Activation and Functionalization of Vinylic C−F Bonds by Transition Metal Compounds: The Factors Determining Reactions between Nucleophiles and a (Perfluorovinyl)diiron(I) Complex; Syntheses of Diiron Derivatives Containing New C−N, C−S, C−H and C−O Bonds

The reactions between alcohols ROH (R = Me, Et) and RR(OH)2 (RR = CH2−CH2) and the [perfluoro(sulfanyl)vinyl]diiron complex [{Fe(CO)3}2{µ‐C(SMe)(CF3)CβCαF2}] (1) in THF at room temperature involve substitution at the Cα atom to give new (alkoxymethylene)thiaferracyclobutadiene compounds [{Fe(CO)3}2{...

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Veröffentlicht in:	European journal of inorganic chemistry 2002-03, Vol.2002 (3), p.639-657
Hauptverfasser:	de Cadenet, Karine Guennou, Rumin, René, Pétillon, François Y., Yufit, Dmitri S., Muir, Kenneth W.
Format:	Artikel
Sprache:	eng
Schlagworte:	Carbenes Chemical Sciences C−F activation C−N C−N, C−S coupling C−S coupling Nucleophiles Vinyl complexes
Online-Zugang:	Volltext
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