Synthesis of Comblike Poly(butyl methacrylate) Using Reversible Addition−Fragmentation Chain Transfer and an Activated Ester

Comblike polymers of poly(n-butyl methacrylate) were prepared using an activated ester-type comonomer (N-acryloxysuccinimide, NAS) to generate branch points. The conventional solution free-radical copolymerization kinetics of n-butyl methacrylate (BMA) and NAS were first investigated by following in...

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Veröffentlicht in:	Macromolecules 2004-04, Vol.37 (7), p.2371-2382
Hauptverfasser:	Vosloo, Johannes J, Tonge, Matthew P, Fellows, Christopher M, D'Agosto, Franck, Sanderson, Ronald D, Gilbert, Robert G
Format:	Artikel
Sprache:	eng
Schlagworte:	Applied sciences Chemical Sciences Copolymerization Exact sciences and technology Organic polymers Physicochemistry of polymers Preparation, kinetics, thermodynamics, mechanism and catalysts
Online-Zugang:	Volltext
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