Transition metal-free stereospecific access to (E)-(1-fluoro-2-arylvinyl)phosphine borane complexes

This work describes the first transition metal-free stereospecific synthesis of (E)-(1-fluoro-2-arylvinyl)phosphine boranes through the addition of diarylphosphine-boranes to gem-bromofluoroalkenes in the presence of a base at room temperature. The reaction proceeds well under very mild conditions a...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2017, Vol.53 (12), p.2048-2051
Hauptverfasser:	Rousée, Kevin, Pannecoucke, Xavier, Gaumont, Annie-Claude, Lohier, Jean-François, Morlet-Savary, Fabrice, Lalevée, Jacques, Bouillon, Jean-Philippe, Couve-Bonnaire, Samuel, Lakhdar, Sami
Format:	Artikel
Sprache:	eng
Schlagworte:	Boranes Chemical Sciences Electron paramagnetic resonance Fluorination Formations Synthesis Vinyl radical
Online-Zugang:	Volltext
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