Bromate electroreduction from sulfuric acid solution at rotating disk electrode: Experimental study

Our recent theoretical analysis of the bromate reduction from acidic media at rotating disk electrode (RDE) under steady-state conditions gave astonishing predictions for the current at the plateau of the voltammogram (called “the maximal current”, jmax) which deviated cardinally from those for the...

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Veröffentlicht in:	Electrochimica acta 2018-01, Vol.259, p.655-663
Hauptverfasser:	Modestov, A.D., Konev, D.V., Antipov, A.E., Petrov, M.M., Pichugov, R.D., Vorotyntsev, M.A.
Format:	Artikel
Sprache:	eng
Schlagworte:	Anomalous frequency region Autocatalytic cycle Bromates Bromine Bromine/bromide redox mediation Chemical Sciences Comproportionation reaction Computer simulation Dependence Diffusion limited current Diffusion rate Dilution Electroactivity Electrodes Experiments Mathematical models Maximal current Molecular chains Parameters Qualitative analysis Qualitative research Reduction Rotating disks Sulfuric acid
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