Synthesis and structural characterization of a diruthenium pentalene complex, [Cp∗Ru{(Cp∗Ru)2B6H14}(Cp∗Ru)]

  Treatment of nido -[1,2-(Cp*Ru) 2 ( μ -H) 2 B 3 H 7 ], 1 with five equivalents of Te powder led to the isolation of diruthenium pentalene analogue [ ( Cp*Ru ) { ( Cp*Ru ) 2 B 6 H 14 } ( RuCp* ) ] , 2 and a metal indenyl complex [ ( Cp*Ru ) 2 B 2 H 6 C 6 H 3 ( CH 3 ) ], 3 . The [ ( Cp*Ru ) 2 B 6 H...

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Veröffentlicht in:	Journal of chemical sciences (Bangalore, India) India), 2018-07, Vol.130 (7), p.1-9, Article 89
Hauptverfasser:	Joseph, Benson, Barik, Subrat Kumar, Sinha, Soumya Kumar, Roisnel, Thierry, Ghosh, Sundargopal
Format:	Artikel
Sprache:	eng
Schlagworte:	Boron Chemical Sciences Chemistry Chemistry and Materials Science Chemistry/Food Science Coordination compounds Crystallography Density functional theory Electrons Ligands Molecular chains Molecular orbitals Regular Article Structural analysis
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