Synthesis of copolymers of ethylene and (meth)acrylates or styrene by an original dual radical/catalytic mechanism
Neutral Ni complexes, classically used for catalytic ethylene polymerization, can play an additional role as radical initiators of the homo- and copolymerizations of (meth)acrylates and styrene. Benefiting from this duality, the copolymerization of ethylene and various (meth)acrylates or styrene was...
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| Veröffentlicht in: | Pure and applied chemistry 2012-01, Vol.84 (10), p.2113-2120 |
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| container_end_page | 2120 |
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| container_issue | 10 |
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| container_title | Pure and applied chemistry |
| container_volume | 84 |
| creator | Leblanc, Alexandra Broyer, Jean-Pierre Boisson, Christophe Spitz, Roger Monteil, Vincent |
| description | Neutral Ni
complexes, classically used for catalytic ethylene polymerization, can play an additional role as radical initiators of the homo- and copolymerizations of (meth)acrylates and styrene. Benefiting from this duality, the copolymerization of ethylene and various (meth)acrylates or styrene was successfully performed. Multiblock copolymers containing sequences of both ethylene and (meth)acrylates were prepared for the first time from an original dual radical/catalytic mechanism. |
| doi_str_mv | 10.1351/PAC-CON-11-10-05 |
| format | Article |
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complexes, classically used for catalytic ethylene polymerization, can play an additional role as radical initiators of the homo- and copolymerizations of (meth)acrylates and styrene. Benefiting from this duality, the copolymerization of ethylene and various (meth)acrylates or styrene was successfully performed. Multiblock copolymers containing sequences of both ethylene and (meth)acrylates were prepared for the first time from an original dual radical/catalytic mechanism.</abstract><cop>Berlin</cop><pub>De Gruyter</pub><doi>10.1351/PAC-CON-11-10-05</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0003-3530-1789</orcidid><orcidid>https://orcid.org/0000-0002-7909-901X</orcidid><oa>free_for_read</oa></addata></record> |
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| ispartof | Pure and applied chemistry, 2012-01, Vol.84 (10), p.2113-2120 |
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| language | eng |
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| source | Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; Free Full-Text Journals in Chemistry |
| subjects | (meth)acrylates Acrylates Addition polymerization Catalysis Chemical Sciences Chemical synthesis Copolymerization Copolymers Ethylene free radicals Initiators olefins polymerization Styrenes |
| title | Synthesis of copolymers of ethylene and (meth)acrylates or styrene by an original dual radical/catalytic mechanism |
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