Structure of Pb‐rich chabournéite from Jas Roux, France
The crystal structure of a specimen of `Pb‐rich' chabournéite from Jas Roux, Hautes‐Alpes, France, with the chemical formula obtained by electron microprobe analysis of Ag0.04 (1)Tl2.15 (2)Pb0.64 (1)Sb5.12 (1)As5.05 (1)S17.32 (5), has been solved by X‐ray single‐crystal diffraction on the basis...
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| Veröffentlicht in: | Acta crystallographica Section B, Structural science, crystal engineering and materials Structural science, crystal engineering and materials, 2015-02, Vol.71 (1), p.81-88 |
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| creator | Biagioni, Cristian Moëlo, Yves Favreau, Georges Bourgoin, Vincent Boulliard, Jean‐Claude |
| description | The crystal structure of a specimen of `Pb‐rich' chabournéite from Jas Roux, Hautes‐Alpes, France, with the chemical formula obtained by electron microprobe analysis of Ag0.04 (1)Tl2.15 (2)Pb0.64 (1)Sb5.12 (1)As5.05 (1)S17.32 (5), has been solved by X‐ray single‐crystal diffraction on the basis of 36 550 observed reflections (with Fo > 4σFo) with a final R1 = 0.074. Pb‐rich chabournéite is triclinic P1, with unit‐cell parameters a = 8.5197 (4), b = 42.461 (2), c = 16.293 (8) Å, α = 83.351 (2), β = 90.958 (2), γ = 84.275 (2)°, V = 5823 (3) Å3. Its structural formula is close to [Tl2(Pb0.8Tl0.1Sb1.1)](Sb4.1As4.9)S17, with Z = 8. Its crystal structure is formed by the alternation of two pairs of slabs along the b axis, deriving from the SnS and PbS archetypes, respectively. 104 independent cation sites and 136 S sites occur in the unit cell. Slab interfaces show the alternation, along c, of Tl sites, ninefold coordinated, with Pb, Sb or mixed/split (Pb,Sb) and (Pb,Tl) sites. Within the slabs, 72 independent M3+ sites (M3+ = As, Sb) occur. Considering M3+—S bond distances shorter than 2.70 Å, MS3 triangular pyramidal groups are condensed according to various MmSn chain fragments (`polymers'). The solution of the crystal structure of chabournéite allows its comparison with the closely related homeotypes protochabournéite and dalnegroite. |
| doi_str_mv | 10.1107/S2052520614028157 |
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Pb‐rich chabournéite is triclinic P1, with unit‐cell parameters a = 8.5197 (4), b = 42.461 (2), c = 16.293 (8) Å, α = 83.351 (2), β = 90.958 (2), γ = 84.275 (2)°, V = 5823 (3) Å3. Its structural formula is close to [Tl2(Pb0.8Tl0.1Sb1.1)](Sb4.1As4.9)S17, with Z = 8. Its crystal structure is formed by the alternation of two pairs of slabs along the b axis, deriving from the SnS and PbS archetypes, respectively. 104 independent cation sites and 136 S sites occur in the unit cell. Slab interfaces show the alternation, along c, of Tl sites, ninefold coordinated, with Pb, Sb or mixed/split (Pb,Sb) and (Pb,Tl) sites. Within the slabs, 72 independent M3+ sites (M3+ = As, Sb) occur. Considering M3+—S bond distances shorter than 2.70 Å, MS3 triangular pyramidal groups are condensed according to various MmSn chain fragments (`polymers'). The solution of the crystal structure of chabournéite allows its comparison with the closely related homeotypes protochabournéite and dalnegroite.</description><identifier>ISSN: 2052-5206</identifier><identifier>ISSN: 2052-5192</identifier><identifier>EISSN: 2052-5206</identifier><identifier>DOI: 10.1107/S2052520614028157</identifier><identifier>PMID: 25643719</identifier><language>eng</language><publisher>5 Abbey Square, Chester, Cheshire CH1 2HU, England: International Union of Crystallography</publisher><subject>Alternations ; Antimony ; Cations ; chabournéite ; Condensed Matter ; Crystal structure ; Fragments ; geochemical behavior ; homeotypes ; hydrothermal ore deposits ; Lead (metal) ; Materials Science ; Physics ; Slabs ; Unit cell ; X-rays</subject><ispartof>Acta crystallographica Section B, Structural science, crystal engineering and materials, 2015-02, Vol.71 (1), p.81-88</ispartof><rights>International Union of Crystallography, 2015</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a5123-e1b6eee307cf8f8a7409665dec9f5f2a0807e7388f54f8cbf9b88b27f93dff883</citedby><cites>FETCH-LOGICAL-a5123-e1b6eee307cf8f8a7409665dec9f5f2a0807e7388f54f8cbf9b88b27f93dff883</cites><orcidid>0000-0002-3917-7984</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1107%2FS2052520614028157$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1107%2FS2052520614028157$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>230,314,776,780,881,1411,27901,27902,45550,45551</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/25643719$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink><backlink>$$Uhttps://hal.science/hal-01725858$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Biagioni, Cristian</creatorcontrib><creatorcontrib>Moëlo, Yves</creatorcontrib><creatorcontrib>Favreau, Georges</creatorcontrib><creatorcontrib>Bourgoin, Vincent</creatorcontrib><creatorcontrib>Boulliard, Jean‐Claude</creatorcontrib><title>Structure of Pb‐rich chabournéite from Jas Roux, France</title><title>Acta crystallographica Section B, Structural science, crystal engineering and materials</title><addtitle>Acta Crystallogr B Struct Sci Cryst Eng Mater</addtitle><description>The crystal structure of a specimen of `Pb‐rich' chabournéite from Jas Roux, Hautes‐Alpes, France, with the chemical formula obtained by electron microprobe analysis of Ag0.04 (1)Tl2.15 (2)Pb0.64 (1)Sb5.12 (1)As5.05 (1)S17.32 (5), has been solved by X‐ray single‐crystal diffraction on the basis of 36 550 observed reflections (with Fo > 4σFo) with a final R1 = 0.074. Pb‐rich chabournéite is triclinic P1, with unit‐cell parameters a = 8.5197 (4), b = 42.461 (2), c = 16.293 (8) Å, α = 83.351 (2), β = 90.958 (2), γ = 84.275 (2)°, V = 5823 (3) Å3. Its structural formula is close to [Tl2(Pb0.8Tl0.1Sb1.1)](Sb4.1As4.9)S17, with Z = 8. Its crystal structure is formed by the alternation of two pairs of slabs along the b axis, deriving from the SnS and PbS archetypes, respectively. 104 independent cation sites and 136 S sites occur in the unit cell. Slab interfaces show the alternation, along c, of Tl sites, ninefold coordinated, with Pb, Sb or mixed/split (Pb,Sb) and (Pb,Tl) sites. Within the slabs, 72 independent M3+ sites (M3+ = As, Sb) occur. Considering M3+—S bond distances shorter than 2.70 Å, MS3 triangular pyramidal groups are condensed according to various MmSn chain fragments (`polymers'). The solution of the crystal structure of chabournéite allows its comparison with the closely related homeotypes protochabournéite and dalnegroite.</description><subject>Alternations</subject><subject>Antimony</subject><subject>Cations</subject><subject>chabournéite</subject><subject>Condensed Matter</subject><subject>Crystal structure</subject><subject>Fragments</subject><subject>geochemical behavior</subject><subject>homeotypes</subject><subject>hydrothermal ore deposits</subject><subject>Lead (metal)</subject><subject>Materials Science</subject><subject>Physics</subject><subject>Slabs</subject><subject>Unit cell</subject><subject>X-rays</subject><issn>2052-5206</issn><issn>2052-5192</issn><issn>2052-5206</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><recordid>eNqFkc1KAzEUhYMoVqoP4EYG3ChYvUkmkzvu2uIvBYs_C1chkyZ0ZNrRpOPPzkfwNXwO38QncYaqiC5c3XD4zuHeHELWKexSCnLvgoFggkFCY2BIhVwgK43UabTFH-8WWQvhBgBqm2AJXSYtJpKYS5qukP2Lma_MrPI2Kl00zN6fX3xuxpEZ66ys_PTtNZ_ZyPlyEp3qEJ2X1eNOdOj11NhVsuR0Eeza52yTq8ODy_5xZ3B2dNLvDjpaUMY7lmaJtZaDNA4dahlDmiRiZE3qhGMaEKSVHNGJ2KHJXJohZky6lI-cQ-Rtsj3PHetC3fp8ov2TKnWujrsD1WhAJRMo8J7W7NacvfXlXWXDTE3yYGxR6Kktq6ColAgs4Rz-RxPBYgGIskY3f6E3zd_URzcUYBrHrKHonDK-DMFb970sBdVUpv5UVns2PpOrbGJH346vgmognQMPeWGf_k9U3ese6w0FSM4_AKmmnoY</recordid><startdate>201502</startdate><enddate>201502</enddate><creator>Biagioni, Cristian</creator><creator>Moëlo, Yves</creator><creator>Favreau, Georges</creator><creator>Bourgoin, Vincent</creator><creator>Boulliard, Jean‐Claude</creator><general>International Union of Crystallography</general><general>Blackwell Publishing Ltd</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7X8</scope><scope>7U5</scope><scope>L7M</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0002-3917-7984</orcidid></search><sort><creationdate>201502</creationdate><title>Structure of Pb‐rich chabournéite from Jas Roux, France</title><author>Biagioni, Cristian ; Moëlo, Yves ; Favreau, Georges ; Bourgoin, Vincent ; Boulliard, Jean‐Claude</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a5123-e1b6eee307cf8f8a7409665dec9f5f2a0807e7388f54f8cbf9b88b27f93dff883</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>Alternations</topic><topic>Antimony</topic><topic>Cations</topic><topic>chabournéite</topic><topic>Condensed Matter</topic><topic>Crystal structure</topic><topic>Fragments</topic><topic>geochemical behavior</topic><topic>homeotypes</topic><topic>hydrothermal ore deposits</topic><topic>Lead (metal)</topic><topic>Materials Science</topic><topic>Physics</topic><topic>Slabs</topic><topic>Unit cell</topic><topic>X-rays</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Biagioni, Cristian</creatorcontrib><creatorcontrib>Moëlo, Yves</creatorcontrib><creatorcontrib>Favreau, Georges</creatorcontrib><creatorcontrib>Bourgoin, Vincent</creatorcontrib><creatorcontrib>Boulliard, Jean‐Claude</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>MEDLINE - Academic</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>Acta crystallographica Section B, Structural science, crystal engineering and materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Biagioni, Cristian</au><au>Moëlo, Yves</au><au>Favreau, Georges</au><au>Bourgoin, Vincent</au><au>Boulliard, Jean‐Claude</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Structure of Pb‐rich chabournéite from Jas Roux, France</atitle><jtitle>Acta crystallographica Section B, Structural science, crystal engineering and materials</jtitle><addtitle>Acta Crystallogr B Struct Sci Cryst Eng Mater</addtitle><date>2015-02</date><risdate>2015</risdate><volume>71</volume><issue>1</issue><spage>81</spage><epage>88</epage><pages>81-88</pages><issn>2052-5206</issn><issn>2052-5192</issn><eissn>2052-5206</eissn><abstract>The crystal structure of a specimen of `Pb‐rich' chabournéite from Jas Roux, Hautes‐Alpes, France, with the chemical formula obtained by electron microprobe analysis of Ag0.04 (1)Tl2.15 (2)Pb0.64 (1)Sb5.12 (1)As5.05 (1)S17.32 (5), has been solved by X‐ray single‐crystal diffraction on the basis of 36 550 observed reflections (with Fo > 4σFo) with a final R1 = 0.074. Pb‐rich chabournéite is triclinic P1, with unit‐cell parameters a = 8.5197 (4), b = 42.461 (2), c = 16.293 (8) Å, α = 83.351 (2), β = 90.958 (2), γ = 84.275 (2)°, V = 5823 (3) Å3. Its structural formula is close to [Tl2(Pb0.8Tl0.1Sb1.1)](Sb4.1As4.9)S17, with Z = 8. Its crystal structure is formed by the alternation of two pairs of slabs along the b axis, deriving from the SnS and PbS archetypes, respectively. 104 independent cation sites and 136 S sites occur in the unit cell. Slab interfaces show the alternation, along c, of Tl sites, ninefold coordinated, with Pb, Sb or mixed/split (Pb,Sb) and (Pb,Tl) sites. Within the slabs, 72 independent M3+ sites (M3+ = As, Sb) occur. Considering M3+—S bond distances shorter than 2.70 Å, MS3 triangular pyramidal groups are condensed according to various MmSn chain fragments (`polymers'). The solution of the crystal structure of chabournéite allows its comparison with the closely related homeotypes protochabournéite and dalnegroite.</abstract><cop>5 Abbey Square, Chester, Cheshire CH1 2HU, England</cop><pub>International Union of Crystallography</pub><pmid>25643719</pmid><doi>10.1107/S2052520614028157</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0002-3917-7984</orcidid><oa>free_for_read</oa></addata></record> |
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| subjects | Alternations Antimony Cations chabournéite Condensed Matter Crystal structure Fragments geochemical behavior homeotypes hydrothermal ore deposits Lead (metal) Materials Science Physics Slabs Unit cell X-rays |
| title | Structure of Pb‐rich chabournéite from Jas Roux, France |
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