The Mackay‐Type Cluster [Cu43Al12](Cp)12: Open‐Shell 67‐Electron Superatom with Emerging Metal‐Like Electronic Structure

The paramagnetic cluster [Cu43Al12](Cp*)12 was obtained from the reaction of [CuMes]5 and [AlCp*]4 (Cp*=η5‐C5Me5; Mes=mesityl). This all‐hydrocarbon ligand‐stabilized M55 magic atom‐number cluster features a Mackay‐type nested icosahedral structure. Its open‐shell 67‐electron superatom configuration...

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Veröffentlicht in:	Angewandte Chemie International Edition 2018-10, Vol.57 (44), p.14630-14634
Hauptverfasser:	Weßing, Jana, Ganesamoorthy, Chelladurai, Kahlal, Samia, Marchal, Rémi, Gemel, Christian, Cador, Olivier, Da Silva, Augusto C. H., Da Silva, Juarez L. F., Saillard, Jean‐Yves, Fischer, Roland A.
Format:	Artikel
Sprache:	eng
Schlagworte:	aluminum Chemical Sciences Clusters Conduction Conduction bands Coordination chemistry copper Electronic structure Icosahedral phase Jellium Ligands Magnetism superatoms
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