Ester-substituted cyclometallated rhodium and iridium coordination assemblies with π-bonded dioxolene ligand: synthesis, structures and luminescent properties

Ester-substituted cyclometallated rhodium and iridium coordination assemblies with π-bonded dioxolene ligand: synthesis, structures and luminescent properties

A series of functionalized cyclometallated rhodium and iridium coordination assemblies 2–7 displaying a π-bonded dioxolene ligand is described. The X-ray molecular structures of two of the above compounds showed the formation of a 1D supramolecular chain mediated by π–π interactions among individual...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:RSC advances 2014, Vol.4 (45), p.23740-23748
Hauptverfasser: Damas, Aurelie, Sesolis, Hugo, Rager, Marie Noelle, Chamoreau, Lise Marie, Gullo, Maria Pia, Barbieri, Andrea, Amouri, Hani
Format: Artikel
Sprache:eng
Schlagworte:
Chemical Sciences
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 23748
container_issue 45
container_start_page 23740
container_title RSC advances
container_volume 4
creator Damas, Aurelie
Sesolis, Hugo
Rager, Marie Noelle
Chamoreau, Lise Marie
Gullo, Maria Pia
Barbieri, Andrea
Amouri, Hani
description A series of functionalized cyclometallated rhodium and iridium coordination assemblies 2–7 displaying a π-bonded dioxolene ligand is described. The X-ray molecular structures of two of the above compounds showed the formation of a 1D supramolecular chain mediated by π–π interactions among individual units. The luminescent properties of these compounds are presented and discussed. These results show that the stacking interactions are retained also in solution and emission from excited dimeric species is observed.
doi_str_mv 10.1039/C4RA01185F
format Article
fullrecord <record><control><sourceid>hal_cross</sourceid><recordid>TN_cdi_hal_primary_oai_HAL_hal_01662106v1</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>oai_HAL_hal_01662106v1</sourcerecordid><originalsourceid>FETCH-LOGICAL-c265t-84c7db67f44e0621fdda57e6533cc0ba23b242b8250685b96f15f4ff6724c3343</originalsourceid><addsrcrecordid>eNpNkc1KAzEUhYMoWGo3PkG2iqNJJpNp3ZXSWqEgiK6H_I0TySQlyajd-SY-kq_kjBX1bu65l3O-zQHgFKNLjPLZ1YLezxHG02J1AEYEUZYRxGaH__QxmMT4jPphBSYMj8DHMiYdstiJmEzqklZQ7qT1rU7cWj7cofHKdC3kTkETzLeW3gdlHE_GO8hj1K2wRkf4alIDP98z4Z3qo8r4N2-109Capz5_DePOpUZHEy9gTKGTqQt9bEDbrjVOR6ldgtvgtzqknngCjmpuo5787DF4XC0fFutsc3dzu5hvMklYkbIplaUSrKwp1YgRXCvFi1KzIs-lRIKTXBBKxJQUiE0LMWM1Lmpa16wkVOY5zcfgbM9tuK22wbQ87CrPTbWeb6rhhzDruYi94N57vvfK4GMMuv4NYFQNTVR_TeRfay1_7A</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Ester-substituted cyclometallated rhodium and iridium coordination assemblies with π-bonded dioxolene ligand: synthesis, structures and luminescent properties</title><source>Royal Society Of Chemistry Journals 2008-</source><creator>Damas, Aurelie ; Sesolis, Hugo ; Rager, Marie Noelle ; Chamoreau, Lise Marie ; Gullo, Maria Pia ; Barbieri, Andrea ; Amouri, Hani</creator><creatorcontrib>Damas, Aurelie ; Sesolis, Hugo ; Rager, Marie Noelle ; Chamoreau, Lise Marie ; Gullo, Maria Pia ; Barbieri, Andrea ; Amouri, Hani</creatorcontrib><description>A series of functionalized cyclometallated rhodium and iridium coordination assemblies 2–7 displaying a π-bonded dioxolene ligand is described. The X-ray molecular structures of two of the above compounds showed the formation of a 1D supramolecular chain mediated by π–π interactions among individual units. The luminescent properties of these compounds are presented and discussed. These results show that the stacking interactions are retained also in solution and emission from excited dimeric species is observed.</description><identifier>ISSN: 2046-2069</identifier><identifier>EISSN: 2046-2069</identifier><identifier>DOI: 10.1039/C4RA01185F</identifier><language>eng</language><publisher>Royal Society of Chemistry</publisher><subject>Chemical Sciences</subject><ispartof>RSC advances, 2014, Vol.4 (45), p.23740-23748</ispartof><rights>Distributed under a Creative Commons Attribution 4.0 International License</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c265t-84c7db67f44e0621fdda57e6533cc0ba23b242b8250685b96f15f4ff6724c3343</citedby><cites>FETCH-LOGICAL-c265t-84c7db67f44e0621fdda57e6533cc0ba23b242b8250685b96f15f4ff6724c3343</cites><orcidid>0000-0001-6955-8406 ; 0000-0002-8841-9521</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,780,784,885,4024,27923,27924,27925</link.rule.ids><backlink>$$Uhttps://hal.science/hal-01662106$$DView record in HAL$$Hfree_for_read</backlink></links><search><creatorcontrib>Damas, Aurelie</creatorcontrib><creatorcontrib>Sesolis, Hugo</creatorcontrib><creatorcontrib>Rager, Marie Noelle</creatorcontrib><creatorcontrib>Chamoreau, Lise Marie</creatorcontrib><creatorcontrib>Gullo, Maria Pia</creatorcontrib><creatorcontrib>Barbieri, Andrea</creatorcontrib><creatorcontrib>Amouri, Hani</creatorcontrib><title>Ester-substituted cyclometallated rhodium and iridium coordination assemblies with π-bonded dioxolene ligand: synthesis, structures and luminescent properties</title><title>RSC advances</title><description>A series of functionalized cyclometallated rhodium and iridium coordination assemblies 2–7 displaying a π-bonded dioxolene ligand is described. The X-ray molecular structures of two of the above compounds showed the formation of a 1D supramolecular chain mediated by π–π interactions among individual units. The luminescent properties of these compounds are presented and discussed. These results show that the stacking interactions are retained also in solution and emission from excited dimeric species is observed.</description><subject>Chemical Sciences</subject><issn>2046-2069</issn><issn>2046-2069</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNpNkc1KAzEUhYMoWGo3PkG2iqNJJpNp3ZXSWqEgiK6H_I0TySQlyajd-SY-kq_kjBX1bu65l3O-zQHgFKNLjPLZ1YLezxHG02J1AEYEUZYRxGaH__QxmMT4jPphBSYMj8DHMiYdstiJmEzqklZQ7qT1rU7cWj7cofHKdC3kTkETzLeW3gdlHE_GO8hj1K2wRkf4alIDP98z4Z3qo8r4N2-109Capz5_DePOpUZHEy9gTKGTqQt9bEDbrjVOR6ldgtvgtzqknngCjmpuo5787DF4XC0fFutsc3dzu5hvMklYkbIplaUSrKwp1YgRXCvFi1KzIs-lRIKTXBBKxJQUiE0LMWM1Lmpa16wkVOY5zcfgbM9tuK22wbQ87CrPTbWeb6rhhzDruYi94N57vvfK4GMMuv4NYFQNTVR_TeRfay1_7A</recordid><startdate>2014</startdate><enddate>2014</enddate><creator>Damas, Aurelie</creator><creator>Sesolis, Hugo</creator><creator>Rager, Marie Noelle</creator><creator>Chamoreau, Lise Marie</creator><creator>Gullo, Maria Pia</creator><creator>Barbieri, Andrea</creator><creator>Amouri, Hani</creator><general>Royal Society of Chemistry</general><scope>AAYXX</scope><scope>CITATION</scope><scope>1XC</scope><orcidid>https://orcid.org/0000-0001-6955-8406</orcidid><orcidid>https://orcid.org/0000-0002-8841-9521</orcidid></search><sort><creationdate>2014</creationdate><title>Ester-substituted cyclometallated rhodium and iridium coordination assemblies with π-bonded dioxolene ligand: synthesis, structures and luminescent properties</title><author>Damas, Aurelie ; Sesolis, Hugo ; Rager, Marie Noelle ; Chamoreau, Lise Marie ; Gullo, Maria Pia ; Barbieri, Andrea ; Amouri, Hani</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c265t-84c7db67f44e0621fdda57e6533cc0ba23b242b8250685b96f15f4ff6724c3343</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Chemical Sciences</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Damas, Aurelie</creatorcontrib><creatorcontrib>Sesolis, Hugo</creatorcontrib><creatorcontrib>Rager, Marie Noelle</creatorcontrib><creatorcontrib>Chamoreau, Lise Marie</creatorcontrib><creatorcontrib>Gullo, Maria Pia</creatorcontrib><creatorcontrib>Barbieri, Andrea</creatorcontrib><creatorcontrib>Amouri, Hani</creatorcontrib><collection>CrossRef</collection><collection>Hyper Article en Ligne (HAL)</collection><jtitle>RSC advances</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Damas, Aurelie</au><au>Sesolis, Hugo</au><au>Rager, Marie Noelle</au><au>Chamoreau, Lise Marie</au><au>Gullo, Maria Pia</au><au>Barbieri, Andrea</au><au>Amouri, Hani</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ester-substituted cyclometallated rhodium and iridium coordination assemblies with π-bonded dioxolene ligand: synthesis, structures and luminescent properties</atitle><jtitle>RSC advances</jtitle><date>2014</date><risdate>2014</risdate><volume>4</volume><issue>45</issue><spage>23740</spage><epage>23748</epage><pages>23740-23748</pages><issn>2046-2069</issn><eissn>2046-2069</eissn><abstract>A series of functionalized cyclometallated rhodium and iridium coordination assemblies 2–7 displaying a π-bonded dioxolene ligand is described. The X-ray molecular structures of two of the above compounds showed the formation of a 1D supramolecular chain mediated by π–π interactions among individual units. The luminescent properties of these compounds are presented and discussed. These results show that the stacking interactions are retained also in solution and emission from excited dimeric species is observed.</abstract><pub>Royal Society of Chemistry</pub><doi>10.1039/C4RA01185F</doi><tpages>9</tpages><orcidid>https://orcid.org/0000-0001-6955-8406</orcidid><orcidid>https://orcid.org/0000-0002-8841-9521</orcidid></addata></record>
fulltext fulltext
identifier ISSN: 2046-2069
ispartof RSC advances, 2014, Vol.4 (45), p.23740-23748
issn 2046-2069
2046-2069
language eng
recordid cdi_hal_primary_oai_HAL_hal_01662106v1
source Royal Society Of Chemistry Journals 2008-
subjects Chemical Sciences
title Ester-substituted cyclometallated rhodium and iridium coordination assemblies with π-bonded dioxolene ligand: synthesis, structures and luminescent properties
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-04T16%3A57%3A23IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-hal_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Ester-substituted%20cyclometallated%20rhodium%20and%20iridium%20coordination%20assemblies%20with%20%CF%80-bonded%20dioxolene%20ligand:%20synthesis,%20structures%20and%20luminescent%20properties&rft.jtitle=RSC%20advances&rft.au=Damas,%20Aurelie&rft.date=2014&rft.volume=4&rft.issue=45&rft.spage=23740&rft.epage=23748&rft.pages=23740-23748&rft.issn=2046-2069&rft.eissn=2046-2069&rft_id=info:doi/10.1039/C4RA01185F&rft_dat=%3Chal_cross%3Eoai_HAL_hal_01662106v1%3C/hal_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true