Hierarchical porous titanium terephthalate based material with highly active sites for deep oxidative desulfurization
Deep desulfurization of fuel oil has received much attention due to the stringent demand of environmental regulations. In this work, we report that titanium terephthalate based materials with hierarchical porosity have been successfully synthesized for deep oxidative desulfurization of fuel oil. The...
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| Veröffentlicht in: | Microporous and mesoporous materials 2018-11, Vol.270, p.241-247 |
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| container_title | Microporous and mesoporous materials |
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| creator | Ye, Gan Sun, Yinyong Zhang, Dan Zhou, Wei Lancelot, Christine Rives, Alain Lamonier, Carole Xu, Wei |
| description | Deep desulfurization of fuel oil has received much attention due to the stringent demand of environmental regulations. In this work, we report that titanium terephthalate based materials with hierarchical porosity have been successfully synthesized for deep oxidative desulfurization of fuel oil. The catalytic results indicated that hierarchical porous titanium terephthalate based materials displayed superior catalytic performance in the ODS reactions of benzothiophene, dibenzothiophene and 4,6-dimethyldibenzothiophene. Additionally, this type of catalyst is also of great potential in other oxidative reactions involving the oxidation of phenethyl alcohol or cyclohexene. Such outstanding catalytic performance could be attributed to the presence of highly active sites and rich mesoporosity in hierarchical porous titanium terephthalate based materials.
[Display omitted]
•Hierarchical porous titanium terephthalate based materials have been synthesized.•Relatively high synthetic temperature is beneficial for producing the materials with rich mesoporosity.•Ti-BDC-180 displayed superior catalytic performance in oxidation reactions.•Ti-BDC-180 is a heterogeneous catalyst and can be reused. |
| doi_str_mv | 10.1016/j.micromeso.2018.05.025 |
| format | Article |
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[Display omitted]
•Hierarchical porous titanium terephthalate based materials have been synthesized.•Relatively high synthetic temperature is beneficial for producing the materials with rich mesoporosity.•Ti-BDC-180 displayed superior catalytic performance in oxidation reactions.•Ti-BDC-180 is a heterogeneous catalyst and can be reused.</description><identifier>ISSN: 1387-1811</identifier><identifier>EISSN: 1873-3093</identifier><identifier>DOI: 10.1016/j.micromeso.2018.05.025</identifier><language>eng</language><publisher>Elsevier Inc</publisher><subject>Catalysis ; Chemical Sciences ; Dibenzothiophene ; Hierarchical ; Material chemistry ; MOFs ; Organic chemistry ; Oxidation desulfurization ; Titanium terephthalate</subject><ispartof>Microporous and mesoporous materials, 2018-11, Vol.270, p.241-247</ispartof><rights>2018 Elsevier Inc.</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c435t-fe05ca63dd960bc785603ef5e881a0d1da8c9fa2a81a1ca74f346dd2e84a93433</citedby><cites>FETCH-LOGICAL-c435t-fe05ca63dd960bc785603ef5e881a0d1da8c9fa2a81a1ca74f346dd2e84a93433</cites><orcidid>0000-0002-5570-5089 ; 0000-0003-0092-824X ; 0000-0002-5100-8139 ; 0000-0002-0691-0721 ; 0000-0003-3641-1429</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.micromeso.2018.05.025$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>230,315,781,785,886,3551,27929,27930,46000</link.rule.ids><backlink>$$Uhttps://hal.science/hal-01869516$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Ye, Gan</creatorcontrib><creatorcontrib>Sun, Yinyong</creatorcontrib><creatorcontrib>Zhang, Dan</creatorcontrib><creatorcontrib>Zhou, Wei</creatorcontrib><creatorcontrib>Lancelot, Christine</creatorcontrib><creatorcontrib>Rives, Alain</creatorcontrib><creatorcontrib>Lamonier, Carole</creatorcontrib><creatorcontrib>Xu, Wei</creatorcontrib><title>Hierarchical porous titanium terephthalate based material with highly active sites for deep oxidative desulfurization</title><title>Microporous and mesoporous materials</title><description>Deep desulfurization of fuel oil has received much attention due to the stringent demand of environmental regulations. In this work, we report that titanium terephthalate based materials with hierarchical porosity have been successfully synthesized for deep oxidative desulfurization of fuel oil. The catalytic results indicated that hierarchical porous titanium terephthalate based materials displayed superior catalytic performance in the ODS reactions of benzothiophene, dibenzothiophene and 4,6-dimethyldibenzothiophene. Additionally, this type of catalyst is also of great potential in other oxidative reactions involving the oxidation of phenethyl alcohol or cyclohexene. Such outstanding catalytic performance could be attributed to the presence of highly active sites and rich mesoporosity in hierarchical porous titanium terephthalate based materials.
[Display omitted]
•Hierarchical porous titanium terephthalate based materials have been synthesized.•Relatively high synthetic temperature is beneficial for producing the materials with rich mesoporosity.•Ti-BDC-180 displayed superior catalytic performance in oxidation reactions.•Ti-BDC-180 is a heterogeneous catalyst and can be reused.</description><subject>Catalysis</subject><subject>Chemical Sciences</subject><subject>Dibenzothiophene</subject><subject>Hierarchical</subject><subject>Material chemistry</subject><subject>MOFs</subject><subject>Organic chemistry</subject><subject>Oxidation desulfurization</subject><subject>Titanium terephthalate</subject><issn>1387-1811</issn><issn>1873-3093</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNqFkE1v1DAQhqMKpJbCb6ivPSR44nw4x1UFbKWVuLRna2pPyKyS9cp2Fsqvx8uiXjnN1_u-0jxFcQeyAgnd5321sA1-oeirWoKuZFvJur0qbkD3qlRyUO9yr3Rfgga4Lj7EuJcSeqjhpli3TAGDndjiLI4--DWKxAkPvC4iUaDjlCacMZF4wUhOLLkNnMU_OU1i4h_T_CrQJj6RiJwoitEH4YiOwv9ih38PjuI6j2vg33n2h4_F-xHnSJ_-1dvi-euXp4dtufv-7fFhsytto9pUjiRbi51ybujki-1120lFY0taA0oHDrUdRqwxj2Cxb0bVdM7VpBscVKPUbXF_yc0fmGPgBcOr8chmu9mZ8y7z6oYWuhNkbX_RZpgxBhrfDCDNmbTZmzfS5kzayNZk0tm5uTgpv3LKPE20TAdLjgPZZJzn_2b8Afqpj20</recordid><startdate>20181101</startdate><enddate>20181101</enddate><creator>Ye, Gan</creator><creator>Sun, Yinyong</creator><creator>Zhang, Dan</creator><creator>Zhou, Wei</creator><creator>Lancelot, Christine</creator><creator>Rives, Alain</creator><creator>Lamonier, Carole</creator><creator>Xu, Wei</creator><general>Elsevier Inc</general><general>Elsevier</general><scope>AAYXX</scope><scope>CITATION</scope><scope>1XC</scope><scope>VOOES</scope><orcidid>https://orcid.org/0000-0002-5570-5089</orcidid><orcidid>https://orcid.org/0000-0003-0092-824X</orcidid><orcidid>https://orcid.org/0000-0002-5100-8139</orcidid><orcidid>https://orcid.org/0000-0002-0691-0721</orcidid><orcidid>https://orcid.org/0000-0003-3641-1429</orcidid></search><sort><creationdate>20181101</creationdate><title>Hierarchical porous titanium terephthalate based material with highly active sites for deep oxidative desulfurization</title><author>Ye, Gan ; Sun, Yinyong ; Zhang, Dan ; Zhou, Wei ; Lancelot, Christine ; Rives, Alain ; Lamonier, Carole ; Xu, Wei</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c435t-fe05ca63dd960bc785603ef5e881a0d1da8c9fa2a81a1ca74f346dd2e84a93433</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Catalysis</topic><topic>Chemical Sciences</topic><topic>Dibenzothiophene</topic><topic>Hierarchical</topic><topic>Material chemistry</topic><topic>MOFs</topic><topic>Organic chemistry</topic><topic>Oxidation desulfurization</topic><topic>Titanium terephthalate</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ye, Gan</creatorcontrib><creatorcontrib>Sun, Yinyong</creatorcontrib><creatorcontrib>Zhang, Dan</creatorcontrib><creatorcontrib>Zhou, Wei</creatorcontrib><creatorcontrib>Lancelot, Christine</creatorcontrib><creatorcontrib>Rives, Alain</creatorcontrib><creatorcontrib>Lamonier, Carole</creatorcontrib><creatorcontrib>Xu, Wei</creatorcontrib><collection>CrossRef</collection><collection>Hyper Article en Ligne (HAL)</collection><collection>Hyper Article en Ligne (HAL) (Open Access)</collection><jtitle>Microporous and mesoporous materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ye, Gan</au><au>Sun, Yinyong</au><au>Zhang, Dan</au><au>Zhou, Wei</au><au>Lancelot, Christine</au><au>Rives, Alain</au><au>Lamonier, Carole</au><au>Xu, Wei</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Hierarchical porous titanium terephthalate based material with highly active sites for deep oxidative desulfurization</atitle><jtitle>Microporous and mesoporous materials</jtitle><date>2018-11-01</date><risdate>2018</risdate><volume>270</volume><spage>241</spage><epage>247</epage><pages>241-247</pages><issn>1387-1811</issn><eissn>1873-3093</eissn><abstract>Deep desulfurization of fuel oil has received much attention due to the stringent demand of environmental regulations. In this work, we report that titanium terephthalate based materials with hierarchical porosity have been successfully synthesized for deep oxidative desulfurization of fuel oil. The catalytic results indicated that hierarchical porous titanium terephthalate based materials displayed superior catalytic performance in the ODS reactions of benzothiophene, dibenzothiophene and 4,6-dimethyldibenzothiophene. Additionally, this type of catalyst is also of great potential in other oxidative reactions involving the oxidation of phenethyl alcohol or cyclohexene. Such outstanding catalytic performance could be attributed to the presence of highly active sites and rich mesoporosity in hierarchical porous titanium terephthalate based materials.
[Display omitted]
•Hierarchical porous titanium terephthalate based materials have been synthesized.•Relatively high synthetic temperature is beneficial for producing the materials with rich mesoporosity.•Ti-BDC-180 displayed superior catalytic performance in oxidation reactions.•Ti-BDC-180 is a heterogeneous catalyst and can be reused.</abstract><pub>Elsevier Inc</pub><doi>10.1016/j.micromeso.2018.05.025</doi><tpages>7</tpages><orcidid>https://orcid.org/0000-0002-5570-5089</orcidid><orcidid>https://orcid.org/0000-0003-0092-824X</orcidid><orcidid>https://orcid.org/0000-0002-5100-8139</orcidid><orcidid>https://orcid.org/0000-0002-0691-0721</orcidid><orcidid>https://orcid.org/0000-0003-3641-1429</orcidid><oa>free_for_read</oa></addata></record> |
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| ispartof | Microporous and mesoporous materials, 2018-11, Vol.270, p.241-247 |
| issn | 1387-1811 1873-3093 |
| language | eng |
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| source | ScienceDirect Journals (5 years ago - present) |
| subjects | Catalysis Chemical Sciences Dibenzothiophene Hierarchical Material chemistry MOFs Organic chemistry Oxidation desulfurization Titanium terephthalate |
| title | Hierarchical porous titanium terephthalate based material with highly active sites for deep oxidative desulfurization |
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