O-O bond cleavage by electrochemical reduction of a side-on peroxo dicopper model of hemocyanin

The redox properties of the μ-η2:η2 peroxo complex [Cu2(H6M4h)(O2)]2+ were elucidated. This study constitutes the first full electrochemical and spectroelectrochemical characterization of a side-on peroxo Cu2:O2 bioinorganic model complex. The peroxo complex is irreversibly reduced in a two- electro...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2018
Hauptverfasser:	López, Isidoro, Porras Gutiérrez, Ana Gabriela, Douziech, Bénédicte, Wojcik, Laurianne, Le Mest, Yves, Kodera, Masahito, Le Poul, Nicolas
Format:	Artikel
Sprache:	eng
Schlagworte:	Analytical chemistry Chemical Sciences Coordination chemistry Other
Online-Zugang:	Volltext
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