Solvothermal flow synthesis of zinc phosphate pigment
Synthesis of phase pure hopeite pigment through a solvothermal flow method is reported here for the first time. The products show two-step dehydration behaviour from thermogravimetric analysis (TGA), and a higher degree of purity and homogeniety than commercial zinc phosphate pigment. By increasing...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2018, Vol.47 (27), p.9136-9142 |
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| container_end_page | 9142 |
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| container_issue | 27 |
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| container_title | Dalton transactions : an international journal of inorganic chemistry |
| container_volume | 47 |
| creator | Broge, N L N Philippot, G Iversen, B B Aymonier, C |
| description | Synthesis of phase pure hopeite pigment through a solvothermal flow method is reported here for the first time. The products show two-step dehydration behaviour from thermogravimetric analysis (TGA), and a higher degree of purity and homogeniety than commercial zinc phosphate pigment. By increasing the reaction temperature stepwise from room temperature to 350 °C it was possible to decrease the size of the individual crystallite sheets and to tune their packing into larger assemblies. The conversion of reactants to product proved to be significantly higher at increased temperature with a measured yield of 98.7% at 250 °C versus 85.4% at room temperature. The synthesis route demonstrated here is environmentally sustainable, increases cost-efficiency through minimization of waste, and is compatible with a scale-up strategy. |
| doi_str_mv | 10.1039/c8dt01476k |
| format | Article |
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The products show two-step dehydration behaviour from thermogravimetric analysis (TGA), and a higher degree of purity and homogeniety than commercial zinc phosphate pigment. By increasing the reaction temperature stepwise from room temperature to 350 °C it was possible to decrease the size of the individual crystallite sheets and to tune their packing into larger assemblies. The conversion of reactants to product proved to be significantly higher at increased temperature with a measured yield of 98.7% at 250 °C versus 85.4% at room temperature. The synthesis route demonstrated here is environmentally sustainable, increases cost-efficiency through minimization of waste, and is compatible with a scale-up strategy.</description><identifier>ISSN: 1477-9226</identifier><identifier>EISSN: 1477-9234</identifier><identifier>DOI: 10.1039/c8dt01476k</identifier><identifier>PMID: 29946581</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Chemical Sciences ; Dehydration ; Material chemistry ; Synthesis ; Thermogravimetric analysis ; Zinc phosphate</subject><ispartof>Dalton transactions : an international journal of inorganic chemistry, 2018, Vol.47 (27), p.9136-9142</ispartof><rights>Copyright Royal Society of Chemistry 2018</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c349t-789ece99254675806e16af55d5f6a055ba0e6aca63b5d31ce5ed9a448faf2d403</citedby><cites>FETCH-LOGICAL-c349t-789ece99254675806e16af55d5f6a055ba0e6aca63b5d31ce5ed9a448faf2d403</cites><orcidid>0000-0002-4632-1024 ; 0000-0003-1775-0716 ; 0000-0001-8560-1240</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,776,780,881,4010,27900,27901,27902</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/29946581$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://hal.science/hal-01845499$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Broge, N L N</creatorcontrib><creatorcontrib>Philippot, G</creatorcontrib><creatorcontrib>Iversen, B B</creatorcontrib><creatorcontrib>Aymonier, C</creatorcontrib><title>Solvothermal flow synthesis of zinc phosphate pigment</title><title>Dalton transactions : an international journal of inorganic chemistry</title><addtitle>Dalton Trans</addtitle><description>Synthesis of phase pure hopeite pigment through a solvothermal flow method is reported here for the first time. The products show two-step dehydration behaviour from thermogravimetric analysis (TGA), and a higher degree of purity and homogeniety than commercial zinc phosphate pigment. By increasing the reaction temperature stepwise from room temperature to 350 °C it was possible to decrease the size of the individual crystallite sheets and to tune their packing into larger assemblies. The conversion of reactants to product proved to be significantly higher at increased temperature with a measured yield of 98.7% at 250 °C versus 85.4% at room temperature. The synthesis route demonstrated here is environmentally sustainable, increases cost-efficiency through minimization of waste, and is compatible with a scale-up strategy.</description><subject>Chemical Sciences</subject><subject>Dehydration</subject><subject>Material chemistry</subject><subject>Synthesis</subject><subject>Thermogravimetric analysis</subject><subject>Zinc phosphate</subject><issn>1477-9226</issn><issn>1477-9234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><recordid>eNpdkDtPwzAUhS0EoqWw8ANQJBZACvgde6zKo4hKDJTZch2bpiRxiJOi8utJKHRgug99OvfcA8ApgtcIEnljRNpARBP-vgeGXU1iiQnd3_WYD8BRCCsIMYYMH4IBlpJyJtAQsBefr32ztHWh88jl_jMKm7KbQxYi76KvrDRRtfShWurGRlX2VtiyOQYHTufBnvzWEXi9v5tPpvHs-eFxMp7FhlDZxImQ1lgpMaM8YQJyi7h2jKXMcQ0ZW2houTaakwVLCTKW2VRqSoXTDqcUkhG43Oouda6qOit0vVFeZ2o6nql-B5GgjEq5Rh17sWWr2n-0NjSqyIKxea5L69ugMORQJJBQ3KHn_9CVb-uy-6Snks4A4_3xqy1lah9Cbd3OAYKqD15NxO38J_inDj77lWwXhU136F_S5BsZenwV</recordid><startdate>2018</startdate><enddate>2018</enddate><creator>Broge, N L N</creator><creator>Philippot, G</creator><creator>Iversen, B B</creator><creator>Aymonier, C</creator><general>Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope><scope>7X8</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0002-4632-1024</orcidid><orcidid>https://orcid.org/0000-0003-1775-0716</orcidid><orcidid>https://orcid.org/0000-0001-8560-1240</orcidid></search><sort><creationdate>2018</creationdate><title>Solvothermal flow synthesis of zinc phosphate pigment</title><author>Broge, N L N ; Philippot, G ; Iversen, B B ; Aymonier, C</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c349t-789ece99254675806e16af55d5f6a055ba0e6aca63b5d31ce5ed9a448faf2d403</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Chemical Sciences</topic><topic>Dehydration</topic><topic>Material chemistry</topic><topic>Synthesis</topic><topic>Thermogravimetric analysis</topic><topic>Zinc phosphate</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Broge, N L N</creatorcontrib><creatorcontrib>Philippot, G</creatorcontrib><creatorcontrib>Iversen, B B</creatorcontrib><creatorcontrib>Aymonier, C</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>MEDLINE - Academic</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Broge, N L N</au><au>Philippot, G</au><au>Iversen, B B</au><au>Aymonier, C</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Solvothermal flow synthesis of zinc phosphate pigment</atitle><jtitle>Dalton transactions : an international journal of inorganic chemistry</jtitle><addtitle>Dalton Trans</addtitle><date>2018</date><risdate>2018</risdate><volume>47</volume><issue>27</issue><spage>9136</spage><epage>9142</epage><pages>9136-9142</pages><issn>1477-9226</issn><eissn>1477-9234</eissn><abstract>Synthesis of phase pure hopeite pigment through a solvothermal flow method is reported here for the first time. The products show two-step dehydration behaviour from thermogravimetric analysis (TGA), and a higher degree of purity and homogeniety than commercial zinc phosphate pigment. By increasing the reaction temperature stepwise from room temperature to 350 °C it was possible to decrease the size of the individual crystallite sheets and to tune their packing into larger assemblies. The conversion of reactants to product proved to be significantly higher at increased temperature with a measured yield of 98.7% at 250 °C versus 85.4% at room temperature. 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| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2018, Vol.47 (27), p.9136-9142 |
| issn | 1477-9226 1477-9234 |
| language | eng |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Chemical Sciences Dehydration Material chemistry Synthesis Thermogravimetric analysis Zinc phosphate |
| title | Solvothermal flow synthesis of zinc phosphate pigment |
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