Activation of a σ‑SnSn Bond at Copper, Followed by Double Addition to an Alkyne

Many synthetically useful copper-catalyzed transformations involve the activation of apolar or weakly polar σ-bonds (E–H and E–E′ bonds, with E = C, B, Si, Sn, etc.). Yet, little is known so far about the associated elementary steps, and it is highly desirable to gain better knowledge regarding the...

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Veröffentlicht in:	Journal of the American Chemical Society 2013-09, Vol.135 (37), p.13827-13834
Hauptverfasser:	Lassauque, Nicolas, Gualco, Pauline, Mallet-Ladeira, Sonia, Miqueu, Karinne, Amgoune, Abderrahmane, Bourissou, Didier
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Chemical Sciences Coordination chemistry or physical chemistry Organic chemistry Polymers Theoretical and
Online-Zugang:	Volltext
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