Desymmetrization on both ligands of pentaphenylcyclopentadienylhydrotris(indazolyl) borate ruthenium(II) complexes: Prototypes of organometallic molecular gears and motors

•Desymmetrized pentaphenylcyclopentadienyl tris(indazolyl)borate ruthenium organometallic complexes has been synthesized.•A tetraferrocenyl ruthenium-based molecular motor has been shown to exhibit controlled clockwise or counterclockwise unidirectional rotation.•We also present prototypes of molecu...

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Veröffentlicht in:	Coordination chemistry reviews 2015-03, Vol.287, p.79-88
Hauptverfasser:	Stefak, Roman, Sirven, Agnès M., Fukumoto, Sayo, Nakagawa, Hisako, Rapenne, Gwénaël
Format:	Artikel
Sprache:	eng
Schlagworte:	Desymmetrization Ferrocene Half-sandwich complexes Pentaphenylcyclopentadienyl ligand Physics Ruthenium Tris(indazolyl)borate ligand
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