Ligand-Centered Redox Activity in Cobalt(II) and Nickel(II) Bis(phenolate)-Dipyrrin Complexes

One for all: A trianionic ligand containing the biologically relevant moieties phenolate and porphyrin was designed and synthesized. One‐electron oxidation of the nickel and cobalt complexes of these ligands affords an unprecedented and highly stable hybrid porphyrinyl–phenoxyl radical bound to the...

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Veröffentlicht in:	Chemistry : a European journal 2012-11, Vol.18 (46), p.14590-14593
Hauptverfasser:	Kochem, Amélie, Chiang, Linus, Baptiste, Benoit, Philouze, Christian, Leconte, Nicolas, Jarjayes, Olivier, Storr, Tim, Thomas, Fabrice
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemical Sciences Chemistry cobalt Cobalt - chemistry dipyrrin Electrons Ligands Molecular Structure nickel Nickel - chemistry Organometallic Compounds - chemical synthesis Organometallic Compounds - chemistry Oxidation-Reduction porphyrins Porphyrins - chemical synthesis Porphyrins - chemistry redox chemistry
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