Corrosion behaviour in saline solution of pulsed‐electrodeposited zinc‐nickel‐ceria nanocomposite coatings

Pure Zn‐Ni and Zn–Ni–ceria (CeO2) nanocomposite coatings were deposited onto steel substrates using pulse electrodeposition process from an acidic bath combined with preliminary sonication. Influences of different parameters such as pulse parameters, addition of nanoparticles in the electroplating b...

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Veröffentlicht in:Materials and corrosion 2017-10, Vol.68 (10), p.1129-1142
Hauptverfasser: Exbrayat, L., Rébéré, C., Ndong Eyame, R., Steyer, P., Creus, J.
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container_end_page 1142
container_issue 10
container_start_page 1129
container_title Materials and corrosion
container_volume 68
creator Exbrayat, L.
Rébéré, C.
Ndong Eyame, R.
Steyer, P.
Creus, J.
description Pure Zn‐Ni and Zn–Ni–ceria (CeO2) nanocomposite coatings were deposited onto steel substrates using pulse electrodeposition process from an acidic bath combined with preliminary sonication. Influences of different parameters such as pulse parameters, addition of nanoparticles in the electroplating bath, use of sonication to ensure their dispersion, were studied in terms of morphology, composition, and corrosion behaviour in saline solution. Results revealed a strong influence of the electrodeposition parameters on the corrosion behaviour of the Zn‐Ni coatings. Incorporation of ceria nanoparticles is enhanced for the very short duration of the pulse due to the refinement of the microstructure. It was proved that composite coatings present an enhanced corrosion behaviour, while sonification does not afford a further improvement. Pure Zn‐Ni and Zn–Ni–ceria nanocomposite coatings were deposited onto steel substrates using pulse electrodeposition process from an acidic bath combined with preliminary sonication. Influences of pulse parameters, addition of nanoparticles in the electroplating bath, use of sonication to ensure their dispersion, were studied in terms of morphology, composition and corrosion behaviour in saline solution.
doi_str_mv 10.1002/maco.201709419
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Influences of different parameters such as pulse parameters, addition of nanoparticles in the electroplating bath, use of sonication to ensure their dispersion, were studied in terms of morphology, composition, and corrosion behaviour in saline solution. Results revealed a strong influence of the electrodeposition parameters on the corrosion behaviour of the Zn‐Ni coatings. Incorporation of ceria nanoparticles is enhanced for the very short duration of the pulse due to the refinement of the microstructure. It was proved that composite coatings present an enhanced corrosion behaviour, while sonification does not afford a further improvement. Pure Zn‐Ni and Zn–Ni–ceria nanocomposite coatings were deposited onto steel substrates using pulse electrodeposition process from an acidic bath combined with preliminary sonication. 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subjects Cerium oxides
Coated electrodes
Corrosion
EIS
Electrodeposition
Electroplating
Engineering Sciences
Materials
metal matrix composite
Nanocomposites
Nanoparticles
Nickel coatings
Saline solutions
Substrates
Zinc coatings
Zn‐Ni alloys
title Corrosion behaviour in saline solution of pulsed‐electrodeposited zinc‐nickel‐ceria nanocomposite coatings
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