Asymmetric Azido−Copper(II) Bridges:  Ferro- or Antiferromagnetic? Experimental and Theoretical Magneto−Structural Studies

Reaction of NaN3 with the [CuII(tn)]2+ ion (tn = 1,3-diaminopropane) in basic aqueous solution yields the azido-bridged complex of formula [Cu2(tn)2(N3)4] (1), which is characterized by X-ray crystallography. The structure of 1 is made up of dinuclear neutral complexes, of formula [Cu2(tn)2(N3)4], r...

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Veröffentlicht in:	Inorganic chemistry 2005-07, Vol.44 (15), p.5501-5508
Hauptverfasser:	Triki, Smaïl, Gómez-García, Carlos J, Ruiz, Eliseo, Sala-Pala, Jean
Format:	Artikel
Sprache:	eng
Schlagworte:	Azides - chemistry Chemical Sciences Copper - chemistry Crystallography, X-Ray Iron - chemistry Magnetics Models, Chemical Models, Molecular Molecular Structure Organometallic Compounds - chemical synthesis Organometallic Compounds - chemistry Temperature
Online-Zugang:	Volltext
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