Highly crystalline MOF-based materials grown on electrospun nanofibers
Supported Metal Organic Frameworks (MOFs) with a high specific surface area are of great interest for applications in gas storage, separation, sensing, and catalysis. In the present work we report the synthesis of a novel composite architecture of MOF materials supported on a flexible mat of electro...
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| Veröffentlicht in: | Nanoscale 2015-01, Vol.7 (13), p.5794-5802 |
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| container_title | Nanoscale |
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| creator | Bechelany, M Drobek, M Vallicari, C Abou Chaaya, A Julbe, A Miele, P |
| description | Supported Metal Organic Frameworks (MOFs) with a high specific surface area are of great interest for applications in gas storage, separation, sensing, and catalysis. In the present work we report the synthesis of a novel composite architecture of MOF materials supported on a flexible mat of electrospun nanofibers. The system, based on three-dimensional interwoven nanofibers, was designed by using a low-cost and scalable multistep synthesis protocol involving a combination of electrospinning and low-temperature atomic layer deposition of oxide materials, and their subsequent solvothermal conversion under either conventional or microwave-assisted heating. This highly versatile approach allows the production of different types of supported MOF crystals with controlled sizes, morphology, orientation and high accessibility. |
| doi_str_mv | 10.1039/c4nr06640e |
| format | Article |
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| source | Royal Society Of Chemistry Journals; Alma/SFX Local Collection |
| subjects | Chemical Sciences Crystal structure Electrospinning Heating Nanofibers Nanostructure Specific surface Synthesis Three dimensional |
| title | Highly crystalline MOF-based materials grown on electrospun nanofibers |
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