Syntheses of a wide family of new aryl based perfluorosulfonimide lithium salts. Electrochemical performances of the related polymer electrolytes
[Display omitted] ► Multistep synthesis allowing wide variety of salts to be prepared. ► High conductivity of PEO electrolytes. ► Wide electrochemical stability window. This paper reports both on a general multistep synthesis of a wide family of aryl substituted perfluorosulfonimides and on a prelim...
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| Veröffentlicht in: | Journal of fluorine chemistry 2011-12, Vol.132 (12), p.1213-1218 |
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| container_title | Journal of fluorine chemistry |
| container_volume | 132 |
| creator | Paillard, E. Toulgoat, F. Arvai, R. Iojoiu, C. Cointeaux, L. Medebielle, M. Alloin, F. Langlois, B. Sanchez, J.-Y. |
| description | [Display omitted]
► Multistep synthesis allowing wide variety of salts to be prepared. ► High conductivity of PEO electrolytes. ► Wide electrochemical stability window.
This paper reports both on a general multistep synthesis of a wide family of aryl substituted perfluorosulfonimides and on a preliminary electrochemical investigation of two lithium salts hosted by a poly(oxyethylene) homopolymer. Both salts have a cationic transference number more than twice that of LiTFSI. Additionally, one of these salts exhibits markedly higher cationic conductivities than POE/LiTFSI electrolytes. These preliminary data are very encouraging as, thanks to the aryl moiety, a wide variety of salts can be considered in order to still improve the performances of polymer electrolytes. |
| doi_str_mv | 10.1016/j.jfluchem.2011.06.041 |
| format | Article |
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► Multistep synthesis allowing wide variety of salts to be prepared. ► High conductivity of PEO electrolytes. ► Wide electrochemical stability window.
This paper reports both on a general multistep synthesis of a wide family of aryl substituted perfluorosulfonimides and on a preliminary electrochemical investigation of two lithium salts hosted by a poly(oxyethylene) homopolymer. Both salts have a cationic transference number more than twice that of LiTFSI. Additionally, one of these salts exhibits markedly higher cationic conductivities than POE/LiTFSI electrolytes. These preliminary data are very encouraging as, thanks to the aryl moiety, a wide variety of salts can be considered in order to still improve the performances of polymer electrolytes.</description><identifier>ISSN: 0022-1139</identifier><identifier>EISSN: 1873-3328</identifier><identifier>DOI: 10.1016/j.jfluchem.2011.06.041</identifier><language>eng</language><publisher>Elsevier B.V</publisher><subject>Aromatic compounds ; Cationic ; Cationic transference numbers ; Chemical Sciences ; Conductivity ; Electrolytes ; Fluorine ; Lithium ; Multistep syntheses ; PEO ; Perfluorosulfonimide lithium salts ; Performance enhancement ; POE ; Polymer electrolytes ; Synthesis (chemistry)</subject><ispartof>Journal of fluorine chemistry, 2011-12, Vol.132 (12), p.1213-1218</ispartof><rights>2011 Elsevier B.V.</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c379t-7133f0487748c2d854b97e451f422c2e92ee81f06d96d52788b0fec49c1973ef3</citedby><cites>FETCH-LOGICAL-c379t-7133f0487748c2d854b97e451f422c2e92ee81f06d96d52788b0fec49c1973ef3</cites><orcidid>0000-0002-6032-4790 ; 0000-0001-7882-1587</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.jfluchem.2011.06.041$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>230,314,780,784,885,3550,27924,27925,45995</link.rule.ids><backlink>$$Uhttps://hal.science/hal-01884296$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Paillard, E.</creatorcontrib><creatorcontrib>Toulgoat, F.</creatorcontrib><creatorcontrib>Arvai, R.</creatorcontrib><creatorcontrib>Iojoiu, C.</creatorcontrib><creatorcontrib>Cointeaux, L.</creatorcontrib><creatorcontrib>Medebielle, M.</creatorcontrib><creatorcontrib>Alloin, F.</creatorcontrib><creatorcontrib>Langlois, B.</creatorcontrib><creatorcontrib>Sanchez, J.-Y.</creatorcontrib><title>Syntheses of a wide family of new aryl based perfluorosulfonimide lithium salts. Electrochemical performances of the related polymer electrolytes</title><title>Journal of fluorine chemistry</title><description>[Display omitted]
► Multistep synthesis allowing wide variety of salts to be prepared. ► High conductivity of PEO electrolytes. ► Wide electrochemical stability window.
This paper reports both on a general multistep synthesis of a wide family of aryl substituted perfluorosulfonimides and on a preliminary electrochemical investigation of two lithium salts hosted by a poly(oxyethylene) homopolymer. Both salts have a cationic transference number more than twice that of LiTFSI. Additionally, one of these salts exhibits markedly higher cationic conductivities than POE/LiTFSI electrolytes. These preliminary data are very encouraging as, thanks to the aryl moiety, a wide variety of salts can be considered in order to still improve the performances of polymer electrolytes.</description><subject>Aromatic compounds</subject><subject>Cationic</subject><subject>Cationic transference numbers</subject><subject>Chemical Sciences</subject><subject>Conductivity</subject><subject>Electrolytes</subject><subject>Fluorine</subject><subject>Lithium</subject><subject>Multistep syntheses</subject><subject>PEO</subject><subject>Perfluorosulfonimide lithium salts</subject><subject>Performance enhancement</subject><subject>POE</subject><subject>Polymer electrolytes</subject><subject>Synthesis (chemistry)</subject><issn>0022-1139</issn><issn>1873-3328</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNqFUctq3DAUFaGFTNP-QtEyXdjRayx5lxDyKAx00XYtNPIVo0G2JpKd4M_oH1eO026zunA5j3vPQegrJTUltLk61kcXJnuAvmaE0po0NRH0DG2okrzinKkPaEMIYxWlvD1Hn3I-EkIkkWqD_vych_EAGTKODhv84jvAzvQ-zMtigBds0hzw3mTo8AlSsYop5im4OPh-QQc_HvzU42zCmGt8F8COKS73eGvCKyem3gx29ShuOEEw46IXw9xDwrBywjxC_ow-OhMyfHmbF-j3_d2v28dq9-Ph--3NrrJctmMlKeeOCCWlUJZ1aiv2rQSxpU4wZhm0DEBRR5qubbotk0rtiQMrWktbycHxC_Rt1T2YoE_J9-VPHY3Xjzc7vewIVUqwtnmmBXu5Yk8pPk2QR937bCEEM0CcsqZSiEbKckSBNivUlpRyAvdfmxK99KWP-l9feulLk0aXvgrxeiVCefrZQ9LZeiipdT6VdHQX_XsSfwHtk6Sf</recordid><startdate>20111201</startdate><enddate>20111201</enddate><creator>Paillard, E.</creator><creator>Toulgoat, F.</creator><creator>Arvai, R.</creator><creator>Iojoiu, C.</creator><creator>Cointeaux, L.</creator><creator>Medebielle, M.</creator><creator>Alloin, F.</creator><creator>Langlois, B.</creator><creator>Sanchez, J.-Y.</creator><general>Elsevier B.V</general><general>Elsevier</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0002-6032-4790</orcidid><orcidid>https://orcid.org/0000-0001-7882-1587</orcidid></search><sort><creationdate>20111201</creationdate><title>Syntheses of a wide family of new aryl based perfluorosulfonimide lithium salts. Electrochemical performances of the related polymer electrolytes</title><author>Paillard, E. ; Toulgoat, F. ; Arvai, R. ; Iojoiu, C. ; Cointeaux, L. ; Medebielle, M. ; Alloin, F. ; Langlois, B. ; Sanchez, J.-Y.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c379t-7133f0487748c2d854b97e451f422c2e92ee81f06d96d52788b0fec49c1973ef3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Aromatic compounds</topic><topic>Cationic</topic><topic>Cationic transference numbers</topic><topic>Chemical Sciences</topic><topic>Conductivity</topic><topic>Electrolytes</topic><topic>Fluorine</topic><topic>Lithium</topic><topic>Multistep syntheses</topic><topic>PEO</topic><topic>Perfluorosulfonimide lithium salts</topic><topic>Performance enhancement</topic><topic>POE</topic><topic>Polymer electrolytes</topic><topic>Synthesis (chemistry)</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Paillard, E.</creatorcontrib><creatorcontrib>Toulgoat, F.</creatorcontrib><creatorcontrib>Arvai, R.</creatorcontrib><creatorcontrib>Iojoiu, C.</creatorcontrib><creatorcontrib>Cointeaux, L.</creatorcontrib><creatorcontrib>Medebielle, M.</creatorcontrib><creatorcontrib>Alloin, F.</creatorcontrib><creatorcontrib>Langlois, B.</creatorcontrib><creatorcontrib>Sanchez, J.-Y.</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Journal of fluorine chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Paillard, E.</au><au>Toulgoat, F.</au><au>Arvai, R.</au><au>Iojoiu, C.</au><au>Cointeaux, L.</au><au>Medebielle, M.</au><au>Alloin, F.</au><au>Langlois, B.</au><au>Sanchez, J.-Y.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Syntheses of a wide family of new aryl based perfluorosulfonimide lithium salts. Electrochemical performances of the related polymer electrolytes</atitle><jtitle>Journal of fluorine chemistry</jtitle><date>2011-12-01</date><risdate>2011</risdate><volume>132</volume><issue>12</issue><spage>1213</spage><epage>1218</epage><pages>1213-1218</pages><issn>0022-1139</issn><eissn>1873-3328</eissn><abstract>[Display omitted]
► Multistep synthesis allowing wide variety of salts to be prepared. ► High conductivity of PEO electrolytes. ► Wide electrochemical stability window.
This paper reports both on a general multistep synthesis of a wide family of aryl substituted perfluorosulfonimides and on a preliminary electrochemical investigation of two lithium salts hosted by a poly(oxyethylene) homopolymer. Both salts have a cationic transference number more than twice that of LiTFSI. Additionally, one of these salts exhibits markedly higher cationic conductivities than POE/LiTFSI electrolytes. These preliminary data are very encouraging as, thanks to the aryl moiety, a wide variety of salts can be considered in order to still improve the performances of polymer electrolytes.</abstract><pub>Elsevier B.V</pub><doi>10.1016/j.jfluchem.2011.06.041</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0002-6032-4790</orcidid><orcidid>https://orcid.org/0000-0001-7882-1587</orcidid></addata></record> |
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| ispartof | Journal of fluorine chemistry, 2011-12, Vol.132 (12), p.1213-1218 |
| issn | 0022-1139 1873-3328 |
| language | eng |
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| source | Access via ScienceDirect (Elsevier) |
| subjects | Aromatic compounds Cationic Cationic transference numbers Chemical Sciences Conductivity Electrolytes Fluorine Lithium Multistep syntheses PEO Perfluorosulfonimide lithium salts Performance enhancement POE Polymer electrolytes Synthesis (chemistry) |
| title | Syntheses of a wide family of new aryl based perfluorosulfonimide lithium salts. Electrochemical performances of the related polymer electrolytes |
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