifier>CODEN: JPBPEM</identifier><language>eng</language><publisher>Hoboken: Wiley Subscription Services, Inc</publisher><subject>Anisotropy ; Barriers ; Degradation ; Delaminating ; Delamination ; dimensional stability ; Engineering Sciences ; Interfacial shear stresses ; Materials ; Multilayers ; polymer–metal multilayer ; Shrinkage</subject><ispartof>Journal of polymer science. Part B, Polymer physics, 2017-02, Vol.55 (4), p.309-319</ispartof><rights>2016 Wiley Periodicals, Inc.</rights><rights>2017 Wiley Periodicals, Inc.</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c3684-e564598c4ee74f49cf5b227a0d1dec7ca780cbe4a8526e7f5e75a1ea564ea3c93</citedby><cites>FETCH-LOGICAL-c3684-e564598c4ee74f49cf5b227a0d1dec7ca780cbe4a8526e7f5e75a1ea564ea3c93</cites><orcidid>0000-0002-1117-2268 ; 0000-0003-2555-8206 ; 0000-0003-3582-7705</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fpolb.24274$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fpolb.24274$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>230,314,780,784,885,1417,27924,27925,45574,45575</link.rule.ids><backlink>$$Uhttps://hal.science/hal-01884531$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Dubelley, Florence</creatorcontrib><creatorcontrib>Planes, Emilie</creatorcontrib><creatorcontrib>Bas, Corine</creatorcontrib><creatorcontrib>Pons, Emmanuelle</creatorcontrib><creatorcontrib>Yrieix, Bernard</creatorcontrib><creatorcontrib>Flandin, Lionel</creatorcontrib><title>Dimensional instabilities of polyester and polyolefin films as origin of delamination in laminated multilayer</title><title>Journal of polymer science. Part B, Polymer physics</title><description>ABSTRACT
Polymer–metal multilayer films provide attractive barrier properties to air and water, provided by several films bonded together. Used in high temperature and humidity, the delamination is the most common degradation mechanism. This mode of failure is critical because it leads to premature loss of barrier properties. Therefore, delaminations limit the use of multilayer in these conditions. Delamination should result from interfacial shear stress, and plausibly from difference of shrinkage of the films, due to relaxation of internal stress. A method was developed for measuring the deformations of each individual film. The measurements indicate that the shrinkage is anisotropic and controls the decohesion in the multilayer. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2017, 55, 309–319
In stacked films, interfacial delamination is a common and well‐identified problem. This failure mechanism reduces the use of multilayer polymer systems. Unfortunately this degradation might originate from a series of very dissimilar causes. This work details why the difference in dilatation and/or shrinkage between assembled films should be considered as a very plausible cause for interfacial separations.</description><subject>Anisotropy</subject><subject>Barriers</subject><subject>Degradation</subject><subject>Delaminating</subject><subject>Delamination</subject><subject>dimensional stability</subject><subject>Engineering Sciences</subject><subject>Interfacial shear stresses</subject><subject>Materials</subject><subject>Multilayers</subject><subject>polymer–metal multilayer</subject><subject>Shrinkage</subject><issn>0887-6266</issn><issn>1099-0488</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNp90U1PxCAQBmBiNHH9uPgLmnhRkyq0UOjRb0020YOeySydKoaWFbqa_fdSazx48EQGnnkDDCEHjJ4ySouzpXeL04IXkm-QGaN1nVOu1CaZUaVkXhVVtU12YnyjNJ2Jeka6K9thH63vwWW2jwMsrLODxZj5Nktxa4wDhgz65rvyDlvbZ611XcwgoWBfUp1sgw4628OQslJS9lNhk3UrN1gHawx7ZKsFF3H_Z90lzzfXT5d3-fzh9v7yfJ6bslI8R1FxUSvDESVveW1asSgKCbRhDRppQCpqFshBiaJC2QqUAhhCakMoTV3ukuMp9xWcXgbbQVhrD1bfnc_1uEeZUlyU7IMlezTZZfDvq_Ra3dlo0Dno0a-iTpJSVhacJnr4h775VUg_NyohRimrpE4mZYKPMWD7ewNG9TglPU5Jf08pYTbhT-tw_Y_Ujw_zi6nnC2jElhY</recordid><startdate>20170215</startdate><enddate>20170215</enddate><creator>Dubelley, Florence</creator><creator>Planes, Emilie</creator><creator>Bas, Corine</creator><creator>Pons, Emmanuelle</creator><creator>Yrieix, Bernard</creator><creator>Flandin, Lionel</creator><general>Wiley Subscription Services, Inc</general><general>Wiley</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0002-1117-2268</orcidid><orcidid>https://orcid.org/0000-0003-2555-8206</orcidid><orcidid>https://orcid.org/0000-0003-3582-7705</orcidid></search><sort><creationdate>20170215</creationdate><title>Dimensional instabilities of polyester and polyolefin films as origin of delamination in laminated multilayer</title><author>Dubelley, Florence ; Planes, Emilie ; Bas, Corine ; Pons, Emmanuelle ; Yrieix, Bernard ; Flandin, Lionel</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c3684-e564598c4ee74f49cf5b227a0d1dec7ca780cbe4a8526e7f5e75a1ea564ea3c93</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Anisotropy</topic><topic>Barriers</topic><topic>Degradation</topic><topic>Delaminating</topic><topic>Delamination</topic><topic>dimensional stability</topic><topic>Engineering Sciences</topic><topic>Interfacial shear stresses</topic><topic>Materials</topic><topic>Multilayers</topic><topic>polymer–metal multilayer</topic><topic>Shrinkage</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Dubelley, Florence</creatorcontrib><creatorcontrib>Planes, Emilie</creatorcontrib><creatorcontrib>Bas, Corine</creatorcontrib><creatorcontrib>Pons, Emmanuelle</creatorcontrib><creatorcontrib>Yrieix, Bernard</creatorcontrib><creatorcontrib>Flandin, Lionel</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Journal of polymer science. Part B, Polymer physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Dubelley, Florence</au><au>Planes, Emilie</au><au>Bas, Corine</au><au>Pons, Emmanuelle</au><au>Yrieix, Bernard</au><au>Flandin, Lionel</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Dimensional instabilities of polyester and polyolefin films as origin of delamination in laminated multilayer</atitle><jtitle>Journal of polymer science. Part B, Polymer physics</jtitle><date>2017-02-15</date><risdate>2017</risdate><volume>55</volume><issue>4</issue><spage>309</spage><epage>319</epage><pages>309-319</pages><issn>0887-6266</issn><eissn>1099-0488</eissn><coden>JPBPEM</coden><abstract>ABSTRACT
Polymer–metal multilayer films provide attractive barrier properties to air and water, provided by several films bonded together. Used in high temperature and humidity, the delamination is the most common degradation mechanism. This mode of failure is critical because it leads to premature loss of barrier properties. Therefore, delaminations limit the use of multilayer in these conditions. Delamination should result from interfacial shear stress, and plausibly from difference of shrinkage of the films, due to relaxation of internal stress. A method was developed for measuring the deformations of each individual film. The measurements indicate that the shrinkage is anisotropic and controls the decohesion in the multilayer. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2017, 55, 309–319
In stacked films, interfacial delamination is a common and well‐identified problem. This failure mechanism reduces the use of multilayer polymer systems. Unfortunately this degradation might originate from a series of very dissimilar causes. This work details why the difference in dilatation and/or shrinkage between assembled films should be considered as a very plausible cause for interfacial separations.</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/polb.24274</doi><tpages>11</tpages><orcidid>https://orcid.org/0000-0002-1117-2268</orcidid><orcidid>https://orcid.org/0000-0003-2555-8206</orcidid><orcidid>https://orcid.org/0000-0003-3582-7705</orcidid></addata></record> |
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| source | Wiley Journals |
| subjects | Anisotropy Barriers Degradation Delaminating Delamination dimensional stability Engineering Sciences Interfacial shear stresses Materials Multilayers polymer–metal multilayer Shrinkage |
| title | Dimensional instabilities of polyester and polyolefin films as origin of delamination in laminated multilayer |
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