Supramolecular Assembly with Calix[6]arene and Copper Ions − Formation of a Novel Tetranuclear Core Exhibiting Unusual Redox Properties and Catecholase Activity

The supramolecular biomimetic chemistry based on calix[6]arene N‐ligands has been further explored. A tris(imidazole)CuI complex was treated with 1 mol‐equiv. of cuprous ion under dioxygen to produce a tetranuclear cupric species. X‐ray structural determination of this novel Cu4 complex revealed tha...

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Veröffentlicht in:	European journal of inorganic chemistry 2002-08, Vol.2002 (8), p.2007-2014
Hauptverfasser:	Sénèque, Olivier, Campion, Morgan, Douziech, Bénédicte, Giorgi, Michel, Rivière, Eric, Journaux, Yves, Mest, Yves Le, Reinaud, Olivia
Format:	Artikel
Sprache:	eng
Schlagworte:	Bioinorganic chemistry Calixarenes Chemical Sciences Copper Electrochemistry N Ligands
Online-Zugang:	Volltext
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