Synthesis of nanostructured ZnO/copper electrodes for nitrate electroreduction
In this work, ZnO thin films were electrochemically precipitated on copper electrode in zinc nitrate solution. The effects of the electrodeposition potential and time on the morphology, structure and electrocatalytic properties of ZnO towards nitrate reduction were studied. Surface morphology and st...
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Veröffentlicht in: | Desalination and water treatment 2017-10, Vol.94, p.156-163 |
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creator | Ahmed, N. Ait Hammache, H. Eyraud, M. Makhloufi, L. Gabouze, N. |
description | In this work, ZnO thin films were electrochemically precipitated on copper electrode in zinc nitrate solution. The effects of the electrodeposition potential and time on the morphology, structure and electrocatalytic properties of ZnO towards nitrate reduction were studied. Surface morphology and structure were investigated by scanning electron microscopy (SEM) and X-ray diffraction (XRD) techniques. Voltammetric results show that under optimized ZnO electrodeposition conditions, the ZnO/Cu modified electrode exhibits interesting electrocatalytic performance towards nitrate reduction. A well-defined and reproducible peak with maximum current density was obtained for ZnO/Cu electrode elaborated at –1 V for 20 min electrodeposition time. Kinetic study by chronoamperometry is indicative of ammonia formation. |
doi_str_mv | 10.5004/dwt.2017.21555 |
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Ait ; Hammache, H. ; Eyraud, M. ; Makhloufi, L. ; Gabouze, N.</creator><creatorcontrib>Ahmed, N. Ait ; Hammache, H. ; Eyraud, M. ; Makhloufi, L. ; Gabouze, N.</creatorcontrib><description>In this work, ZnO thin films were electrochemically precipitated on copper electrode in zinc nitrate solution. The effects of the electrodeposition potential and time on the morphology, structure and electrocatalytic properties of ZnO towards nitrate reduction were studied. Surface morphology and structure were investigated by scanning electron microscopy (SEM) and X-ray diffraction (XRD) techniques. Voltammetric results show that under optimized ZnO electrodeposition conditions, the ZnO/Cu modified electrode exhibits interesting electrocatalytic performance towards nitrate reduction. A well-defined and reproducible peak with maximum current density was obtained for ZnO/Cu electrode elaborated at –1 V for 20 min electrodeposition time. Kinetic study by chronoamperometry is indicative of ammonia formation.</description><identifier>ISSN: 1944-3986</identifier><identifier>ISSN: 1944-3994</identifier><identifier>EISSN: 1944-3986</identifier><identifier>DOI: 10.5004/dwt.2017.21555</identifier><language>eng</language><publisher>Elsevier Inc</publisher><subject>Chemical Sciences ; Electrocatalysis ; Electrodeposition ; Material chemistry ; Modified electrode ; Nitrate reduction ; ZnO</subject><ispartof>Desalination and water treatment, 2017-10, Vol.94, p.156-163</ispartof><rights>2017 Elsevier Inc.</rights><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c317t-8d4aeb139aedcfa34fe8f473407f061bbe074b6e18bf526add1d8f10828c32463</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,780,784,885,27924,27925</link.rule.ids><backlink>$$Uhttps://amu.hal.science/hal-01674713$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Ahmed, N. 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A well-defined and reproducible peak with maximum current density was obtained for ZnO/Cu electrode elaborated at –1 V for 20 min electrodeposition time. Kinetic study by chronoamperometry is indicative of ammonia formation.</description><subject>Chemical Sciences</subject><subject>Electrocatalysis</subject><subject>Electrodeposition</subject><subject>Material chemistry</subject><subject>Modified electrode</subject><subject>Nitrate reduction</subject><subject>ZnO</subject><issn>1944-3986</issn><issn>1944-3994</issn><issn>1944-3986</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNp1kEFLAzEQhYMoWGqvnvfqYbfJJrtJj6WoFRZ7UC9eQjaZ0EjdlCSt9N-bWhUvzmWGx_sG3kPomuCqwZhNzUeqakx4VZOmac7QiMwYK-lMtOd_7ks0ifEN52kYb1g9Qo9PhyGtIbpYeFsMavAxhZ1OuwCmeB1WU-23WwgFbECn4A3EwvpQDC4FleBHzubMOD9coQurNhEm33uMXu5unxfLslvdPyzmXakp4akUhinoCZ0pMNoqyiwIyzhlmFvckr4HzFnfAhG9bepWGUOMsASLWmhas5aO0c3p71pt5Da4dxUO0isnl_NOHjVMWs44oXuSvdXJq4OPMYD9BQiWx_JkLk8ey5Nf5WVAnADICfYOgozawaDBuJDjSuPdf-gn4Q52og</recordid><startdate>20171001</startdate><enddate>20171001</enddate><creator>Ahmed, N. 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Ait</creatorcontrib><creatorcontrib>Hammache, H.</creatorcontrib><creatorcontrib>Eyraud, M.</creatorcontrib><creatorcontrib>Makhloufi, L.</creatorcontrib><creatorcontrib>Gabouze, N.</creatorcontrib><collection>ScienceDirect Open Access Titles</collection><collection>Elsevier:ScienceDirect:Open Access</collection><collection>CrossRef</collection><collection>Hyper Article en Ligne (HAL)</collection><collection>Hyper Article en Ligne (HAL) (Open Access)</collection><jtitle>Desalination and water treatment</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ahmed, N. 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Voltammetric results show that under optimized ZnO electrodeposition conditions, the ZnO/Cu modified electrode exhibits interesting electrocatalytic performance towards nitrate reduction. A well-defined and reproducible peak with maximum current density was obtained for ZnO/Cu electrode elaborated at –1 V for 20 min electrodeposition time. Kinetic study by chronoamperometry is indicative of ammonia formation.</abstract><pub>Elsevier Inc</pub><doi>10.5004/dwt.2017.21555</doi><tpages>8</tpages><oa>free_for_read</oa></addata></record> |
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subjects | Chemical Sciences Electrocatalysis Electrodeposition Material chemistry Modified electrode Nitrate reduction ZnO |
title | Synthesis of nanostructured ZnO/copper electrodes for nitrate electroreduction |
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